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91.
do A Kehrig H Seixas TG Palermo EA Baêta AP Castelo-Branco CW Malm O Moreira I 《Environmental science and pollution research international》2009,16(1):10-24
Background, aim, and scope Selenium (Se) has been shown to reduce mercury (Hg) bioavailability and trophic transfer in aquatic ecosystems. The study
of methylmercury (MeHg) and Se bioaccumulation by plankton is therefore of great significance in order to obtain a better
understanding of the estuarine processes concerning Hg and Se accumulation and biomagnification throughout the food web. In
the western South Atlantic, few studies have documented trace element and MeHg in fish tissues. No previous study about trace
elements and MeHg in plankton has been conducted concerning tropical marine food webs. Se, Hg, and MeHg were determined in
two size classes of plankton, microplankton (70–290 μm) and mesoplankton (≥290 μm), and also in muscle tissues and livers
of four fish species of different trophic levels (Mugil liza, a planktivorous fish; Bagre spp., an omnivorous fish; Micropogonias furnieri, a benthic carnivorous fish; and Centropomus undecimalis, a pelagic carnivorous fish) from a polluted estuary in the Brazilian Southeast coast, Guanabara Bay. Biological and ecological
factors such as body length, feeding habits, and trophic transfer were considered in order to outline the relationships between
these two elements. The differences in trace element levels among the different trophic levels were investigated.
Materials and methods Fish were collected from July 2004 to August 2005 at Guanabara Bay. Plankton was collected from six locations within the bay
in August 2005. Total mercury (THg) was determined by cold vapor atomic absorption spectrometry (CV-AAS) with sodium borohydride
as a reducing agent. MeHg analysis was conducted by digesting samples with an alcoholic potassium hydroxide solution followed
by dithizone-toluene extraction. MeHg was then identified and quantified in the toluene layer by gas chromatography with an
electron capture detector (GC-ECD). Se was determined by AAS using graphite tube with Pin platform and Zeeman background correction.
Results and discussion Total mercury, MeHg, and Se increased with plankton size class. THg and Se values were below 2.0 and 4.8 μg g−1 dry wt in microplankton and mesoplankton, respectively. A large excess of molar concentrations of Se in relation to THg was
observed in both plankton size class and both fish tissues. Plankton presented the lowest concentrations of this element.
In fish, the liver showed the highest THg and Se concentrations. THg and Se in muscle were higher in Centropomus undecimalis (3.4 and 25.5 nmol g−1) than in Micropogonias furnieri (2.9 and 15.3 nmol g−1), Bagre spp (1.3 and 3.4 nmol g−1) and Mugil liza (0.3 and 5.1 nmol g−1), respectively. The trophic transfer of THg and Se was observed between trophic levels from prey (considering microplankton
and mesoplankton) to top predator (fish). The top predators in this ecosystem, Centropomus undecimalis and Micropogonias furnieri, presented similar MeHg concentrations in muscles and liver. Microplankton presented lower ratios of methylmercury to total
mercury concentration (MeHg/THg) (34%) than those found in mesoplankton (69%) and in the muscle of planktivorous fish, Mugil liza (56%). The other fish species presented similar MeHg/THg in muscle tissue (of around 100%). M. liza showed lower MeHg/THg in the liver than C. undecimalis (35%), M. furnieri (31%) and Bagre spp. (22%). Significant positive linear relationships were observed between the molar concentrations of THg and Se in the
muscle tissue of M. furnieri and M. liza. These fish species also showed significant inverse linear relationships between hepatic MeHg and Se, suggesting a strong
antagonistic effect of Se on MeHg assimilation and accumulation.
Conclusions Differences found among the concentrations THg, MeHg, and Se in microplankton, mesozooplankton, and fishes were probably related
to the preferred prey and bioavailability of these elements in the marine environment. The increasing concentration of MeHg
and Se at successively higher trophic levels of the food web of Guanabara Bay corresponds to a transfer between trophic levels
from the lower trophic level to the top-level predator, suggesting that MeHg and Se were biomagnified throughout the food
web. Hg and Se were positively correlated with the fish standard length, suggesting that larger and older fish bioaccumulated
more of these trace elements. THg, MeHg, and Se were a function of the plankton size.
