Mercury (Hg) emissions from domestic biomass combustion for space heating

Three mercury (Hg) species (gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and fine particulate-bound mercury (PBM_2.5)) were measured in the stack of a small scale wood combustion chamber at 400 °C, in the stack of an advanced wood boiler, and in two areas influenced by wood combustion. The low temperature process (lab-scale) emitted mostly GEM (∼99% when burning wood pellets and ∼95% when burning unprocessed wood). The high temperature wood boiler emitted a greater proportion of oxidized Hg (approximately 65%) than the low temperature system. In field measurements, mean PBM_2.5 concentrations at the rural and urban sites in winter were statistically significantly higher than in warmer seasons and were well correlated with Delta-C concentrations, a wood combustion indictor measured by an aethalometer (UV-absorbable carbon minus black carbon). Overall the results suggest that wood combustion may be an important source of oxidized mercury (mostly in the particulate phase) in northern climates in winter.     

Two neighborhood-free plot designs for adaptive sampling of forests

Adaptive cluster sampling (ACS) has the potential of being superior for sampling rare and geographically clustered populations. However, setting up an efficient ACS design is challenging. In this study, two adaptive plot designs are proposed as alternatives: one for fixed-area plot sampling and the other for relascope sampling (also known as variable radius plot sampling). Neither includes a neighborhood search which makes them much easier to execute. They do, however, include a conditional plot expansion: at a sample point where a predefined condition is satisfied, sampling is extended to a predefined larger cluster-plot or a larger relascope plot. Design-unbiased estimators of population total and its variance are derived for each proposed design, and they are applied to ten artificial and one real tree position maps to estimate density (number of trees per ha) and basal area (the cross-sectional area of a tree stem at breast height) per hectare. The performances—in terms of relative standard error (SE%)—of the proposed designs and their non-adaptive alternatives are compared. The adaptive plot designs were superior for the clustered populations in all cases of equal sample sizes and in some cases of equal area of sample plots. However, the improvement depends on: (1) the plot size factor; (2) the critical value (the minimum number of trees triggering an expansion); (3) the subplot distance for the adapted cluster-plots, and (4) the spatial arrangement of the sampled population. For some spatial arrangements, the improvement is relatively small. The adaptive designs may be particularly attractive for sampling in rare and compactly clustered populations with critical value of 1, subplot distance equal to the diameter of initial circular plots, or plot size factor of 2.5 for an initial basal area factor of 2.     

MODELING NORTH CASCADES ANNUAL RUNOFF DISTRIBUTION USING DRAINAGE BASIN ELEVATION DISTRIBUTION1

ABSTRACT: The annual distribution of flow in a drainage basin within a given region is a function of many factors. These may include annual distribution of rainfall, basin orientation, ground cover, or presence of glaciers. Since the North Cascades region of northern Washington State has little variation in precipitation distribution by month, and the region has significant snowpack, one would predict that in an unregulated basin, basin elevation would be one of the most important factors impacting an annual hydrograph distribution. Such a prediction can be made since the higher a drainage basin is, the larger the portion of runoff that would occur as late spring snowmelt. Given that there is a relationship between elevation distribution and annual hydrograph, the problem becomes one of how to use this relationship to model an ungaged basin's hydrograph. This study concludes that, within the North Cascades region and perhaps within other regions, an effective method of determining annual flow distribution is to model ungaged flows in the same manner as flows from a gaged basin with an elevation distribution similar to that of the subject basin.     

