Study of vehicle speeds on a major highway in Ghana: implication for monitoring and control

OBJECTIVE: Vehicular speeds have been identified to be at the core of road accident severity and frequency globally. Whereas speed control is a fundamental priority and the cornerstone of road safety in the developed world, the subject is at rudimentary stages in most developing countries thus making research into vehicle speeds in developing nations imperative. The main aim of the study was to establish two major speed parameters, namely the mean speed and dispersion, and their implications for more extensive and long-term speed monitoring in Ghana. METHODS: Research workers stationed themselves in a parked car and used a radar gun to unobtrusively measure the travelling speeds of 4,163 vehicles over two 24-hour periods at two separate sites on one of the main inter-urban roads (Accra-Kumasi). Both sites were settled areas with posted speed limits of 50 km/hr. RESULTS: Over 95% of vehicles travelled above the posted speed limit of 50 km/hr. Vehicles on an average travelled at 87 km/hr, (95% CI=87, 88). Variation in speeds was wide, with a standard deviation of 18 km/hr for all classes of vehicles, and with a range of 40 to 187 km/hr. The highest vehicular speed was associated with the private car (97.6+/-18.3 km/hr) followed by large buses (93.6+/-13.3 km/hr) and the least was with heavy trucks (73.8+/-12.9 km/hr). CONCLUSION: The excessive vehicular speeds coupled with the wide speed variations explain in part the high incidence of traffic crashes and fatalities on the Accra-Kumasi highway. An integrated speed monitoring and control program, and realigning the highway to by-pass small and medium settlements would be required as a long-term measure for the reduction of speed-related road traffic crashes, fatalities, and injuries in Ghana.     

Molecular Transport of Xylene Through Palm Pressed Fibre Filled Low Density Polyethylene: Role of Fibre Content,Alkali Treatment and Particle Size

We report in this paper the transport of an aromatic solvent, xylene through palm pressed fibre filled low density polyethylene composites studied at three different temperatures (40, 60, and 80 °C) by conventional weight-gain method. The diffusion parameters were investigated with special reference to the effect of fibre content, temperature and particle size. The effect of alkali treatment on solvent uptake was also analyzed. The transport coefficients of diffusion, permeation and sorption were determined to evaluate the influence of interface bonding on transport properties. The van’t Hoff relationship was used to determine the thermodynamic parameters and was found that the estimated free energies of sorption were all positive, indicating non-spontaneity of the solubility of PPF/LDPE composites. The first order kinetic rate constant and swelling parameters were also evaluated.     

Impacts of “metals” on human health: a comparison between nine different methodologies for Life Cycle Impact Assessment (LCIA)

This paper looks into the differences and uncertainties in determining the impact of “metals’” emissions on human health, in Life Cycle Impact Assessment (LCIA). Metals are diverse substances, with different properties and characteristics, considered important in LCIA because of their toxicity to humans and ecosystems. First, we defined a list of the most significant metals in terms of impacts on human health. This was done according to precise criteria accounting for both physical and toxic properties of the metals. Second, we performed an LCIA on different key processes using various existing LCIA methodologies and including also USEtox: the recently developed consensus-model for LCIA. Last, we compared the results in relative terms using a contribution analysis. The analysis showed poor or no agreement between the methods: the relative contribution of each metal and of the metals in total to the total impact on human health changes greatly according to the LCIA method used. These differences are due mainly to the number of metals included in each method and to the technique used to calculate the characterization factors. Results obtained with USEtox show no apparent correlation with results calculated with other methods. At present time USEtox is recommended as the best model for LCIA on human toxicity, but mainly because of the large consensus behind it, because its uncertainties regarding metals are still high. The study gives a good and simple overview regarding the way different methods address the impact assessment for metals, and helps in the interpretation of LCIA results for actual LCA studies where metal emissions are involved.     

The semiochemically mediated interactions between bacteria and insects

In natural environment, semiochemicals are involved in many interactions between the different trophic levels involving insects, plants and hosts for parasitoids or prey for predators. These volatile compounds act as messengers within or between insect species, inducing particular behaviours, such as the localisation of a source of food, the orientation to an adequate oviposition site, the selection of a suitable breeding site and the localisation of hosts or prey. In this sense, bacteria have been shown to play an important role in the production of volatile compounds which ones act as semiochemicals. This review, focusing on the semiochemically mediated interactions between bacteria and insects, highlights that bacterial semiochemicals act as important messengers for insects. Indeed, in most of the studies reported here, insects respond to specific volatiles emitted by specific bacteria hosted by the insect itself (gut, mouthparts, etc.) or present in the natural environment where the insect evolves. Particularly, bacteria from the families Enterobacteriaceae, Pseudomonaceae and Bacillaceae are involved in many interactions with insects. Because semiochemicals naturally produced by bacteria could be a very interesting option for pest management, advances in this field are discussed in the context of biological control against insect pests.     