Recommendations and perspectives There is a need to assess the role of selenium in mercury accumulation in tropical ecosystems. Without further studies of
the speciation of selenium in livers of fishes from this region, the precise role of this element, if any, cannot be verified
in positively affecting mercury accumulation. Further studies of this element in the study of marine species should include
liver samples containing relatively high concentrations of mercury. A basin-wide survey of selenium in fishes is also recommended. 相似文献
92.
Phytoremediation of polyaromatic hydrocarbons, anilines and phenols 总被引:12,自引:0,他引:12
Harvey PJ Campanella BF Castro PM Harms H Lichtfouse E Schäffner AR Smrcek S Werck-Reichhart D 《Environmental science and pollution research international》2002,9(1):29-47
Phytoremediation technologies based on the combined action of plants and the microbial communities that they support within the rhizosphere hold promise in the remediation of land and waterways contaminated with hydrocarbons but they have not yet been adopted in large-scale remediation strategies. In this review plant and microbial degradative capacities, viewed as a continuum, have been dissected in order to identify where bottle-necks and limitations exist. Phenols, anilines and polyaromatic hydrocarbons (PAHs) were selected as the target classes of molecule for consideration, in part because of their common patterns of distribution, but also because of the urgent need to develop techniques to overcome their toxicity to human health. Depending on the chemical and physical properties of the pollutant, the emerging picture suggests that plants will draw pollutants including PAHs into the plant rhizosphere to varying extents via the transpiration stream. Mycorrhizosphere-bacteria and -fungi may play a crucial role in establishing plants in degraded ecosystems. Within the rhizosphere, microbial degradative activities prevail in order to extract energy and carbon skeletons from the pollutants for microbial cell growth. There has been little systematic analysis of the changing dynamics of pollutant degradation within the rhizosphere; however, the importance of plants in supplying oxygen and nutrients to the rhizosphere via fine roots, and of the beneficial effect of microorganisms on plant root growth is stressed. In addition to their role in supporting rhizospheric degradative activities, plants may possess a limited capacity to transport some of the more mobile pollutants into roots and shoots via fine roots. In those situations where uptake does occur (i.e. only limited microbial activity in the rhizosphere) there is good evidence that the pollutant may be metabolised. However, plant uptake is frequently associated with the inhibition of plant growth and an increasing tendency to oxidant stress. Pollutant tolerance seems to correlate with the ability to deposit large quantities of pollutant metabolites in the 'bound' residue fraction of plant cell walls compared to the vacuole. In this regard, particular attention is paid to the activities of peroxidases, laccases, cytochromes P450, glucosyltransferases and ABC transporters. However, despite the seemingly large diversity of these proteins, direct proof of their participation in the metabolism of industrial aromatic pollutants is surprisingly scarce and little is known about their control in the overall metabolic scheme. Little is known about the bioavailability of bound metabolites; however, there may be a need to prevent their movement into wildlife food chains. In this regard, the application to harvested plants of composting techniques based on the degradative capacity of white-rot fungi merits attention. 相似文献
93.
Salomao O.Bandeira Rui Paula e Silva Jose Paula Adriano Macia Lars Hernroth Almeida T.Guissamulo 《Ambio-人类环境杂志》2002,31(8)
本文概述了莫桑比克包括渔业在内的海洋生物学研究的发展情况.莫桑比克的海岸线约为3000km,海洋的生物资源在莫桑比克的社会中起着重要的作用,主要是作为人们的蛋白质来源以及收入和出口创汇的来源. 相似文献
94.
