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811.
Source types or source regions contributing to the concentration of atmospheric fine particles measured at Brigantine National Wildlife Refuge, NJ, were identified using a factor analysis model called Positive Matrix Factorization (PMF). Cluster analysis of backward air trajectories on days of high- and low-factor concentrations was used to link factors to potential source regions. Brigantine is a Class I visibility area with few local sources in the center of the eastern urban corridor and is therefore a good location to study Mid-Atlantic regional aerosol. Sulfate (expressed as ammonium sulfate) was the most abundant species, accounting for 49% of annual average fine mass. Organic compounds (22%; expressed as 1.4 x organic carbon) and ammonium nitrate (10%) were the next abundant species. Some evidence herein suggests that secondary organic aerosol formation is an important contributor to summertime regional aerosol. Nine factors were identified that contributed to PM2.5 mass concentrations: coal combustion factors (66%, summer and winter), sea salt factors (9%, fresh and aged), motor vehicle/mixed combustion (8%), diesel/Zn-Pb (6%), incinerator/industrial (5%), oil combustion (4%), and soil (2%). The aged sea salt concentrations were highest in springtime, when the land breeze-sea breeze cycle is strongest. Comparison of backward air trajectories of high- and low-concentration days suggests that Brigantine is surrounded by sources of oil combustion, motor vehicle/mixed combustion, and waste incinerator/industrial emissions that together account for 17% of PM2.5 mass. The diesel/Zn-Pb factor was associated with sources north and west of Brigantine. Coal combustion factors were associated with coal-fired power plants west and southwest of the site. Particulate carbon was associated not only with oil combustion, motor vehicle/mixed combustion, waste incinerator/industrial, and diesel/Pb-Zn, but also with the coal combustion factors, perhaps through common transport.  相似文献   
812.
An investigation using in situ analysis by portable X-ray fluorescence (PXRF) has shown that contamination present on industrial buildings at a heritage arsenic works site near Redruth, Cornwall, UK results from the absorption of arsenic by porous and semi-porous building materials that were in contact with arsenic-rich flue gases. Results from a preliminary survey indicate that arsenic remains locked in these materials and is being gradually leached out by weathering processes. This weathering causes general contamination of the adjacent building surfaces averaging 1845 microg g(-1) arsenic, presumably caused by evaporation of leach solutions in contact with air at the surface of the building materials. More extensive crystalline deposits were found under arches protected from dissolution and further dispersion by rain water. These deposits appeared to comprise calcium sulfate (gypsum), associated with on average between 1.2 and 6.8% m/m As. In situ PXRF proved to be highly effective in locating sources of contamination at the site and in providing data that allowed a hypotheses for the origin of this contamination to be formulated and tested in the field.  相似文献   
813.
Military installations provide important native habitat for songbirds, including many species that have experienced population declines in recent decades. As part of the Land Condition Trend Analysis (LCTA) program to monitor animal populations on military lands, we surveyed small (<250 g) breeding landbirds on 60 permanent plots on the Fort Riley Military Installation in northeastern Kansas from 1991 to 2002. During this period, species richness averaged 39.0 species (SE 0.9)/year and mean species richness per plot ranged from 3.6 species (SE=0.2)/plot (1999) to 7.5 species (SE=0.3)/plot (1992). Turnover (the appearance and disappearance of species on all plots from one year to the next) ranged from 5 species (2000–2001) to 16 species (1992–1993) and was driven primarily by turnover of woodland species. We developed an index of relative difference (C) to evaluate relative trends of local populations and found that 25 species declined, 15 species increased, and 7 did not change. Based on migration assemblages, more resident species (6 of 10) and more short-distant migrants (9 of 12) decreased than long-distance migrants (10 vs. 11). Our analysis of major vegetation communities on plots showed few changes in the quantity of habitats (grassland vs. woodlands) during the study. Our results indicate that Fort Riley provides important habitats for many landbirds, particularly those that require grasslands for breeding. Several species exhibited local declines when compared to the regional Breeding Bird Survey routes. We offer an approach that evaluates population changes of small landbirds and provides objective inputs for conservation directives. These can be adopted easily for use on military installations (that use LCTA), parks, and wildlife refuges that have data from annual breeding bird surveys.  相似文献   
814.
