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31.
The work aims to characterise PCDDs/Fs in environmental matrices by high resolution gas chromatography coupled to low resolution quadrupole ion-trap mass spectrometry (GC-QITMS/MS). In particular, the study was mainly focused in different environmental samples such as sewage sludge, soils, and sediments and in combustion residues as fly ashes. Previous experiences have already detected and quantified PCDDs/PCDFs in all matrices studied. Moreover, isomer-specific analysis of 2,3,7,8-PCDDs/Fs compounds corroborated good correlation between GC-QITMS/MS and a well-established technique such as high resolution mass spectrometry (HRMS). Finally, QC measures included the participation in intercalibration exercises. Successful results were achieved using GC-QITMS/MS in the analysis of fly ashes, soils and sediment materials. In general, GC-QITMS/MS constitutes an interesting alternative for routine analysis of dioxins in such as matrices. 相似文献
32.
Marianne Lefebvre Maria Espinosa Sergio Gomez y Paloma Maria Luisa Paracchini Annette Piorr Ingo Zasada 《Journal of Environmental Planning and Management》2015,58(12):2088-2112
During the last 50 years, the Common Agricultural Policy (CAP) has impacted the evolution of European agricultural landscapes by driving changes in land use and farming practices. We propose a typology characterising the scales relevant for agricultural landscapes management and argue that action is required on three scales: (1) a landscape oriented management at the farm level; (2) the coordination of land managers’ actions at the landscape level; and (3) the conservation of the diversity of agricultural landscapes in the EU. We provide evidence that until now the CAP has mainly focused on the first scale. We also illustrate how agricultural policy could encourage coordinated actions at the landscape- and EU-scales. In particular, we propose policy instruments to coordinate actions of individual land owners (e.g. collective bonus in agro-environmental contracts or support to environmental cooperatives (scale 2)). We also analyse how the recognition and transposition of the European Landscape Convention could promote trans-frontier landscape cooperation in order, not only to conserve high-quality rural landscapes, but also to ensure the conservation of the diversity of EU landscapes (scale 3). This paper provides a knowledge base to support an integrated CAP design in the direction of improved landscape management, as an important component of the EU project towards more sustainable agriculture. 相似文献
33.
Meier Sebastián Moore Francisca González María-Eugenia Medina Jorge Campos Pedro Khan Naser Cumming Jonathan Sanhueza Mario Mejías Jaime Morales Arturo Hirzel Juan Seguel Alex 《Environmental geochemistry and health》2021,43(4):1441-1456
Environmental Geochemistry and Health - Biochar (BC) is a porous, carbonaceous material produced by slow pyrolysis of biomass under oxygen-limited conditions. BC production has been attracting... 相似文献
34.
Sánchez-Blanco MJ Rodríguez P Morales MA Torrecillas A 《Journal of environmental quality》2003,32(6):2238-2244
Plants of two wild native species from littoral areas, marguerite [Argyranthemum coronopifolium (Willd.) C.J. Humphries] and dwarf sea-lavender [Limonium pectinatum (Aiton) O. Kuntze], grown in an unheated plastic greenhouse, were sprayed 2 to 3 min per day over a 7-d period with different aqueous solutions containing (i) an anionic surfactant (S1); (ii) a solution simulating the composition of sea aerosol (S2); (iii) a solution simulating sea aerosol with anionic surfactant (S3), and (iv) deionized water alone (control). The plant resistance to sea aerosol and the ability to recover from treatments were studied. By the end of the spraying period, marguerite showed a significant reduction in growth compared with control. However, most of the growth parameters were significantly unaffected in dwarf sea-lavender when plants were treated with sea aerosol containing surfactant. Measurements of water relations variables in marguerite showed a slight decrease in leaf turgor potential after spraying with sea aerosol containing surfactant. The surfactant enhanced the foliar absorption of salt in marguerite plants, inducing reductions in leaf stomatal conductance and causing such damage in the photosynthetic apparatus that the level of net photosynthesis decreased and had not recovered by the end of the experiment. The treatments had no effect on leaf stomatal conductance and photosynthesis rate in dwarf sea-lavender plants. The response of the species studied to sea aerosol was related to the degree of salinity tolerance. Although both species are wild native plants from littoral areas, marguerite is not salt tolerant and was the most sensitive to the sea aerosol treatments, while dwarf sea-lavender, a halophyte species, was more efficient at decreasing the toxic salt content of the tissues as its growth and ornamental characteristics were not affected. 相似文献
35.