Suvi Monni Paula Perälä Kristiina Regina 《Mitigation and Adaptation Strategies for Global Change》2007,12(4):545-571
According to the United Nations Framework Convention on Climate Change (UNFCCC) and Kyoto Protocol under it, industrial countries
have to estimate their greenhouse gas emissions annually, and assess the uncertainties in these estimates. In Finland, agricultural
methane (CH4) and nitrous oxide (N2O) emissions represent 7% of anthropogenic greenhouse gas emissions, and globally the share is much higher. Agriculture is
one of the most uncertain emission categories (representing over 20% of greenhouse gas inventory uncertainty in Finland),
due to both high natural variability of the emission sources and poor knowledge of the emission-generating processes. In this
paper, we present an uncertainty estimate of agricultural CH4 and N2O emissions from Finland in 2002. Uncertainties were estimated based on measurement data, literature and expert judgement,
and total uncertainty in agriculture was calculated using Monte Carlo simulation. According to the calculations, agricultural
CH4 and N2O emissions from Finland were 3.7 to 7.8 Tg carbon dioxide (CO2) equivalents, 5.4 Tg being the mean value.Estimates of CH4 emissions are more reliable than those of N2O. N2O from agricultural soils was the most uncertain emission category, and the uncertainty was not reduced by using available
national measurement data of N2O fluxes. Sensitivity study revealed that the uncertainty in total agricultural inventory could be 7% points lower, if more
accurate emission estimation methods were used, including 1) improved data collection in area estimates of organic soils,
2) climate-specific methods for N2O from agricultural soils as already presented in literature, and 3) more detailed CH4 estimation methods for enteric fermentation which can be achieved by investigating national circumstances and digestible
systems of animals in more detail. 相似文献
95.
Olivier Maire Jean-Michel Amouroux Jean-Claude Duchêne Antoine Grémare 《Marine Biology》2007,152(6):1293-1307
The filtration activity of the Mediterranean mussel, Mytilus galloprovincialis, was assessed under different concentrations and compositions of seston by using a new automated image acquisition and analysis
system. This approach allowed for frequent and simultaneous measurements of valve gape and exhalant siphon area. Filtration
rates were measured through clearance measurements whereas pumping rates were measured using hot-film probes. The average
filtration rate (17.5 l g h−1 DW−1 for a 0.36 g DW mussel) recorded during the present study was higher than those available for Mytilus edulis when standardized to flesh dry weight but almost equivalent (17.5 l h−1 g DW−1 for a 53 mm shell length mussel) to those rates when standardized to shell length. Immediately after the addition of algal
cells (Isochrysis galbana; 4.5 μm in size), valve gape, exhalant siphon area and filtration rate increased quickly as mussels reached their maximum
filtration activity. These three parameters then gradually decreased until complete closure of the shell. The algal cell concentration
inducing this transition was close to 800 cells ml−1 and 0.5 μg Chl a l−1. When algal concentration was maintained above this threshold by successive algal additions, both valve gape and exhalant
siphon area remained maximal. Temporal changes in the exhalant siphon area were continuous as opposed to those of valve gape.
Therefore, despite the significant correlation between these two parameters, valves and siphon were sometimes dissociated
due to a reduction of the area or even a closure of the exhalant siphon while the valves remained open. The velocity of exhaled
water tended to be constant irrespective of exhalant siphon area and thus pumping rates were a linear function of exhalant
siphon area. Consequently, reductions in exhalant siphon area and pumping rate were almost similar in M. galloprovincialis. Our results thus clearly support the hypothesis that exhalant siphon area constitutes a better proxy of pumping rate than
valve gape as already suggested for Mytilus edulis. Finally, the high filtration rates measured during the present study together with the high concentrations of inorganic
matter (> 40 mg DW l−1) requested to alter those rates suggest that the studied mussels were well adapted to oligotrophic waters featuring strong
hydrodynamism and frequent sediment resuspension events. 相似文献
96.
