Nitrogen and phosphorus exports from channelizedstream watersheds were elevated over those from nearby natural swamp-stream watersheds. Nitrate exports were significantly greater from channelized-stream watersheds, and higher exports were attributed to faster groundwater drawdown, continual streamflow, and transformation of former floodplain to croplands following channelization. Exports of total organic nitrogen and total nitrogen were also significantly greater from channelized-stream watersheds. Differences in the exports of ammonium, filterable reactive phosphorus, and filterable unreactive phosphorus between the two watershed types were not detectable. Particulate phosphorus exports were significantly higher from channelized-stream watersheds, presumably because of greater erosion potential of nearby croplands and steep channel banks in the altered watersheds. The presence of nonpoint sources of pollution increased watershed exports of nutrients regardless of stream morphology. Examination of nutrient budgets for a portion of swamp floodplain at the base of one natural-stream watershed revealed that changes in local groundwater hydrology and stream morphology associated with channelization appeared to have greater effect on nutrient exports than simply the loss of bordering forested floodplain. 相似文献
Little is known about the physicochemical properties of beryllium aerosols associated with increased risk of beryllium sensitization and chronic beryllium disease (CBD). Such information is needed to evaluate whether airborne mass of beryllium is the appropriate metric of exposure or alternatively to provide a scientific basis for using information on particle size, surface area, and chemistry to support an improved exposure limit based on bioavailability through the inhalation and dermal routes of exposure. Thus, we used a suite of analytical techniques to characterize aerodynamically size-fractionated beryllium particles and powders that have been associated in epidemiological studies with higher prevalence of CBD. Aerosol particles were sampled from the ventilation systems of production lines for powders of beryllium metal and beryllium oxide and for ingots of copper-beryllium alloy. End product powders from the metal and oxide production lines were also collected.Particles released during production of beryllium metal were found to be complex, having heterogeneous composition, including reactive species such as fluorine. Powders from beryllium metal production were of high purity with only a minor component of beryllium oxide. Both particles and powders from oxide production were high-purity oxide. Particles released during production of copper-beryllium alloy were heterogeneous, being predominantly copper oxides. Thus, all particles and powders contain at least some beryllium in the form of beryllium oxide.These data justify efforts to thoroughly characterize beryllium aerosol properties when performing exposure assessments. The data also suggest that differences in particle chemical composition, size, number, and surface area may influence bioavailability of beryllium and contribute to risk of CBD. However, a scientific basis does not yet exist to replace mass as the current metric of exposure. 相似文献
The popularity of sustainability indicators is almost inescapable. From the early pioneers such as the 'Sustainable Seattle' project (Atkisson, 'Developing Indicators of a Sustainable Community: lessons from Sustainable Seattle', in: D. Satterthwaite (Ed), The Earthscan Reader in Sustainable Cities, London, Earthscan, 1996) to the comprehensive European Union benchmarking launched in 2003 (European Commission, European Common Indicators: towards a local sustainability profile, Milan, Ambiente Italia, 2003), it seems that consensus has been reached about the positive impacts that establishing sustainability indicators can bring. This paper uses the case of developing sustainability indicators on the Island of Guernsey over the last three years to show that Agenda 21's call to activate grassroots action is being realised, but in ways that are neither top-down and modernist in approach nor bottom-up and postmodernist as Agenda 21 advocates. Although best practice literature often suggests that community involvement must be engaged prior to designing sustainability indicators, this paper explores the reasons why this is not always possible. Guernsey's case is used to show how it only became possible to generate interest in the indicator process once they were actually up and running. However, it also shows that once interest was secured by a few relevant stakeholders it became possible to further evolve the indicators in a process that has slowly been attracting more and more of the Island's community. 相似文献
Dynamic zoning (systematic alteration in the spatial and temporal allocation of even-aged forest management practices) has been proposed as a means to change the spatial pattern of timber harvest across a landscape to maximize forest interior habitat while holding timber harvest levels constant. Simulation studies have established that dynamic zoning strategies produce larger tracts of interior, closed canopy forest, thus increasing the value of these landscapes for interior-dependent wildlife. We used the simulation model LANDIS to examine how the implementation of a dynamic zoning strategy would change trajectories of ecological succession in the Great Divide Ranger District of the Chequamegon–Nicolet National Forest in northern Wisconsin over 500 years. The components of dynamic zoning strategies (number of zones in a scenario and the length of the