Biodegradation of carbofuran in soils within Nzoia River Basin,Kenya

Carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) has been used within the Nzoia River Basin (NRB), especially in Bunyala Rice Irrigation Schemes, in Kenya for the control of pests. In this study, the capacity of native bacteria to degrade carbofuran in soils from NRB was investigated. A gram positive, rod-shaped bacteria capable of degrading carbofuran was isolated through liquid cultures with carbofuran as the only carbon and nitrogen source. The isolate degraded 98% of 100-μg mL^?1 carbofuran within 10 days with the formation of carbofuran phenol as the only detectable metabolite. The degradation of carbofuran was followed by measuring its residues in liquid cultures using high performance liquid chromatography (HPLC). Physical and morphological characteristics as well as molecular characterization confirmed the bacterial isolate to be a member of Bacillus species. The results indicate that this strain of Bacillus sp. could be considered as Bacillus cereus or Bacillus thuringiensis with a bootstrap value of 100% similar to the 16S rRNA gene sequences. The biodegradation capability of the native strains in this study indicates that they have great potential for application in bioremediation of carbofuran-contaminated soil sites.     

CHANGING RAINFALL-RUNOFF RELATIONSHIPS IN THE URBANIZING PEACHTREE CREEK WATERSHED,ATLANTA, GEORGIA1

ABSTRACT: Peachtree Creek is a gaged watershed that has experienced a substantial increase in urbanization. The relationships of runoff to rainfall were studied for total annual flows, low flows, and peak flows. For each type of flow the relationship in the later, more urbanized period was compared to that in the earlier, less urbanized period. An increase in total runoff in wet years was observed as urbanization increased, but a decrease occurred during dry years. For low flows a similar decrease of runoff in dry years was found. An increase in peak runoff was observed over most of the range of precipitation. Increasing peak flows and declining low flows can be adequately explained by urban hydrologic theoryshed. which focuses on the effects of urban impervious surfaces upon direct runoff and infiltration. However, a decline of total runoff in dry years can be explained only by taking into account evapotranspiration as well. The concept of advectively assisted urban evapotranspiration, previously discovered by climatologists, is needed to explain such a loss of total runoff. Urban hydrologic theory must take into account vegetation and evapotranspiration, as well as impervious surfaces and their direct runoff, to explain the magnitude of total annual flows and low flows. Urban stormwater management should address the restoration of low flows, as well as the control of floods.     

Productivity equation for reclaiming surface mines

This article addresses the development of an agricultural productivity equation for predicting new soil (neo-sol) plant growth potential in Clay County, Minnesota, USA. Soil factors examined in the study include percent organic matter, percent slope, percent rock fragments, hydraulic conductivity, electrical conductivity, pH, topographic position, available water-holding capacity, bulk density, and percent clay. Squared terms and two-factor interaction terms were also examined as possible regressors. A best equation was selected that had a multiple coefficient of determination of 0.7399 and has five significant regressors and intercept withP.0001. The regressors are hydraulic conductivity, percent slope squared, bulk density times percent rock fragments, electrical conductivity times percent rock fragments, and electrical conductivity times percent organic matter. The regressors predict soil suitability for a general crop model. The crops included in the model are wheat, oats, barley, soybeans, sugar beets, sunflowers, and grasses/legumes.     

IN SITU MEASUREMENT OF ADSORPTION AND BIOTRANSFORMATION AT A HAZARDOUS WASTE SITE1

ABSTRACT: A three well injection-production test was performed at the United Creosoting Company (UCC) site in Conroe, Texas, to estimate the effective in situ retardation factors for adsorption and to evaluate the significance of biotransformation in limiting the transport of polycydic aromatics present in the shallow aquifer. The field test was also used as a model to determine if this type of testing would be feasible at other hazardous waste sites. During the test, chloride, a non-reactive tracer and two organic compounds, naphthalene and paradichlorobenzene (pDCB), were injected into a center well for 24 hours followed by clean ground water for six days. Ground water was continuously produced from two adjoining wells and monitored to observe the breakthrough of these compounds. Data from the test were analyzed by comparing the statistical moments of the chloride and organics distributions. Retardation factors for naphthalene and pDCB were estimated to be 1.03 and 0.97 by comparison of the statistical moments. A significant loss of naphthalene and pDCB was also observed during the three well test, apparently due to biotransformation. These results suggest that biotransformation is the major process limiting the transport of naphthalene and similar compounds at the UCC site.     

Impact of power utility rights-of-way on wooded wetland

This study documents the effects of power utility right-of-way construction and maintenance on the vegetation of a wooded wetland in North Reading, Massachusetts, USA. Neither activity had a substantial, long-term negative impact. Except for differences in size and maturity, the vegetation recovered in two years from nearly total destruction caused by construction. Maintenance that included the periodic removal of high-growing species led to the formation of a plant association different from the one occurring naturally, but as diverse and species rich.