In the routine São Paulo state (Brazil) surface water quality-monitoring program, which includes the Salmonella microsome mutagenicity assay as one of its parameters, a river where water is taken and treated for drinking water purposes has repeatedly shown mutagenic activity. A textile dyeing facility employing azo-type dyes was the only identifiable source of mutagenic compounds. We extracted the river and drinking water samples with XAD4 at neutral and acidic pH and with blue rayon, which selectively adsorbs polycyclic compounds. We tested the industrial effluent, raw, and treated water and sediment samples with YG1041 and YG1042 and compared the results with the TA98 and TA100 strains. The elevated mutagenicity detected with YG-strains suggested that nitroaromatics and/or aromatic amines were causing the mutagenicity detected in the samples analyzed. Positive responses for the blue rayon extracts indicated that mutagenic polycyclic compounds were present in the water samples analyzed. The mutagen or mixture of mutagens present in the effluent and water samples cause mainly frameshift mutations and are positive with and without metabolic activation. The Salmonella assay combined with different extraction procedures proved to be very useful in the identification of the origin of the pollution and in the identification of the classes of chemical compounds causing the mutagenic activity in the river analyzed. 相似文献
97.
Survey of organotin compounds in rivers and coastal environments in Portugal 1999-2000 总被引:1,自引:0,他引:1
Díez S Lacorte S Viana P Barceló D Bayona JM 《Environmental pollution (Barking, Essex : 1987)》2005,136(3):525-536
In the period from April 1999 to May 2000, organotin pollution, namely butyl and phenyltins, was investigated in coastal and continental waters (46 stations), estuarine sediments (15 stations) and mussels (Mytilus galloprovincialis) (13 stations) throughout Portugal. Sampling points were chosen in areas of specific industrial, agricultural and harbor activities. Butyltins (BTs) were the only tin species identified of which tributyltin (TBT) was found in the whole area. Concentrations of TBT in river water ranged from 3 to 30 ng L(-1) (as Sn), marine sediment ranged from 4 to 12 microg kg(-1) (as Sn), whereas concentrations in mussel tissue ranged from 2.5 to 490 microg kg(-1) (as Sn). Given that some water samples appeared to be contaminated by higher monobutyltin (MBT) and dibutyltin (DBT) concentrations, the role of biological degradation and direct inputs from agricultural and industrial applications areas are discussed. The study compares depleted butyltin pollution in sediments and mussels of the Portuguese coastline associated with antifouling paints with previously reported levels. Inputs in river waters are more related to (i) PVC leaching and (ii) industrial sources, in some cases discharged by municipal wastewaters. 相似文献
98.
Inês D S Henriques Richard T Kelly Jennifer L Dauphinais Nancy G Love 《Water environment research》2007,79(9):940-951
The effects of shock loads of 1-chloro-2,4-dinitrobenzene (CDNB); cadmium; 1-octanol; 2,4-dinitrophenol (DNP); weakly complexed cyanide; pH 5, 9, and 11; and high ammonia levels on activated sludge biomass growth, respiration rate, flocculation, chemical oxygen demand removal, dewaterability, and settleability were studied. For all chemical shocks, except ammonia and pH, concentrations that caused 15, 25, and 50% respiration inhibition were used to provide a single pulse shock to sequencing batch reactor systems containing a nitrifying or non-nitrifying biomass. Cadmium and pH 11 shocks were most detrimental to all processes, followed by CDNB. The DNP and cyanide primarily affected respiration, while pH 5, pH 9, octanol, and ammonia did not affect the treatment process to a significant extent. A chemical source-process effect matrix is provided, which we believe will aid in the development of methods that prevent and/or attenuate the effects of toxic shock loads on activated sludge systems. 相似文献
99.
Owen Douglas Paula Russell Mark Scott 《Journal of Environmental Planning and Management》2019,62(4):626-646
The provision of green and open space in the face of wider development pressure is a key urban challenge. Despite this, few studies have critically investigated the quality of life implications of such provision. This paper focuses on perceptions of built environment factors and their influence on neighbourhood quality of life. Data are drawn from a household survey questionnaire completed by 483 residents living in three neighbourhoods in Dublin, Ireland – an inner city neighbourhood, a suburb and a peri-urban settlement. Positive perceptions of green and open space were identified as important predictors of high levels of neighbourhood satisfaction, surpassed only by dwelling characteristics. This suggests that development strategies which fail to provide for properly planned green and open spaces may be detrimental to neighbourhood quality of life. Furthermore, the results suggest a need for design solutions which consider neighbourhood typology in achieving improved neighbourhood quality of life. 相似文献
100.