Mixed models for assessing correlation in the presence of replication

The need to assess correlation in settings where multiple measurements are available on each of the variables of interest often arises in environmental science. However, this topic is not covered in introductory statistics texts. Although several ad hoc approaches can be used, they can easily lead to invalid conclusions and to a difficult choice of an appropriate measure of the correlation. Lam et al. approached this problem by using maximum likelihood estimation in cases where the replicate measurements are linked over time, but the method requires specialized software. We reanalyze the data of Lam et al. using PROC MIXED in SAS and show how to obtain the parameter estimates of interest with just a few lines of code. We then extend Lam et al.'s method to settings where the replicate measurements are not linked. Analysis of the unlinked case is illustrated with data from a study designed to assess correlations between indoor and outdoor measurements of benzene concentration in the air.     

County‐Scale Rainwater Harvesting Feasibility in the United States: Climate,Collection Area,Density, and Reuse Considerations

Roof rainwater harvesting (RWH) has the potential to augment water supplies for urban and suburban uses throughout the United States (U.S.). Studies of the performance of RWH at the building and city scales in the U.S. are available, but a countrywide overview of the potential performance of RWH at the county scale has not been done before. Three approaches were taken: (1) assess the viability of RWH in terms of the rainfall that could be captured in relation to the water demand in each county (excluding agriculture), (2) evaluate the performance of a “typical” domestic RWH system across all counties with metrics related to its ability to supply the potable and nonpotable demand, and (3) evaluate the effect of adding a 50% rainwater reuse component to the analysis. We find RWH could be a viable supplemental water source in the U.S., particularly in counties of the Pacific Northwest, Central, and Eastern regions (percent demand covered >50%). Low population density counties have the potential to meet their annual water needs with RWH, while high‐density counties could only source a small portion (~20%) of their annual demand with RWH. Typical RWH systems in counties in the Central and Eastern U.S. performed better than in Western counties. Adding a reuse component can be a key factor in making RWH attractive in many areas of the country. This work can inform future water infrastructure investment and planning in the U.S.     

The Gravikinetic Response of Paramecium is Based on Orientation-Dependent Mechanotransduction

  Paramecium generates persistent shifts of the membrane potential of a few millivolts depending on its orientation with respect to the gravity vector. The resulting potential-induced modulation of the speed of propulsion is called gravikinesis because it acts to neutralize, fully or in part, sedimentation. Gravisensitivity is maximal at neutral orientation, i.e., in horizontally swimming cells, when the gravitational force per unit membrane area is at minimum. Stimulus-response relationships and energetic considerations show that sensing of the gravity vector by a nonspecialized, single-cell organism ranks among the most sensitive mechanoreceptors known in nature. Received: 15 December 1998 / Accepted: 18 February 1999     

An analysis of the dust deposition on solar photovoltaic modules

Environmental Science and Pollution Research - Solid particles impair the performance of the photovoltaic (PV) modules. This results in power losses which lower the efficiency of the system as well...     

A City Wide Assessment of the Financial Benefits of Rainwater Harvesting in Mexico City

We assess the potential financial benefits of rooftop rainwater harvesting (RWH) in Mexico City from the perspective of property owners and entrepreneurs. A bottom‐up approach was followed by evaluating RWH at individual buildings and aggregating the results to a borough/city level. We consider sector‐specific water demands, potable and nonpotable uses, and user‐specific water tariffs. We find that RWH is economically most beneficial for nondomestic users rather than for small domestic users, who are often the target of RWH interventions. Based on a net present value analysis, a potable RWH system is not favored for most domestic users under the current subsidized municipal water tariff structure. Our analysis only considers capital and maintenance expenses, and not other benefits related to increased access to water and reliability, or social benefits from a switch to a RWH system. If the initial capital expense for RWH is partly financed by transferring the water subsidy to an entrepreneur, then RWH becomes financially attractive for a wide range of domestic users. To improve water access in Mexico City, RWH is attractive in the most marginalized boroughs where water use is currently lower and precipitation is higher. For domestic users relying on trucked water, RWH can have great financial benefits. Our approach provides quantitative data with high spatial specificity, highlighting the places and types of users that would benefit most from RWH.     

Ecotoxicological sediment evaluations in marine aquaculture areas of Chile

Given its geographic characteristics, the southern Chilean fjord area is subjected to growing environmental pressure from the development of diverse forms of aquaculture (i.e., fish, algae, shellfish). The sediments accumulate substances as a natural sink, and ecotoxicology assays offer a reliable and robust proxy for sediment quality analyses. This study's objective was to establish a mid-range toxicity base line for the sediments in the region by applying a battery of non-specific ecotoxicological assays. Sediment samples (28) were collected in the channels and fjords studied during the CIMAR-Fiordos 11 cruise (July 2005). The sediments were evaluated using different species endemic to the eastern Pacific as targets: Ampelisca araucana, Tisbe longicornis, Arbacia spatuligera, and Dunaliella tertiolecta. The conditions for each assay were reported previously. Of the four species used as ecotoxicological tools, only D. tertiolecta differed significantly from the control group (negative) in terms of its growth. This difference could be attributed to nutrient enrichment. In general, we concluded that, although local changes occurred in the sediments, the mesoscale magnitude of the ecotoxicological alterations was small. Nonetheless, a surveillance program should be implemented that would allow us to follow-up and analyze the changes that are taking place in the systems on broader scales of time and space.     

Involvement of siderophores in the reduction of metal-induced inhibition of auxin synthesis in Streptomyces spp

Unlike synthetic metal chelators, microbe-assisted phytoremediation provides plants with natural metal-solubilizing chelators which do not constitute a potential source of environmental pollution. Concurrently with microbial chelators, plant growth promotion can be enhanced through bacterially-produced phytohormones. In this work, the simultaneous production of siderophores and auxins by Streptomyces was studied to gain insight for future application in plant growth and phytoremediation in a metal-contaminated soil. Standard auxin and siderophore detection assays indicated that all of the investigated Streptomyces strains can produce these metabolites simultaneously. However, Al(3+), Cd(2+), Cu(2+), Fe(3+) and Ni(2+), or a combination of Fe(3+) and Cd(2+), and Fe(3+) and Ni(2+) affected auxin production negatively, as revealed by spectrophotometry and gas chromatography-mass spectrometry. This effect was more dramatic in a siderophore-deficient mutant. In contrast, except for Fe, all the metals stimulated siderophore production. Mass spectrometry showed that siderophore and auxin-containing supernatants from a representative Streptomyces species contain three different hydroxamate siderophores, revealing the individual binding responses of these siderophores to Cd(2+) and Ni(2+), and thus, showing their auxin-stimulating effects. We conclude that siderophores promote auxin synthesis in the presence of Al(3+), Cd(2+), Cu(2+) and Ni(2+) by chelating these metals. Chelation makes the metals less able to inhibit the synthesis of auxins, and potentially increases the plant growth-promoting effects of auxins, which in turn enhances the phytoremediation potential of plants.     

Biochemical and genotoxic effects in women exposed to pesticides in Southern Ecuador

Environmental Science and Pollution Research - Toxicity refers to the potential of a substance such as a pesticide to cause damage to the structure or functions of an exposed organism. Pesticides...