Photocatalytic degradation of the diuron pesticide

The occurrence of chlorinated pesticides in wellwaters is a major problem of public health in Ivory Coast and other African countries. Here, we studied the photocatalytic degradation of the pesticide diuron in aqueous solution in presence of two commercial TiO₂ catalysts, P25 and PC500. The capacity of diuron adsorption at the TiO₂ surface is lower for both photocatalysts. The efficiency of photocatalytic degradation of diuron, it is higher using P25 Degussa than PC500 Millenium TiO₂ catalyst.     

Modelling habitat overlap among sympatric mesocarnivores in southern Illinois,USA

Few researchers have developed large-scale habitat models for sympatric carnivore species. We created habitat models for red foxes (Vulpes vulpes), coyotes (Canis latrans) and bobcats (Lynx rufus) in southern Illinois, USA, using the Penrose distance statistic, remotely sensed landscape data, and sighting location data within a GIS. Our objectives were to quantify and spatially model potential habitat differences among species. Habitat variables were quantified for 1-km² buffered areas around mesocarnivore sighting locations. Following variable reduction procedures, five habitat variables (percentage of grassland patches, interspersion–juxtaposition of forest patches, mean fractal dimension of wetland patches and the landscape, and road density) were used for analysis. Only one variable differed (P < 0.05) between red fox and coyote sighting areas (road density) and bobcat and coyote sighting areas (mean fractal dimension of the landscape). However, all five variables differed between red fox and bobcat sighting areas, indicating considerable differences in habitat affiliation between this pair-group. Compared to bobcats, red fox sightings were affiliated with more grassland cover and larger grassland patches, higher road densities, lower interspersion and juxtaposition of forest patches, and lower mean fractal dimension of wetland patches. These differences can be explained by different life history requirements relative to specific cover types. We then used the Penrose distance statistic to create habitat models for red foxes and bobcats, respectively, based on the five-variable dataset. An independent set of sighting locations were used to validate these models; model fit was good with 65% of mesocarnivore locations within the top 50% of Penrose distance values. In general, red foxes were affiliated with mixtures of agricultural and grassland cover, whereas bobcats were associated with a combination of grassland, wetland, and forest cover. The greatest habitat overlap between red foxes and bobcats was found at the interface between forested areas and more open cover types. Our study provides insight into habitat overlap among sympatric mesocarnivores, and the distance-based modelling approach we used has numerous applications for modelling wildlife–habitat relationships over large scales.     

EFFECTIVENESS OF BIOPHYSICAL CRITERIA IN THE HIERARCHICAL CLASSIFICATION OF DRMNAGE BASINS1

ABSTRACT: A subwatershed base map of 84 hydrologic subregions within the Columbia River Basin (approximately 58,361,000 ha) was developed following hierarchical principles of ecological unit mapping. Our primary objectives were to inspect the relations between direct and indirect biophysical variables in the prediction of valley bottom and stream type patterns, and to identify hydrologic subregions (based on these results) that had similar aquatic patterns for which consistent management practices could be applied. Realization of these objectives required: (1) stratified subsampling of valley bottom and stream type composition within selected sub‐watersheds, (2) identification of direct and indirect biophysical variables that were mappable across the basin and that exerted primary control on the distribution of sampled aquatic patterns, and (3) development of hydrologic subregion maps based on the primary biophysical variables identified. Canonical correspondence analysis indicated that a core set of 15 direct variables (e.g., average watershed slope, drainage density, ten‐year peak flow) and 19 indirect variables (i.e., nine subsection groups, four lithology groups, and six potential vegetation settings) accounted for 31 and 30 percent (respectively) of valley bottom/stream type composition variability and 84 and 80 percent (respectively) of valley bottom/stream type environmental variability within subsamples. The 19 indirect biophysical variables identified were used to produce an ecological unit classification of 7,462 subwatersheds within the basin by a hierarchical agglomerative clustering technique (i.e., hydrologic subregions were identified). Discriminant analysis indicated that 13 direct biophysical variables could correctly assign 80 percent of the subwatersheds to their indirect biophysical classification, thus demonstrating the strong relation that exists between indirect biophysical based classifications (ecological units) and the direct biophysical variables that determine finer‐level aquatic patterns. Our hydrologic subregion classifications were also effective in explaining observed differences in management hazard ratings across all subwatersheds of the basin. Results of this research indicate that ecological units can be effectively used to produce watershed classifications that integrate the effects of direct biophysical variables on finer‐level aquatic patterns, and predict opportunities and limitations for management.     

