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641.
Arturo Torres-Dosal Rebeca Isabel Martinez-Salinas Diego Hernandez-Benavides Francisco Javier Perez-Vazquez Cesar Ilizaliturri-Hernandez Ivan Nelinho Perez-Maldonado 《Environmental monitoring and assessment》2012,184(12):7551-7559
In Mexico, 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) was used until the year 2000, principally in agriculture and anti-paludal program health campaigns. The southeastern region of Mexico was an important area of malaria, and from 1957 DDT was applied indoors every 6?months, with a coverage of 2?g/m2. The current study was performed in Tabasco, a Mexican state located in the southeastern region of Mexico. DDT and 1,1-dichloro-2,2-bis(4-chlorophenyl)ethene (DDE) were analyzed by gas chromatography/mass spectrometry. In general, low levels were found in household outdoor samples; the levels of DDT ranged from not detectable to 0.048?mg/kg, and of DDE from 0.001 to 0.068?mg/kg. An important finding was that, in all communities where DDT in blood was analyzed, exposure to DDT was found, indicating both past and present exposure. Although the levels found in this study were lower than other studies in Mexico, there is a need to evaluate whether the people living in the study area are at risk. 相似文献
642.
Orellana FA Alegre JM Cordero Pérez JC Martín Redondo MP Delgado Huertas A Fernández Sampedro MT Menor-Salván C Ruiz-Bermejo M López-Vera F Rodríguez-Losada JA Martinez-Frias J 《Journal of environmental monitoring : JEM》2008,10(4):570-574
Certain local atmospheric anomalies, such as the formation of unusually large ice conglomerations (megacryometeors), have been proposed to be a potential natural hazard for people and aviation, as well as geoindicators for fingerprinting larger-scale atmospheric environmental changes. On March 13th 2007, at approximately 10:15 am, an ice chunk weighing about 10 kg fell from the clear-sky and crashed through the roof (around 15 m) of an industrial storage house in Mejorada del Campo, a town located 20 km east from Madrid. The megacryometeor monitoring follow-up and the original investigation presented here includes, for the first time, both logistic and scientific collaboration between the Laboratory of the Environment, Criminalistic Service (SECRIM, the Spanish "Guardia Civil") and academic and scientific institutions (universities and the Spanish National Research Council). We propose that the management procedure of the incident, along with the detailed scientific research and combination of analytical methodologies in different laboratories, can serve as a protocol model for other similar events. 相似文献
643.
644.
Flores P Lacasa A Fernández P Hellín P Fenoll J 《Journal of environmental science and health. Part. B》2008,43(6):513-518
A greenhouse study was conducted to evaluate the effect of biofumigation (with sheep and chicken manure) combined with solarization on the dissipation of pesticides (pyrifenox, DDT and dieldrin), and on soil metals accumulation. The treatments consisted of a control, and soil disinfestations by biofumigation combined with solarization (B+S) for two, four, five, six consecutive years. B+S enhanced the dissipation of pyrifenox with regard to control treatment. Significant differences were not detected among plots disinfected with B+S for consecutive years. On the other hand, B+S had no effect on the dissipation of DDT and dieldrin, probably due to the resistance of these pesticides to microbial degradation and/or high temperatures. Biofumigation is considered to be an environmentally safe practice, since no accumulation of heavy metals such as Cd, Co, Cu, Cr, Pb, Ni, or Zn was observed after the subsequent application of organic matter through the treatments. 相似文献
645.