hiatus between successive entries into zones) and their interaction had highly significant impacts on patterns of forest succession. Dynamic zoning scenarios with more zones and shorter hiatus lengths increased the average amount of the forest dominated by early successional aspen (Populus sp.). Dynamic zoning scenarios with two zones produced more late successional mature northern hardwoods than scenarios with four zones. Dynamic zoning scenarios with very short (30 years) or very long (120 years) hiatus lengths resulted in more late successional mature northern hardwoods than scenarios with intermediate hiatus lengths (60 and 90 years). However, none of the dynamic scenarios produced as much late successional mature northern hardwoods as the static alternative. Furthermore, the amounts of all habitat types in all dynamic zoning scenarios fluctuated greatly in time and space relative to static alternatives, which could negatively impact wildlife species that require a stable amount of habitat above some minimum critical threshold. Indeed, implementing dynamic zoning scenarios of different designs would have both positive and negative effects on wildlife species and for other objectives of forest management. 相似文献
Valley bottom wetlands in agricultural landscapes often are neglected in national and regional wetland inventories. Although
these areas are small, located in the bottomlands of the headwater catchments, and scattered in the rural landscape, they
strongly influence hydrology, water quality, and biodiversity over the whole catchment area. Valley bottom wetlands often
are considered as controversial wetlands. Awareness of the functional role of wetlands is increasing, in parallel with their
progressive disappearance in intensive farming landscapes. The need to improve tools for controlling wetland management is
a primary consideration for decision makers and land users. This article proposes a method for the inventory of valley bottom
wetlands. The method is based on the functional analysis of potential, existing, and efficient valley bottom wetlands (the
PEEW approach). Several indicators are proposed for checking the validity of such an approach. Potential wetlands are delineated
by means of a topographic index using topographic and pedoclimatic criteria computed from a Digital Elevation Model and easily
accessible databases. Existing wetlands are identified from observed surface moisture, the presence of specific wetland vegetation,
or soil feature criteria. Efficient wetlands are defined through a given function, such as flow or pollutant regulation or
biodiversity control. An analysis of areas at the limits between potential, existing, and efficient wetlands highlights land
cultivated or drained in the past, which currently represents negotiating areas in which rehabilitation and other intended
management actions can be implemented. 相似文献
During the 1950s and 1960s, reproductive failures and population declines were observed in fish-eating birds such as gulls, terns, cormorants, herons, and eagles in the Great Lakes. DDE-induced eggshell thinning contributed to these declines, but other factors such as embryo toxicity also were implicated. With reduced releases of many pollutants, reproduction recovered in some species. However, biomonitoring during the 1980s and 1990s indicates continuing effects at highly contaminated sites. Improved analytical techniques and bioassays have allowed the assessment of the total dioxin-like toxicity of complex mixtures of organochlorines (TCDD-equivalents). Developmental defects such as embryo mortality, deformities, and edema have been associated with dioxin-like PCBs in several avian species. Improved biochemical techniques have allowed the measurement of biomarkers that detect physiological alterations associated with contaminants. Specific biomarkers studied in Great Lakes birds include cytochrome P-450 monooxygenases, highly carboxylated porphyrins, thyroxine, vitamin A, and immune function. Reproductive and physiological alterations are associated with population-level effects in Caspian terns and bald eagles that feed on highly contaminated fish. Biomonitoring using biomarkers and population-level measures in fish-eating birds will continue to be important for assessing the effects of contaminants on the Great Lakes ecosystem. 相似文献
This paper examines the relationship between psychological contract breach and insomnia among older workers (aged 40 years and up). Drawing upon the conservation of resources theory, we conceptualize breach as a stressful event characterized by a perceived threat, failure to gain, or actual loss of valued resources, which increases psychological distress and insomnia. Moreover, we hypothesized that older workers' generativity concerns would act as a personal resource that would buffer the negative impact of breach. We tested our proposed model in 2 studies (Study 1 = 123; Study 2 = 168) of employee–spouse dyads. Results revealed that psychological distress mediated the relationship between psychological contract breach and insomnia. These mediated relationships were significant for those with low, but not for those with high levels of generativity concerns. These effects remained significant even after controlling for perceived organizational support (i.e., a social exchange mechanism). Theoretical and practical implications are discussed. 相似文献
Objective: This study was designed to evaluate the performance of a pelvic restraint cushion (PRC), a submarining countermeasure that deploys under the thighs when a crash is detected in order to block the forward motion of the pelvis.