Community participation in the management of forest reserves in the Northern Region of Ghana

The 1994 forest and wildlife policy of Ghana provides the basis for community participation in forest management through participatory forest management. Even though forest reserves in the Northern Region are said to be managed collaboratively, fringe communities are supposedly involved only in maintenance activities of the reserve boundaries and seedling planting in plantation programmes. The forest reserves are said to be threatened by illegal activities from the fringe communities. This study therefore examined the nature of community participation in the management of forest reserves.

It is a mixed method research in which structured interview schedule, in-depth interview and focus group discussion guides were used for data collection. Respondents comprised community members, forestry staff and NGOs. Communities’ participation was found to be passive and tokenistic and limited to boundary cleaning and providing labour on plantations. There is no formal collaboration between communities and Forest Services Division. Prospects to communities’ participation lie in the continuous flow of benefits and their active involvement in management decisions. Active involvement of communities in all decision-making processes, capacity building of communities and forestry staff, incentive schemes and awareness creation are recommended for promoting community participation in managing forest reserves in Northern Region.     

Disruption of coastal societies in the Pacific Islands from rapid sea-level fall about AD 1300: new evidence from northern Viti Levu Island, Fiji

This paper reports preliminary findings of a study in northern Viti Levu Island (Fiji) intended to test the model of the AD 1300 Event. This holds that around AD 1250–1350, during the transition between the Medieval Warm Period and the Little Ice Age, there was a rapid climate-driven sea-level fall of 70–80 cm which created a food crisis for coastal dwellers throughout the tropical Pacific Islands and led to conflict and the abandonment of open coastal settlements in favour of those in more defensible locations. Two main areas were targeted—the Ba River Valley and adjoining Vatia Peninsula (plus offshore islands)—and inland/offshore sites in defensible locations, particularly in caves, ridge-top rockshelters, and isolated hilltops, were surveyed and test excavations made. Results show that while some of these sites were established during the AD 1300 Event, most were established shortly afterwards, which is exactly what the model predicts. It is concluded that prehistoric populations in Fiji (and similar island groups) were affected by the food crisis during the AD 1300 Event and did respond in ways that profoundly and enduringly altered contemporary trajectories of societal evolution. This study has great implications for the preservation of the record of prehistoric settlement in Fiji (and other tropical Pacific Island groups) because, as a consequence of this climate-forced migration from coasts to inland/upland sites, large amounts of sediment were released from island interiors and carried to their coasts where they buried earlier settlements or redistributed their material signature. Since European arrival in such places around 150 years ago, a second wave of coastal sedimentation, largely driven by plantation agriculture development had similar effects. The current rise of sea level around Pacific Island coasts is the latest in a series of (largely human) threats to the preservation of their cultural heritage.     

Restoring native fish assemblages to a regulated California stream using the natural flow regime concept