Non-controlled biogenic emissions to the atmosphere from Lazareto landfill, Tenerife, Canary Islands 总被引:3,自引:1,他引:2
Nolasco D Lima RN Hernández PA Pérez NM 《Environmental science and pollution research international》2008,15(1):51-60
GOAL, SCOPE AND BACKGROUND: [corrected] Historically, landfills have been the simplest form of eliminating urban solid waste with the minimum cost. They have been the most usual method for discarding solid waste. However, landfills are considered authentic biochemical reactors that introduce large amounts of contaminants into the environment in the form of gas and leachates. The dynamics of generation and the movement of gas in landfills depend on the input and output parameters, as well as on the structure of the landfill and the kind of waste. The input parameters include water introduced through natural or artificial processes, the characteristics of the urban solid waste, and the input of atmospheric air. The main output parameters for these biochemical reactors include the gases and the leachates that are potentially pollutants for the environment. Control systems are designed and installed to minimize the impact on the environment. However, these systems are not perfect and a significant amount of landfill gas could be released to the atmosphere through the surface in a diffuse form, also known as Non-controlled emission. In this paper, the results of the Non-controlled biogenic gas emissions from the Lazareto landfill in Tenerife, Canary Islands, are presented. The purpose of this study was to evaluate the concentration of CH4 and CO2 in the soil gas of the landfill cover, the CH4 and CO2 efflux from the surface of the landfill and, finally, to compare these parameters with other similar landfills. In this way, a better understanding of the process that controls biogenic gas emissions in landfills is expected. METHODS: A Non-controlled biogenic gas emission survey of 281 sampling sites was carried out during February and March, 2002. The sampling sites were selected in order to obtain a well-distributed sampling grid. Surface landfill CO2 efflux measurements were carried out at each sampling site on the surface landfill together with soil gas collection and ground temperatures at a depth of 30-40 cm.The CH4 efflux was computed from CO2 efflux and from the ratio CH4/CO2 in the soil gas. Soil gas samples were collected at a depth of 30-40 cm using a metallic probe and 20 cc hypodermic syringes, and later stored in evacuated 10 cc vacutainers for laboratory analysis of bulk composition. The gas sample was introduced in a vacutainer filled with deionized water and displacing the water until the vacutainer was filled with the gas sample in order to avoid air contamination from entering. The surface landfill temperature of the landfill was measured at a depth of 40 cm using a digital thermometer type OMEGA 871A. Landfill gases, CO2 and CH4, were analyzed within 24 hours using a double channel VARIAN micro-GC QUAD CP-2002P, with a 10 meter PORAPLOT-Q column, a TCD detector, and He as a carrier gas. The analysis temperature was 40 degrees C and the injection time was 10 msec. Surface landfill CO2 efflux measurements were performed using a portable NDIR spectrophotometer Licor-800 according to the accumulation chamber method (Chiodini et al. 1996). The data treatment, aimed at drawing the flux map and computing the total gas output, was based on the application of stochastic simulation algorithms provided by the GSLIB program (Deutsch and Journel 1998). RESULTS: Diffuse CH4 and CO2 efflux values range from negligible values up to 7,148 and 30,573 g m(-2) d(-1), respectively. The spatial distribution of the concentration and efflux of CO2, CH4 and soil temperature, show three areas of maximum activity in the landfill, suggesting a non-uniform pattern of diffuse degassing. This correlation between high emissions and concentration of CO2, CH4 and soil temperatures suggests that the areas of higher microbial activity and exothermic reactions are releasing CO2 and CH4 to the atmosphere from the landfill. Taking into consideration the spatial distribution of the CO2 and CH4 efflux values as well as the extension of the landfill, the Non-controlled emission of CO2 and CH4 to the atmosphere by the Lazareto's landfill are of 167 +/- 13.3 and 16 +/- 2.5 t d(-1), respectively. DISCUSSION: The patterns of gas flow within the landfill seem to be affected by boundary materials at the sides. The basalt layers have a low permeability and the gas flow in these areas is extensive. In this area, where a basalt layer does not exist, the flow gas diffuses toward the sea and the flux emissions at the landfill