Modelling the Ecological Vulnerability to Forest Fires in Mediterranean Ecosystems Using Geographic Information Technologies 总被引:1,自引:0,他引:1
Beatriz Duguy José Antonio Alloza M. Jaime Baeza Juan De la Riva Maite Echeverría Paloma Ibarra Juan Llovet Fernando Pérez Cabello Pere Rovira Ramon V. Vallejo 《Environmental management》2012,50(6):1012-1026
Forest fires represent a major driver of change at the ecosystem and landscape levels in the Mediterranean region. Environmental features and vegetation are key factors to estimate the ecological vulnerability to fire; defined as the degree to which an ecosystem is susceptible to, and unable to cope with, adverse effects of fire (provided a fire occurs). Given the predicted climatic changes for the region, it is urgent to validate spatially explicit tools for assessing this vulnerability in order to support the design of new fire prevention and restoration strategies. This work presents an innovative GIS-based modelling approach to evaluate the ecological vulnerability to fire of an ecosystem, considering its main components (soil and vegetation) and different time scales. The evaluation was structured in three stages: short-term (focussed on soil degradation risk), medium-term (focussed on changes in vegetation), and coupling of the short- and medium-term vulnerabilities. The model was implemented in two regions: Aragón (inland North-eastern Spain) and Valencia (eastern Spain). Maps of the ecological vulnerability to fire were produced at a regional scale. We partially validated the model in a study site combining two complementary approaches that focused on testing the adequacy of model’s predictions in three ecosystems, all very common in fire-prone landscapes of eastern Spain: two shrublands and a pine forest. Both approaches were based on the comparison of model’s predictions with values of NDVI (Normalized Difference Vegetation Index), which is considered a good proxy for green biomass. Both methods showed that the model’s performance is satisfactory when applied to the three selected vegetation types. 相似文献
36.
Patrícia Moraes Sinohara Souza Ana Rita Morales Maria Aparecida Marin-Morales Lucia Helena Innocentini Mei 《Journal of Polymers and the Environment》2013,21(3):738-759
The concern related to solid waste increases efforts to develop products based on biodegradable materials. At present, PLA has one of the highest potentials among biopolyesters, particularly for packaging. However, its application is limited in some fields. In order to optimize PLA properties, organo-modified montmorilonites have been extensively used to obtain nanocomposites. Although PLA nanocomposites studies are widely reported in the literature, there is still few information about the influence of organoclays on de biodegradation process, which is a relevant information, since one of the main purposals related to the final disposal of biopolymers as PLA is composting. Besides, in the last years some research has been conducted in order to evaluate the potential toxicity of montmorilonite, unmodified or organo-modified. Since the use of montmorilonite is expanding in different applications, human exposure and risk assessment are important issues to be investigated. In this context, this review intends to compile available information related to common organoclays used for PLA nanocomposites, its properties, biodegradation analysis and potential toxicity evaluation of nanocomposites, focused on montmorilonite as filler. Two issues of relevance were pointed out. The first is food safety and quality, and the second consideration is the environmental effect. 相似文献
37.
Armenteras Dolors Rodríguez Nelly Retana Javier Morales Mónica 《Regional Environmental Change》2011,11(3):693-705
Colombian Andean forests cover nine million ha. These forests provide an informative case study of mountain deforestation
in South America. They are surrounded by tropical lowland forests, and they host most of the country’s human population. This
study evaluates the relative importance of human and natural variables in deforestation of the Colombian Andes between 1985
and 2005 using remote sensing methods, geographic information system (GIS) technology and general linear models (GLM). The
following factors affected the annual deforestation in the region positively: forced population migration, unsatisfied basic
needs, economic activity, crops, pastures, illicit crops, protected areas and slope. Factors having a negative effect were
tenure of small land parcels, road density, water scarcity and mean temperature. The results of this study also provide insight
into the differences between the dynamics of lowland forests and those of montane forests. Montane forests had a lower annual
rate of deforestation than did forests in the lowlands. Socio-economic, demographic and biophysical factors explain overall
deforestation rates for the region. However, when altitude variation is taken into account, intraregional differences in the
Andes become evident. Deforestation processes differ between those areas adjacent to the high Andean valleys where most of
the country’s population concentrates and those areas in the tropical lowlands north, west and east of the Andean chain. Differences
between lowland and montane forest dynamics are due partly to the accessibility of forests and differences in wealth and economic
activities. In montane forests, deforestation is positively influenced by economic activity, the presence of protected areas
and higher slopes. Deforestation in montane forests is negatively affected by tenure of small land parcels, road density,
water scarcity and mean temperature. Lowland deforestation rates are more closely related to rural population, pasture percentage,
crops, protected areas and temperature. Our results suggest that montane forests appear to be in a more advanced stage of
colonisation and economic development, whereas lowland forests are closer to the colonisation frontier and to rapidly growing
colonist populations. This study reinforces the idea that although the most common tropical drivers of deforestation are found
in the Andes, these drivers operate differently when intraregional differences are considered. 相似文献
38.
