全文获取类型
收费全文 | 3604篇 |
免费 | 30篇 |
国内免费 | 10篇 |
专业分类
安全科学 | 64篇 |
废物处理 | 245篇 |
环保管理 | 266篇 |
综合类 | 387篇 |
基础理论 | 737篇 |
环境理论 | 7篇 |
污染及防治 | 1352篇 |
评价与监测 | 333篇 |
社会与环境 | 243篇 |
灾害及防治 | 10篇 |
出版年
2023年 | 45篇 |
2022年 | 98篇 |
2021年 | 145篇 |
2020年 | 59篇 |
2019年 | 59篇 |
2018年 | 134篇 |
2017年 | 136篇 |
2016年 | 200篇 |
2015年 | 107篇 |
2014年 | 221篇 |
2013年 | 337篇 |
2012年 | 251篇 |
2011年 | 255篇 |
2010年 | 200篇 |
2009年 | 142篇 |
2008年 | 201篇 |
2007年 | 232篇 |
2006年 | 168篇 |
2005年 | 142篇 |
2004年 | 103篇 |
2003年 | 84篇 |
2002年 | 79篇 |
2001年 | 46篇 |
2000年 | 38篇 |
1999年 | 23篇 |
1998年 | 12篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 14篇 |
1994年 | 8篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1988年 | 2篇 |
1985年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1970年 | 2篇 |
1967年 | 5篇 |
1966年 | 5篇 |
1965年 | 2篇 |
1964年 | 5篇 |
1962年 | 3篇 |
1959年 | 4篇 |
1958年 | 15篇 |
1957年 | 5篇 |
1955年 | 2篇 |
1928年 | 1篇 |
1922年 | 1篇 |
排序方式: 共有3644条查询结果,搜索用时 15 毫秒
751.
This work is focused on the deep catalytic oxidation of methane over supported palladium catalysts. The influences of the metal loading, oxidation state of palladium, nature of supports, presence of promoters in the supports (for zirconia-based supports), and thermal stability have been studied experimentally. Catalysts were prepared by incipient wetness of commercially available supports with aqueous solutions of palladium nitrate. For gamma-alumina support, it was observed that the optimal amount of palladium is between 0.5% and 2%, with higher amounts leading to a loss in specific activity. Concerning the oxidation state of the catalyst, it is concluded that for all the supports tested in the present work, a reduction of the catalyst is not needed, yielding the same conversion at steady state catalysts reduced and oxidised. The thermal stability of various supported catalysts were also studied, zirconia supports being the most active. These supports, specially Y-modified zirconia support, do not suffer appreciable deactivation below 500 degrees C. 相似文献
752.
M. D. Vazquez-Illanes R. Barcia I. Ibarguren J. A. Villamarín J. I. Ramos-Martínez 《Marine Biology》1992,112(2):277-281
6-phosphofructo-2-kinase (PFK-2) from the mantle of the sea musselMytilus galloprovincialis Lmk, collected from the Ría de Arosa (NW Spain) in 1990, was purified 550-fold by extraction and sequential affinity chromatography on Affi-gel Blue and ATP-agarose columns. The enzyme was a dimer with a native molecular weight of 100 kilodaltons (KDa) and a subunitM
r of 53 KDa. PFK-2 activity is dependent on the presence of Pi. At physiological Pi concentrations, the enzyme exhibits hyperbolic kinetics with both ATP and Fru-6-P, withK
m values of 0.62 and 0.37 mM respectively. In vivo, PFK-2 activity is limited by the concentration of Fru-6-P which is low in comparison with theK
m for this substrate. Citrate and PEP inhibited PFK-2 activity. 相似文献
753.
M. Matucha M. Gryndler S. T. Forczek H. Uhlířová K. Fuksová P. Schröder 《Environmental Chemistry Letters》2003,1(2):127-130
The fate of chloroacetic acids (CAA) in forest soils was studied using radio-indicator methods. We showed that chloroacetic acids are both microbially degraded and simultaneously formed by chloroperoxidase-mediated chlorination of acetic and humic acids. The degree of biodegradation of chloroacetic acids in soil depends on their concentration. Dichloroacetic acid (DCA) is degraded faster than trichloroacetic acid (TCA). Chlorination of acetic acid led to a fast formation of dichloroacetic acid, whereas chlorination of humic acids gave rise to trichloroacetic acid. Both processes lead to a steady state in soil, participate in the chlorine cycle and possibly also in decomposition of organic matter in forest ecosystems. 相似文献
754.