surface are lower. This behavior reflects the possible dissolution of gases into water and the deflection of gases towards the surface at the basalt boundary. The proximity to the sea, the installation of a palm tree garden and, as a result, the contribution of water coming from the watering of this garden has reactivated the system. The introduction of sea water into the landfill and the type of boundary could be defining the superficial gas discharges. CONCLUSIONS: Results from this study indicate that the spatial distribution of Non-controlled emission of CO2 and CH4 at the Lazareto's landfill shows a non-uniform pattern of diffuse degassing. The northeast, central and northwest areas of the Lazareto's landfill are the three areas of high emissions and concentration of CO2 and CH4, and high temperatures. The correlation between high emissions and the concentration of CO2, CH4, and the high temperatures suggest that the areas of higher microbial activity and exothermic reactions are releasing more CO2 and CH4 to the atmosphere from the landfill. A high concentration of CO2 is probably due to the presence of methanotrophic bacteria in the soil atmosphere of the landfill. Patterns of gas flow within the landfill seem to be affected by boundary materials (basalt layers) of low permeability, and side boundaries of the flux emissions at the surface are higher. At the sides of seawater and sediment boundaries, flux emissions at the landfill surface are lower. This behavior reflects a possible dissolution of gases into the water and the deflection of gases towards the surface at the basalt boundary. With this study, we can compare the data obtained in this landfill with other landfills and observe the different levels of emission. The proximity to the sea and the installation of the palm tree garden palms and, as a result, the contribution of water coming from the watering of this garden has reactivated the system. Many landfills worldwide located in similar settings could experience similar gas production processes. RECOMMENDATIONS AND PERSPECTIVES: The need for investigating and monitoring sea water and sediment quality in these landfills is advisable. Concentrations and fluxes of contaminants and their impact in the area should be assessed. With this study we can compare the data obtained in these landfills with other landfills and observe the different levels of emission. 相似文献
646.
Nagler PL Glenn EP Hinojosa-Huerta O Zamora F Howard K 《Journal of environmental management》2008,88(4):864-874
Like other great desert rivers, the Colorado River in the United States and Mexico is highly regulated to provide water for human use. No water is officially allotted to support the natural ecosystems in the delta of the river in Mexico. However, precipitation is inherently variable in this watershed, and from 1981-2004, 15% of the mean annual flow of the Lower Colorado River has entered the riparian corridor below the last diversion point for water in Mexico. These flows include flood releases from US dams and much smaller administrative spills released back to the river from irrigators in the US and Mexico. These flows have germinated new cohorts of native cottonwood and willow trees and have established an active aquatic ecosystem in the riparian corridor in Mexico. We used ground and remote-sensing methods to determine the composition and fractional cover of the vegetation in the riparian corridor, its annual water consumption, and the sources of water that support the ecosystem. The study covered the period 2000-2004, a flood year followed by 4 dry years. The riparian corridor occupies 30,000ha between flood control levees in Mexico. Annual evapotranspiration (ET), estimated by Moderate Resolution Imaging Spectrometer (MODIS) satellite imagery calibrated against moisture flux tower data, was about 1.1myr(-1) and was fairly constant throughout the study period despite a paucity of surface flows 2001-2004. Total ET averaged 3.4x10(8)m(3)yr(-1), about 15% of Colorado River water entering Mexico from the US Surface flows could have played only a small part in supporting these high ET losses. We conclude that the riparian ET is supported mainly by the shallow regional aquifer, derived from agricultural return flows, that approaches the surface in the riparian zone. Nevertheless, surface flows are important in germinating cohorts of native trees, in washing salts from the soil and aquifer, and in providing aquatic habitat, thereby enriching the habitat value of the riparian corridor for birds and other wildlife. Conservation and water management strategies to enhance the delta habitats are discussed in light of the findings. 相似文献
647.