We examined the response of fishes to establishment of a new flow regime in lower Putah Creek, a regulated stream in California, U.S.A. The new flow regime was designed to mimic the seasonal timing of natural increases and decreases in stream flow. We monitored fish assemblages annually at six sample sites distributed over approximately 30 km of stream for eight years before and nine years after the new flow regime was implemented. Our purpose was to determine whether more natural stream flow patterns would reestablish native fishes and reduce the abundances of alien (nonnative) fishes. At the onset of our study, native fishes were constrained to habitat immediately (<1 km) below the diversion dam, and alien species were numerically dominant at all downstream sample sites. Following implementation of the new flow regime, native fishes regained dominance across more than 20 km of lower Putah Creek. We propose that the expansion of native fishes was facilitated by creation of favorable spawning and rearing conditions (e.g., elevated springtime flows), cooler water temperatures, maintenance of lotic (flowing) conditions over the length of the creek, and displacement of alien species by naturally occurring high-discharge events. Importantly, restoration of native fishes was achieved by manipulating stream flows at biologically important times of the year and only required a small increase in the total volume of water delivered downstream (i.e., water that was not diverted for other uses) during most water years. Our results validate that natural flow regimes can be used to effectively manipulate and manage fish assemblages in regulated rivers.     

Environmental public health tracking: piloting methods for surveillance of environmentally related diseases in England and Wales

An effective environmental public health tracking system integrates data and intelligence on environmental hazards, exposures, and health outcomes to focus interventions on reducing the impact of environmental contamination on public health. Most work in this area in the UK has focused on assessing data on hazards that are relatively easy to obtain. However, most hazards will present no actual risk and information on exposure is required to make an effective risk assessment. Obtaining exposure data is technically challenging, expensive, and potentially raises ethical concerns. Consequently, the Health Protection Agency is exploring methods for targeting geographical zones for efficient detailed environmental assessment (including exposure assessment). This paper describes and assesses three methods (indirect standardization, statistical process control (SPC) and kernel density contouring) for the surveillance of potentially environmentally related diseases for this purpose. While the evaluation demonstrates the utility of the three methods, particularly SPC, the comparison was limited due to ethical approval issues.     

Miniaturized test system for soil respiration induced by volatile pollutants

A miniaturized method based on 96-well microtitre plates was developed and used to study respiration in pristine and contaminated soils following addition of volatile substrates. Small soil samples were exposed to fuel components, which were volatilized from spatially separate reservoirs of 2,2,4,4,6,8,8-heptamethylnonane (HMN) as an organic carrier. Respiration was determined as CO(2) production by means of a pH-indicator and bicarbonate-containing agar, or as (14)CO(2) evolution from (14)C-labelled substrates. Substrate concentrations inducing maximum microbial activity or inhibition were determined and CO(2) production profiles examined by multivariate analysis. When high concentrations of fuel components were applied, distinction of hydrocarbon exposed soils from unexposed soil was achieved within 6 h of incubation. With low concentrations, adequate distinction was achieved after 24 h, probably as a result of community adaptation. Nutrient limitation was identified with the (14)C method for toluene, and the optimal N and P amendment determined. Further potential applications of this rapid and inexpensive method are outlined.     

Redox potential characterization and soil greenhouse gas concentration across a hydrological gradient in a Gulf coast forest

Soil redox potential (Eh), concentrations of oxygen (O2) and three greenhouse gases (CO2, CH4, and N2O) were measured in the soil profile of a coastal forest at ridge, transition, and swamp across a hydrological gradient. The results delineated a distinct boundary in soil Eh and O2 concentration between the ridge and swamp with essentially no overlap between the two locations. Critical soil Eh to initiate significant CH4 production under this field conditions was about +300 mV, much higher than in the homogenous soils (about -150 mV). The strength of CH4 source to the atmosphere was strong for the swamp, minor for the transition, and negligible or even negative (consumption) for the ridge. Maximum N2O concentration in the soils was found at about Eh +250 mV, and the soil N2O emission was estimated to account for less than 4% for the ridge and transition, and almost negligible for the swamp in the cumulative global warming potential (GWP) of these three gases. The dynamic nature of this study site in response to water table fluctuations across a hydrological gradient makes it an ideal model of impact of future sea level rise to coastal ecosystems. Soil carbon (C) sequestration potential due to increasing soil water content upon sea level rise and subsidence in this coastal forest was likely limited and temporal, and at the expense of increasing soil CH4 production and emission.