Copulatory plugs do not assure high first male fertilisation success: sperm displacement in a lizard
Pedro L. Moreira Vera L. Nunes José Martín Octávio S. Paulo 《Behavioral ecology and sociobiology》2007,62(2):281-288
Sperm competition selects for opposing male defensive and offensive reproductive traits, and its outcome may be determined
by the effectiveness to which one trait has evolved to out-compete the other. We tested the effectiveness of a first male
plug physical interference with a second male insemination (defence) vs the effectiveness of plug and associated sperm displacement
by a second male (offence) on the outcome of sperm competition in Iberian rock lizards. We conducted a double mating experiment
where we compared the proportion of eggs per clutch fertilised by the same second males (against the same first males) when
they copulated with females 30 min (first male plug adhered firmly inside the female cloaca) and 4 h (first male plug loosely
adhered or shed from the female cloaca) after first males. We found that second males fertilised the majority of the eggs
per clutch in the 30-min treatment, whereas fertilisations were equally shared between the two males in the 4-h treatment.
These results show that plugs have little defensive effectiveness, and thus, do not assure high first male fertilisation success.
Instead, sperm displacement appears to be associated with plug displacement. That is, because sperm embedded in first male
plugs, and displaced from competition for fertilisations by second males, is expected to increase in number with decreasing
time allowed for female sperm transport, second males thus enjoy higher fertilisation success. This study shows that offensive
plug displacement out-competes plug defensive role in Iberian rock lizards. Moreover, it reveals sperm displacement as a novel
sperm competition mechanism in reptiles. 相似文献
755.
J.?MartínEmail author P.?López W.?E.?CooperJr. 《Behavioral ecology and sociobiology》2003,54(5):505-510
Because time spent in refuge may be costly if prey lose opportunities to forage, fight, or mate, prey allow predators to approach closer before beginning to flee when opportunity costs are high. Because the same opportunity costs may apply to refuge use as to escape, prey should make similar trade-offs between risk of emerging and cost of remaining in refuge. In the Iberian rock lizard, Lacerta monticola, we studied the effects of sex, reproductive season, speed of predator approach, and potential loss of mating opportunities on time spent in refuge following simulated predatory attacks. Lizards of both sexes adjusted refuge use to the level of risk by spending more time in refuge when approached rapidly than slowly. Females remained in refuge for equal times in the mating and postreproductive seasons, but males emerged sooner during the mating season, suggesting adjustment to a cost of lost opportunity to search for mates during the mating season. When a tethered female was nearby, males emerged from refuge earlier than if no female was present, indicating a trade-off between risk and mating opportunity. Approach speed affected emergence time when females were absent, but not when a female was present. Approach speed did not affect the probability that, after emerging, a male would return to court the female. For males that courted females intensely (bit them) before entering refuge, approach speed did not affect latency to emerge, but males that courted less intensely emerged sooner if approached slowly than rapidly. These findings show that males adjust the length of time spent in refuge to both risk of predation and reproductive cost of refuge use.Communicated by A. Mathis 相似文献
756.
Female preference for dominant males is widespread and it is generally assumed that success in male-male competition reflects high quality. However, male dominance is not always attractive to females. Alternatively, relatively symmetric individuals may experience fitness advantages, but it remains to be determined whether males with more symmetrical secondary sexual traits experience advantages in both intra- and intersexual selection. We analysed the factors that determine dominance status in males of the lizard Lacerta monticola, and their relationship to female mate preference, estimated by the attractiveness of males' scents to females. Sexually dimorphic traits of this lizard (head size and femoral pores) appear to be advanced by different selection pressures. Males with relatively higher heads, which give them advantage in intrasexual contests, were more dominant. However, head size was unimportant to females, which preferred to be in areas marked by relatively heavier males, but also by males more symmetric in their counts of left and right femoral pores. Chemicals arising from the femoral pores and other glands might honestly indicate quality (i.e. related to the symmetry levels) of a male to females and may result from intersexual selection. Females may use this information because the only benefit of mate choice to female lizards may be genetic quality. Chemical signals may be more reliable and have a greater importance in sexual selection processes of lizards than has previously been considered. 相似文献
757.