An evaluation of benthic macroinvertebrate biomass methodology

Evaluation of analytical methods employed for wet weight (live or preserved samples) of benthic macroinvertebrates reveals that centrifugation at 140 x gravity for one minute yields constant biomass estimates. Less relative centrifugal force increases chance of incomplete removal of body moisture and results in weighing error, while greater force may rupture fragile macroinvertebrates, such as mayflies. Duration of specimen exposure in ethanol, formalin, and formol (formaling-ethanol combinations) causes significant body weight loss with within 48 hr formalin and formol cause less body weight loss than ethanol. However, as all preservatives tested cause body weight loss, preservation time of samples collected for comparative purposes should be treated uniformly. Dry weight estimates of macroinvertebrates are not significantly affected by kind of preservative or duration of exposure. Constant dry weights are attained by oven drying at 103 °C at a minimum of four hours or vacuum oven drying (15 inches of mercury pressure) at 103 °C for a minimum of one hour. Although requiring more time in preparation than oven drying and inalterably changing specimen body shape, freeze drying (10 microns pressure, -55 °C, 24 hr) provides constant dry weights and is advantageous for long term sample storage by minimizing curatorial attention. Constant ash-free dry weights of macroinvertebrate samples are attained by igniting samples at 500–550 °C for a minimum of one hour with slow cooling to room temperature in desiccators before weighing.     

Determination of commonly used polar herbicides in agricultural drainage waters in Australia by HPLC

The present study describes the application of different extraction techniques for the preconcentration of ten commonly found acidic and non-acidic polar herbicides (2,4-D, atrazine, bensulfuron-methyl, clomazone, dicamba, diuron, MCPA, metolachlor, simazine and triclopyr) in the aqueous environment. Liquid-liquid extraction (LLE) with dichloromethane, solid-phase extraction (SPE) using Oasis HLB cartridges or SBD-XC Empore disks were compared for extraction efficiency of these herbicides in different matrices, especially water samples from contaminated agricultural drainage water containing high concentrations of particulate matter. Herbicides were separated and quantified by high performance liquid chromatography (HPLC) with an ultraviolet detector. SPE using SDB-XC Empore disks was applied to determine target herbicides in the Murrumbidgee Irrigation Area (NSW, Australia) during a two-week survey from October 2005 to November 2005. The daily aqueous concentrations of herbicides from 24-h composite samples detected at two sites increased after run-off from a storm event and were in the range of: 0.1-17.8 microg l(-1), < 0.1-0.9 microg l(-1) and 0.2-17.8 microg l(-1) at site 1; < 0.1-3.5 microg l(-1), < 0.1-0.2 microg l(-1) and < 0.2-3.2 microg l(-1) at site 2 for simazine, atrazine and diuron, respectively.     

Social competition masculinizes the communication signals of female electric fish

Male intrasexual competition and female choice explain the evolution of male ornaments. Except in sex-role-reversed taxa, female ornaments have been regarded as an epiphenomenon of genetic correlation, with no female-specific function or independently selected basis. Females from species with conventional sex roles may still experience some degree of female–female competition and male choice that could explain the persistence of female ornaments. We studied the effect of female competition on the expression of a sexually dimorphic communication signal. In the electric fish Brachyhypopomus gauderio, both sexes produce an electric signal pulse for communication and electrolocation. Male electric pulses are longer in duration and greater in amplitude than those of females. As competition increases, males further enhance their signals in response to elevated androgen levels. We explored whether females respond to social competition as males do, by enhancing their communication signals and increasing androgen levels. We measured amplitude and duration of the electric signal pulse, and testosterone levels in female B. gauderio in their natural habitat in Uruguay and estimated social competition by calculating population density and adult sex ratio (ASR). In the lab, we manipulated ASR and population density independently to separate these factors and eliminate seasonal confounds. Under both field and lab conditions, signal pulse amplitude increased with population density, while pulse duration increased with female bias in ASR. In the field, but not the lab, androgen levels increased when ASR was female biased. Our findings indicate that the socially mediated mechanism of signal regulation is shared by the sexes, although whether androgens regulate this signal plasticity in females remains unclear.     

Risk-based management of contaminated land in the UK: Lessons for China?