Evaluation of a low-cost adsorbent for removal of toxic metal ions from wastewater of an electroplating factory 总被引:2,自引:0,他引:2
Francisco W. Sousa Marcelo James Sousa Isadora R.N. Oliveira Andr G. Oliveira Rivelino M. Cavalcante Pierre B.A. Fechine Vicente O.S. Neto Denis de Keukeleire Ronaldo F. Nascimento 《Journal of environmental management》2009,90(11):3340-3344
In this study, sugar cane residue or bagasse was used for removal of toxic metal ions from wastewater of an electroplating factory located in northeast Brazil. Prior acid treatment increased the adsorption efficacies in batch wise experiments. The microstructure of the material before and after the treatment was investigated by X-ray diffraction, infrared spectroscopy and scanning electron microscopy. Column operations showed that removals of Cu2+, Ni2+ and Zn2+ from wastewater (in the absence of cyanide) were 95.5%, 96.3.0%, and 97.1%, respectively. Regeneration of the adsorbent obtained in acid indicated that the efficiencies decreased only after the fourth cycle of re-use. Acid-treated sugar cane bagasse can be considered a viable alternative to common methods to remove toxic metal ions from aqueous effluents of electroplating industries. 相似文献
648.
Huidae Cho Francisco Olivera 《Journal of the American Water Resources Association》2009,45(3):673-686
Abstract: The spatial variability of the data used in models includes the spatial discretization of the system into subsystems, the data resolution, and the spatial distribution of hydrologic features and parameters. In this study, we investigate the effect of the spatial distribution of land use, soil type, and precipitation on the simulated flows at the outlet of “small watersheds” (i.e., watersheds with times of concentration shorter than the model computational time step). The Soil and Water Assessment Tool model was used to estimate runoff and hydrographs. Different representations of the spatial data resulted in comparable model performances and even the use of uniform land use and soil type maps, instead of spatially distributed, was not noticeable. It was found that, although spatially distributed data help understand the characteristics of the watershed and provide valuable information to distributed hydrologic models, when the watershed is small, realistic representations of the spatial data do not necessarily improve the model performance. The results obtained from this study provide insights on the relevance of taking into account the spatial distribution of land use, soil type, and precipitation when modeling small watersheds. 相似文献
649.
Paul J. Block Francisco Assis Souza Filho Liqiang Sun Hyun‐Han Kwon 《Journal of the American Water Resources Association》2009,45(4):828-843
Abstract: Water resources planning and management efficacy is subject to capturing inherent uncertainties stemming from climatic and hydrological inputs and models. Streamflow forecasts, critical in reservoir operation and water allocation decision making, fundamentally contain uncertainties arising from assumed initial conditions, model structure, and modeled processes. Accounting for these propagating uncertainties remains a formidable challenge. Recent enhancements in climate forecasting skill and hydrological modeling serve as an impetus for further pursuing models and model combinations capable of delivering improved streamflow forecasts. However, little consideration has been given to methodologies that include coupling both multiple climate and multiple hydrological models, increasing the pool of streamflow forecast ensemble members and accounting for cumulative sources of uncertainty. The framework presented here proposes integration and offline coupling of global climate models (GCMs), multiple regional climate models, and numerous water balance models to improve streamflow forecasting through generation of ensemble forecasts. For demonstration purposes, the framework is imposed on the Jaguaribe basin in northeastern Brazil for a hindcast of 1974‐1996 monthly streamflow. The ECHAM 4.5 and the NCEP/MRF9 GCMs and regional models, including dynamical and statistical models, are integrated with the ABCD and Soil Moisture Accounting Procedure water balance models. Precipitation hindcasts from the GCMs are downscaled via the regional models and fed into the water balance models, producing streamflow hindcasts. Multi‐model ensemble combination techniques include pooling, linear regression weighting, and a kernel density estimator to evaluate streamflow hindcasts; the latter technique exhibits superior skill compared with any single coupled model ensemble hindcast. 相似文献
650.
Jose M. Adam Author Vitae Francisco J. Pallarés Author Vitae Author Vitae 《Journal of Safety Research》2009,40(4):293-299