Phosphorus loss in runoff from agricultural fields has been identified as an important contributor to eutrophication. The objective of this research was to determine the relationship between phosphorus (P) in runoff from a benchmark soil (Cecil sandy loam; fine, kaolinitic, thermic Typic Kanhapludult) and Mehlich III-, deionized water-, and Fe(2)O(3)-extractable soil P, and degree of phosphorus saturation (DPS). Additionally, the value of including other soil properties in P loss prediction equations was evaluated. Simulated rainfall was applied (75 mm h(-1)) to 54 1-m(2) plots installed on six fields with different soil test phosphorus (STP) levels. Runoff was collected in its entirety for 30 min and analyzed for total P and dissolved reactive phosphorus (DRP). Soil samples were collected from 0- to 2-, 0- to 5-, and 0- to 10-cm depths. The strongest correlation for total P and DRP occurred with DPS (r(2) = 0.72). Normalizing DRP by runoff depth resulted in improved correlation with deionized water-extractable P for the 0- to 10-cm sampling depth (r(2) = 0.81). The STP levels were not different among sampling depths and analysis of the regression equations revealed that soil sampling depth had no effect on the relationship between STP and P in runoff. For all forms of P in runoff and STP measures, the relationship between STP and runoff P was much stronger when the data were split into groups based on the ratio of oxalate-extractable Fe to Al. For all forms of P in runoff and all STP methods, R(2) increased with the inclusion of oxalate-extractable Al and Fe in the regression equation. The results of this study indicate that inclusion of site-specific information about soil Al and Fe content can improve the relationship between STP and runoff P.  相似文献   
815.
This research presents an analysis of a goal setting questionnaire developed by Locke and Latham (1984). The Locke and Latham measure attempts to assess the core goal attributes of ‘specificity’ and ‘difficulty’, as well as other attributes of the goal setting process (such as perceptions about ‘performance feedback’, ‘supervisor support’, ‘conflict’ and ‘stress’). The psychometric properties of the measure were examined using respondents from employees of a large, west-coast electronics organization. A principal components analysis extracted 10 meaningful factors and identified a need for additional items. Results generally supported the meaningfulness of the goal setting factors and provide important directions for future research.  相似文献   
816.
817.
ABSTRACT: Six new techniques have been developed for lake watershed analysis and water resource management. The techniques are for determining: (1) watershed land use intensity with reference to water quality, (2) lake vulnerability, (3) water quality, (4) watershed carrying capacity, (5) the economic value of the lake, and (6) the potential of undeveloped lake-shore. These analyses are designed for use by rural planning commissions with guidance and assistance from state agencies and the state university. The comprehensive rural watershed land and water use plan developed by this procedure is inexpensive in time and money, understandable by the layman, and scientificially sound. It is based on presently available information. This water resource planning procedure has been demonstrated in several town planning projects. It is suggested that this method, or modification of it, could be adopted in all rural states by action by a few administrators and without any new enabling or appropriations legislation.  相似文献   
818.
819.
Amazonian forest reserves have significant carbon benefits, but the methodology used for accounting for these benefits will be critical in determining whether the powerful economic force represented by mitigation efforts to slow global warming will be applied to creating these reserves. Opportunities for reserve creation are quickly being lost as new areas are opened to deforestation though highway construction and other developments. Leakage, or the effects that a reserve or other mitigation project provokes outside of the project boundaries, is critical to a proper accounting of net carbon benefits. Protected areas in the Amazon have particularly great potential mitigation benefits over an extended time horizon. Over a 100-year time frame, virtually no unprotected forest is likely to remain, meaning that potential leakages (both leakage to the vicinity of the reserves and that displaced by removing protected areas from the land-grabbing market) should not matter much because any short-term leakage would be “recovered” eventually. The effect of the value attributed to time greatly influences the impact of leakage on benefits credited to reserves. Simple assumptions regarding leakage scenarios illustrate the benefits of reserves and the critical areas where agreement is necessary to make this option a practical component of mitigation efforts. The stakes are too high to allow further delays in reaching agreement on these issues.  相似文献   
820.
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