A survey to estimate the polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) emissions of Spanish hot dip galvanising sector was carried out during 2002. This investigation is the first presenting Spanish experimental data related to this industrial sector. Three different matrices: flue gas, ash and filter dust were tested to quantify the PCDD/Fs generated during the galvanising process. The organic source of PCDD/F formation could be from the insufficient degreasing o from inhibitors or additives used in the pickling steps such as quinoline, isoquinoline, 8-methylquinoline or polyether phosphoric acid. Low levels PCDD/Fs were achieved in air emissions when air control devices are used. On the contrary, filter dusts are highly contaminated; indicating that the absence of air control devices would increase the risk of fugitive emissions. Homologue profiles and Principal Component Analysis demonstrate there are differences in the formation mechanisms in the bath zone (ashes) compared to the stack location (filter dusts and air emissions), related to the de novo synthesis and reaction time. The annual PCDD/F emission to the atmosphere for this sector during 2002 has been estimated in 0.023g I-TEQ. The emission factor of plants with air control devices has been calculated at 0.030microg I-TEQ/ton of galvanised steel. 相似文献
39.
Esther Mancebo Iván Bernardo Maria J. Castro Francisco J. Fernández-Martinez Emilia Barreiro Paloma De-Pablos M.a Jesús Marin Silvia Cortezon Estela Paz-Artal Luis M. Allende 《黑龙江环境通报》2007,27(9):861-864
Mutations of the ataxia-telangiectasia-mutated (ATM) gene are responsible for the autosomal recessive disorder ataxia-telangiectasia (A-T). This study reports the first A-T prenatal diagnosis performed in Spain by direct molecular analysis. The pregnant woman had a previous child suffering from A-T due to a deletion in the ATM gene. The ATM coding region was sequenced in the A-T patient and her parents. Then, a specific polymerase chain reaction (PCR) to detect the deletion was performed for prenatal diagnosis. Additionally, polymorphic HLA loci were examined in order to exclude the possible contamination by maternal DNA. In this family of Gypsy origin, we carried out a rapid molecular diagnosis of A-T. Then, a prenatal diagnosis was carried out, identifying the deletion in the fetal DNA. Additionally, we performed a population study in unrelated Spanish Gypsies and in unrelated controls, showing that the deletion described could be a hotspot in the Spanish Gypsy population. The size of the coding region and the genomic structure, together with the absence of hotspots, make the mutation screening of the ATM gene difficult. The ability to identify ATM mutations provides a tool that can be applied in confirmatory diagnosis, genetic counselling, carrier prediction and prenatal diagnosis. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
40.
Here we analyze herbarium records, surveys, and studies of fungal plant pathogens in tropical natural systems in order to establish a framework to study plant-pathogen interactions from a life-history perspective. We looked at how life-history traits of pathogens and their host plants affect the distribution of pathogens in different tropical habitats, and the importance of host phylogeny in determining the habitat associations of obligate fungal pathogens. Our study reveals that plant-pathogen interactions are prevalent and widespread in the tropics. Phylogenetic analysis of the distribution of obligate pathogens among plant families did not suggest a strong overall pattern of higher-level host phylogeny in pathogen host range, except that smut pathogens are particularly dominant on Poaceae and Asteraceae, and rusts are most common on Fabaceae, families that dominate disturbed areas in the tropics. 相似文献