湖北农村降水中SO_4~(2-)浓度变化研究

在湖北农村 10个地点 ,利用澳大利亚集雨器自 1996年 1月至 1998年 6月 ,按季度采集大气降水样品测定SO2 - 4浓度 ,并对数据进行统计分析。研究结果表明 ,各地 1997年降水中SO2 - 4浓度年均值比 1996年显著升高 ;大多数地点 1996、1997、1998年 1季度和 2季度降水中SO2 - 4浓度呈逐年升高趋势 ;大多数地点每年 1、4季度降水中SO2 - 4浓度高 ,2、3季度降水中SO2 - 4浓度低 ,说明湖北农村降水中的硫对秋冬作物影响比对春夏作物影响大 ;湖北农村降水中SO2 - 4浓度近两年不仅有时间变化规律 ,而且同一季度内的地区差异也很明显 ,在 1996年和 1997年 8个季度 10个点的降水SO2 - 4浓度最大值中 ,有 4个最大值出现在襄樊 ,它是目前湖北继宜昌市区、恩施市区之后又一个酸雨发展较快的地区     

A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

● pz-UiO-66 was synthesized facilely by a solvothermal method. ● Efficient capture of copper from highly acidic solution was achieved by pz-UiO-66. ● pz-UiO-66 exhibited excellent selectivity and capacity for copper capture. ● Pyrazine-N in pz-UiO-66 was shown to be the dominant adsorption site. The selective capture of copper from strongly acidic solutions is of vital importance from the perspective of sustainable development and environmental protection. Metal organic frameworks (MOFs) have attracted the interest of many scholars for adsorption due to their fascinating physicochemical characteristics, including adjustable structure, strong stability and porosity. Herein, pz-UiO-66 containing a pyrazine structure is successfully synthesized for the efficient separation of copper from strongly acidic conditions. Selective copper removal at low pH values is accomplished by using this material that is not available in previously reported metal–organic frameworks. Furthermore, the material exhibits excellent adsorption capacity, with a theoretical maximum copper uptake of 247 mg/g. As proven by XPS and FT-IR analysis, the coordination of pyrazine nitrogen atoms with copper ions is the dominant adsorption mechanism of copper by pz-UiO-66. This work provides an opportunity for efficient and selective copper removal under strongly acidic conditions, and promises extensive application prospects for the removal of copper in the treatment for acid metallurgical wastewater.     

含砷废水净化剂的制备及其应用研究

本文描述了用黄铁矿和还原铁粉或其代用品为原料制备含砷废水净化剂－硫化亚铁的新方法，获得了制备的最佳条件，探讨了其在含砷废水处理中的应用条件和影响因素，结果表明，该净化剂的生产及其处理含砷废水的工艺简单，经济高效，具有良好的开发应用前景。     

高性能纤维在个体防护装备上的应用现状及前景分析

高性能纤维是从化学纤维演化而来,是指耐高温、耐气候、耐化学腐蚀、质量轻、强度高、模量高的特种纤维材料。本文结合几种典型的高性能纤维的具体性能,对高性能纤维在个体防护装备上的应用现状及前景作了分析,旨在进一步推动高性能纤维在个体防护装备上的应用,从而在不同的使用情况下增强个体防护装备对人体的保护功能。     

油田注水泵房噪声治理

调查了油田注水泵房噪声的基本情况.根据噪声来源和特性制定了治理方案,分析了试验应用效果.     

Insights into metals in individual fine particles from municipal solid waste using synchrotron radiation-based micro-analytical techniques

Excessive inter-contamination with heavy metals hampers the application of biological treatment products derived from mixed or mechanically-sorted municipal solid waste(MSW). In this study, we investigated fine particles of 2 mm, which are small fractions in MSW but constitute a significant component of the total heavy metal content, using bulk detection techniques. A total of 17 individual fine particles were evaluated using synchrotron radiation-based micro-X-ray fluorescence and micro-X-ray diffraction. We also discussed the association, speciation and source apportionment of heavy metals. Metals were found to exist in a diffuse distribution with heterogeneous intensities and intense hot-spots of 10 μm within the fine particles. Zn–Cu, Pb–Fe and Fe–Mn–Cr had significant correlations in terms of spatial distribution. The overlapped enrichment, spatial association, and the mineral phases of metals revealed the potential sources of fine particles from size-reduced waste fractions(such as scraps of organic wastes or ceramics) or from the importation of other particles. The diverse sources of heavy metal pollutants within the fine particles suggested that separate collection and treatment of the biodegradable waste fraction(such as food waste) is a preferable means of facilitating the beneficial utilization of the stabilized products.     

醋酸酯生产线物料输送泵的选型与污染物排放量的关系

以钱塘江上游某化工企业的醋酸酯生产线为例,通过分析物料输送泵优化技改前后的工艺流程和污染物排放情况,从而佐证化工行业物料输送泵的选型与污染物排放量是密切相关的,可以达到指导该类项目的环境影响评价和清洁生产审核,同时也能为企业的节能减排提供一定的技术依据。     

Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery

Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25–207 kg CO₂-eq t^?1 rw. Within all process stages, the emission of fossil CO₂ from the combustion of MSW was the main contributor (111–254 kg CO₂-eq t^?1 rw), while the substitution of electricity reduced the GHG emissions by 150–247 kg CO₂-eq t^?1 rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.     

邯钢焦化厂1#～4#焦炉烟尘治理

介绍了邯钢焦化厂1^#～4^#焦炉采用布袋式除尘的烟尘治理方案,装煤和出焦除尘工艺流程及部分改进措施。     

紫外消毒在城市污水处理中的研究进展

介绍城市污水消毒的必要性,对常用污水消毒技术进行现状分析及技术经济比较,紫外线消毒有望成为替代传统液氯消毒的较佳选择.阐述紫外线消毒原理及工程上的应用.最后对紫外消毒技术进行总结.