The management of contaminated land is now assuming greater attention in Chinese debates on environmental governance. However, the existing management system appears ineffective as it lacks a clear policy framework and technical basis. In the United Kingdom (UK), contaminated land issues are dealt with through a risk-based approach. This approach emphasizes the application of risk approaches in both technical and integrated management systems. Conceptually, this paper outlines generic issues related to transferring programmes from one place to another. We argue that too much emphasis has been placed on the barriers to effective transfer, rather than focusing on methods of abstracting lessons for application in foreign settings. We then examine the Chinese system and its problems in managing contaminated land before turning to the UK risk-based approach to see what lessons can be learned from it. Four aspects are analyzed and compared: legislative and policy framework; administrative structure and capacity; technical approaches; and incentive strategy. Based on the experience of the UK in practice, some suggestions are then proposed for China in order to improve its management of contaminated land. We suggest that this should include: a focus on the problem sites; development of a risk-based technical approach and integrated management system; the introduction of financial incentives; and the use of planning control as a management strategy. It is believed that a risk-based integrated management approach may be helpful for China to achieve sustainable solutions for contaminated land.     

The world conservation strategy: Environmental education and local initiative

Summary In the spring of 1981, Tufts University and the International Union for the Conservation of Nature began teaching the World Conservation Strategy to environmentalists working at the local level. The fourteen-week course that they offered was the first of a series of initiatives to increase public awareness of the need for local action toward the solution of global environmental problems. The success of the first course has encouraged other groups to adapt it to their own social and ecological settings, but there is a pressing need for even more public education. While several aids to teaching the World Conservation Strategy are now being developed to give local conservation educators access to the Strategy, the initiative for bringing the World Conservation Strategy to the public should continue to come from these local leaders. Frank Thibodeau is an environmental biologist and policy analyst with MA and PhD degrees from Tufts University. He is currently a Research Associate in the Department of Urban and Environmental Policy at Tufts, preparing a book on the World Conservation Strategy as a foundation for local environmental initiative under the auspicies of IUCN and the World Wildlife Fund. In addition to his writing and teaching related to the Strategy, he maintains an active research program examining the development of national and international strategies for the preservation of genetic diversity. Hermann H. Field, an urban planner and Fellow of the American Institute of Architects, was director of the Planning Office of the Tufts-New England Medical Center in downtown Boston for 12 years. In 1972 he initiated and then directed a new graduate department of Urban and Environmental Policy at Tufts University. Since 1978 he has been Professor Emeritus in Environmental Planning there. In addition to continued involvement in his department he is active on a range of levels in conservation from the local to the international, including membership on IUCN's Commission on Environmental Planning.     

Jordan,minerals extraction and the resource curse

In its role as a competitive producer of phosphate and potash Jordan has not suffered noticeably from the Resource Curse over the past 50 years. However, the effects on its economy because of its geographical proximity to major oil-producing states have been both positive and negative. It is arguable that an oil resource curse has applied to Jordan.     

Cell-free DNA screening in twin pregnancies: A more accurate and reliable screening tool

Objective

Outcome data from cell-free DNA (cfDNA) screening in twin gestations are limited. This study adds an appreciable number of confirmed outcomes to the literature, and assesses performance of cfDNA screening in twins over a 4.5-year period at one large clinical laboratory.

Method

Prenatal cytogenetic and SNP microarray results were cross-referenced with cfDNA results for twin pregnancies, yielding 422 matched cases. Using diagnostic results as truth, performance of cfDNA screening in this population was assessed.

Results

Of the 422 twin pregnancies with both cfDNA and diagnostic results, 3 specimens failed amniocyte analysis, and 48 samples (11.5%) were nonreportable from the initial cfDNA draw. Analysis of the 371 reportable samples demonstrated a collective sensitivity of 98.7% and specificity of 93.2% for trisomies 21/18/13. Positive predictive values (PPVs) in this study population, which is enriched for aneuploidy, were 78.7%, 84.6%, and 66.7% for trisomy 21, 18, and 13, respectively.

Conclusion

CfDNA screening in a cohort of twin pregnancies with matched diagnostic results showed superior performance compared to traditional serum biochemical screening in twins. This study adds to a growing body of evidence suggesting that cfDNA is an accurate and reliable screening tool for the major trisomies in twin pregnancies.