Methods: Sled tests approximating low- and high-speed frontal impacts were conducted with 4 female postmortem human subjects (PMHS) restrained by a lap and shoulder belt in the right front passenger seat. The subjects were tested with and without a PRC.
Results: The PRC is effective in reducing forward motion of the PMHS pelvis and reduces the risk of injury due to lap belt loading in a high-speed frontal crash.
Conclusions: Although small sample size limits the utility of the study's findings, the results suggest that the PRC can limit pelvic forward motion and that pelvic injury due to PRC deployment is not likely. 相似文献
This paper examines historical and future changes in normalised damages resulting from climate-related natural disasters for the Caribbean. Annualised damages of USD824 million are shown to be non-stationary over the historical period 1964 to 2013. Perturbations of (i) sea surface temperatures (SST) in the tropical North Atlantic (TNA) and (ii) the Atlantic multi-decadal oscillation (AMO) appear to be associated with historical damages. Both the TNA and AMO are known modulators of hurricane activity and rainfall amounts in the Caribbean. Indicative future damages are determined using (i) cumulative distribution functions (CDFs) of perturbed climate states and (ii) an artificial neural network (ANN) model of damages using projected TNA values and the state of the AMO derived from an ensemble of five coupled model intercomparison project phase 5 (CMIP5) global climate models (GCMs) run under the RCP 4.5 scenario. Estimates of future damages are determined when global mean surface temperatures (GMST) reach and exceed 1.5 °C above preindustrial levels. Annual normalised damages may potentially increase to at least USD1395 million or close to double for 1.5 °C. At 2 °C, higher damages may occur; however, large uncertainty across all GCMs prohibits the identification of significant difference between 1.5 and 2 °C. Significant differences in damages do, however, exist for at least two of the GCMs for the two climate states. The robustness of the results is discussed in light of a number of issues, including limitations associated with the data. 相似文献
Headwater streams are critical components of the stream network, yet landowner perceptions, attitudes, and property management behaviors surrounding these intermittent and ephemeral streams are not well understood. Our research uses the concept of watershed disproportionality, where coupled social-biophysical conditions bear a disproportionate responsibility for harmful water quality outcomes, to analyze the potential influence of riparian landowner perceptions and attitudes on water quality in headwater regions. We combine social science survey data, aerial imagery, and an analysis of spatial point processes to assess the relationship between riparian landowner perceptions and attitudes in relation to stream flow regularity. Stream flow regularity directly and positively shapes landowners’ water quality concerns, and also positively influences landowners’ attitudes of stream importance—a key determinant of water quality concern as identified in a path analysis. Similarly, riparian landowners who do not notice or perceive a stream on their property are likely located in headwater regions. Our findings indicate that landowners of headwater streams, which are critical areas for watershed-scale water quality, are less likely to manage for water quality than landowners with perennial streams in an obvious, natural channel. We discuss the relationships between streamflow and how landowners develop understandings of their stream, and relate this to the broader water quality implications of headwater stream mismanagement. 相似文献