Carlos Díaz-Avalos Celia Bulit David J. S. Montagnes 《Environmental and Ecological Statistics》2006,13(2):163-181
Planktonic patches are defined as areas where the abundance of plankters is above a threshold value τ. The estimation of patch
size and shape can be approached using spatial statistical tools, using truncated random fields or indicator random fields
as classifiers. In all cases there is the risk of false positive and false negative errors. In this paper we present the results
of a comparative study on the performance of four commonly used methods: conditional simulation and kriging, both in the original
measurement units of the data and under an indicator transform. We used a misclassification cost function to compare the four
methods. Our results show that conditional simulation in the original measurement units attains the lowest misclassification
cost. We also illustrate how the point at which this minimum is attained can be used to chose an optimal cut-off value for
binary classification.
Received: December 2003 / Revised: June 2005 相似文献
758.
Alejandra Valero Robyn Hudson Edgar Ávila Luna Constantino Macías Garcia 《Behavioral ecology and sociobiology》2005,59(2):262-269
When approached by males, females of the Amarillo fish (Girardinichthys multiradiatus) perform a behaviour called vibration or they are aggressively challenged. We quantified vibration and assessed whether it compromises the rate of feeding attempts in dyads kept in outdoor enclosures. Male approaches resulted in female vibration and in a reduced feeding rate. Vibration was not evoked by female–female aggression, which was frequent and always ended in the subordinate fleeing from the dominant female. Using a closed respirometer we found that vibration is costly; oxygen consumption of females was greater in the presence of a male (which evoked vibration) than in the presence of a non-familiar female (when no vibration occurred). By recording interactions of females confined in aquaria in the presence and in the absence of males, we confirmed that escaping is the only available response to deal with female aggression. Females kept without males participated in frequent aggressive (even lethal) interactions that did not abate while the subordinate female was in sight of the dominant, and which caused premature births and injuries. Yet in the alternative treatment aggression ceased when a male approached, prompting vibration in both females. Thus, in the Amarillo, in as much as it evokes energetically costly female vibrations, male courtship is an expression of sexual conflict. However, in the absence of males, frequent female aggression potentially annuls the benefits of not vibrating. We propose that a complete appraisal of the consequences of sexual conflict must include an assessment of the costs imposed by intra-sexual interactions. 相似文献
759.
Control of reproduction in social insect colonies: individual and collective relatedness preferences in the paper wasp, Polistes annularis 总被引:1,自引:0,他引:1
David C. Queller J. M. Peters Carlos R. Solís Joan E. Strassmann 《Behavioral ecology and sociobiology》1997,40(1):3-16
Social insect colonies often have one or a few queens. How these queens maintain their reproductive monopoly, when other
colony members could gain by sharing in the reproduction, is not generally known. DNA microsatellite genotyping is used to
determine reproductive interests of various classes of colony members in the paper wasp, Polistes annularis. The relatedness estimates show that the best outcome for most individuals is to be the reproductive egg-layer. For workers,
this depends on the sex of offspring: they should prefer to lay their own male eggs, but are indifferent if the queen lays
the female eggs. The next-best choice is usually to support the current queen. As a rule, subordinates and workers should
prefer the current queen to reproduce over other candidates (though subordinates have no strong preference for the queen over
other subordinates, and workers may prefer other workers as a source of male eggs). This result supports the theory that reproductive
monopoly stems from the collective preferences of non-reproductives, who suppress each other in favor of the queen. However,
we reject the general hypothesis of collective worker control in this species because its predictions about who should succeed
after the death of the present queen are not upheld. The first successor is a subordinate foundress even though workers should
generally prefer a worker successor. If all foundresses have died, an older worker succeeds as queen, in spite of a collective
worker preference for a young worker. The results support the previous suggestion that age serves as a conventional cue serving
to reduce conflict over queen succession.
Received: 3 May 1996 / Accepted after revision: 22 September 1996 相似文献
760.
Reynaldo Mauricio Rodríguez Amaya Sandra Milena Becerra Pinto 《International journal of occupational safety and ergonomics》2016,22(1):152-158
Objective. The objective of this study was to learn about the health and safety strategies in a sample of taxi drivers in Bucaramanga, Colombia. Methods. A cross-sectional study was conducted among 138 taxi drivers. A survey was used to identify the socio-demographic and working characteristics, knowledge, attitudes and practices according to their occupational risk. Results. Eighty-five percent of the workers labored 9–15?h/day. Of those who suffered accidents, 27% were not affiliated to an occupational risk administrator (p = 0.028). Of the workers who had a work-related accident, 58% considered that the use of a cell phone while driving would not always reduce their attention, 50% always used their seat belt and 7% took active breaks and wore their seat belt (p = 0.01). Conclusions. Within this group of taxi drivers, having or believing to possess knowledge regarding an occupational risk did not ensure that they had a safe attitude or safe working practices. 相似文献