Simulation of solute transport across low-permeability barrier walls

Low-permeability, non-reactive barrier walls are often used to contain contaminants in an aquifer. Rates of solute transport through such barriers are typically many orders of magnitude slower than rates through the aquifer. Nevertheless, the success of remedial actions may be sensitive to these low rates of transport. Two numerical simulation methods for representing low-permeability barriers in a finite-difference groundwater-flow and transport model were tested. In the first method, the hydraulic properties of the barrier were represented directly on grid cells and in the second method, the intercell hydraulic-conductance values were adjusted to approximate the reduction in horizontal flow, allowing use of a coarser and computationally efficient grid. The alternative methods were tested and evaluated on the basis of hypothetical test problems and a field case involving tetrachloroethylene (PCE) contamination at a Superfund site in New Hampshire. For all cases, advective transport across the barrier was negligible, but preexisting numerical approaches to calculate dispersion yielded dispersive fluxes that were greater than expected. A transport model (MODFLOW-GWT) was modified to (1) allow different dispersive and diffusive properties to be assigned to the barrier than the adjacent aquifer and (2) more accurately calculate dispersion from concentration gradients and solute fluxes near barriers. The new approach yields reasonable and accurate concentrations for the test cases.     

Sorption and bioreduction of hexavalent uranium at a military facility by the Chesapeake Bay

Directly adjacent to the Chesapeake Bay lies the Aberdeen Proving Ground, a U.S. Army facility where testing of armor-piercing ammunitions has resulted in the deposition of >70,000 kg of depleted uranium (DU) to local soils and sediments. Results of previous environmental monitoring suggested limited mobilization in the impact area and no transport of DU into the nation's largest estuary. To determine if physical and biological reactions constitute mechanisms involved in limiting contaminant transport, the sorption and biotransformation behavior of the radionuclide was studied using geochemical modeling and laboratory microcosms (500 ppb U(VI) initially). An immediate decline in dissolved U(VI) concentrations was observed under both sterile and non-sterile conditions due to rapid association of U(VI) with natural organic matter in the sediment. Reduction of U(VI) to U(IV) occurred only in non-sterile microcosms. In the non-sterile samples, intrinsic bioreduction of uranium involved bacteria of the order Clostridiales and was only moderately enhanced by the addition of acetate (41% vs. 56% in 121 days). Overall, this study demonstrates that the migration of depleted uranium from the APG site into the Chesapeake Bay may be limited by a combination of processes that include rapid sorption of U(VI) species to natural organic matter, followed by slow, intrinsic bioreduction to U(IV).     

Air emission inventories in North America: a critical assessment

Although emission inventories are the foundation of air quality management and have supported substantial improvements in North American air quality, they have a number of shortcomings that can potentially lead to ineffective air quality management strategies. Major reductions in the largest emissions sources have made accurate inventories of previously minor sources much more important to the understanding and improvement of local air quality. Changes in manufacturing processes, industry types, vehicle technologies, and metropolitan infrastructure are occurring at an increasingly rapid pace, emphasizing the importance of inventories that reflect current conditions. New technologies for measuring source emissions and ambient pollutant concentrations, both at the point of emissions and from remote platforms, are providing novel approaches to collecting data for inventory developers. Advances in information technologies are allowing data to be shared more quickly, more easily, and processed and compared in novel ways that can speed the development of emission inventories. Approaches to improving quantitative measures of inventory uncertainty allow air quality management decisions to take into account the uncertainties associated with emissions estimates, providing more accurate projections of how well alternative strategies may work. This paper discusses applications of these technologies and techniques to improve the accuracy, timeliness, and completeness of emission inventories across North America and outlines a series of eight recommendations aimed at inventory developers and air quality management decision-makers to improve emission inventories and enable them to support effective air quality management decisions for the foreseeable future.     

Amazonian forest loss and the long reach of China’s influence

This paper explores China’s role in deforestation in Latin America. Brazil’s Amazon region contains vast natural resources including land, timber, minerals and hydroelectric potential. China’s strong economy and large demands relative to domestic supplies of these resources mean that China has become Brazil’s largest trading partner, primarily for natural resources. The paper examines how China influences deforestation in Brazilian Amazonia in a variety of ways, including through the direct influence of Chinese enterprises through land purchases and other mechanisms. This paper finds that the rapid rise in exports of soy and beef products to China are two of the major drivers of Amazonian deforestation in Brazil. The paper further argues that Chinese purchases of agricultural and forest land and Chinese imports of commodities such as timber and aluminum also cause environmental impacts in Amazonia. Chinese financing and investment in Amazonian infrastructure such as railways and mineral processing facilities have additional impacts.     

Who Visits a National Park and What do They Get Out of It?: A Joint Visitor Cluster Analysis and Travel Cost Model for Yellowstone National Park

Yellowstone National Park visitor data were obtained from a survey collected for the National Park Service by the Park Studies Unit at the University of Idaho. Travel cost models have been conducted for national parks in the United States; however, this study builds on these studies and investigates how benefits vary by types of visitors who participate in different activities while at the park. Visitor clusters were developed based on activities in which a visitor participated while at the park. The clusters were analyzed and then incorporated into a travel cost model to determine the economic value (consumer surplus) that the different visitor groups received from visiting the park. The model was estimated using a zero-truncated negative binomial regression corrected for endogenous stratification. The travel cost price variable was estimated using both 1/3 and 1/4 the wage rate to test for sensitivity to opportunity cost specification. The average benefit across all visitor cluster groups was estimated at between $235 and $276 per person per trip. However, per trip benefits varied substantially across clusters; from $90 to $103 for the “value picnickers,” to $185–$263 for the “backcountry enthusiasts,” $189–$278 for the “do it all adventurists,” $204–$303 for the “windshield tourists,” and $323–$714 for the “creature comfort” cluster group.     

Why keep lions instead of livestock? Assessing wildlife tourism‐based payment for ecosystem services involving herders in the Maasai Mara,Kenya

This paper examines the effects of wildlife tourism‐based payments for ecosystem services (PES) on poverty, wealth inequality and the livelihoods of herders in the Maasai Mara Ecosystem in south‐western Kenya. It uses the case of Olare Orok Conservancy PES programme in which pastoral landowners have agreed to voluntary resettlement and exclusion of livestock grazing from their sub‐divided lands. These lands are set aside for wildlife tourism, in return for direct monetary payments by a coalition of five commercial tourism operators. Results show that, on the positive side, PES is the most equitable income source that promotes income diversification and buffers households from the livestock income declines during periods of severe drought, such as in 2008‐2009. Without accounting for the opportunity costs, the magnitude of the PES cash transfer to households is, on average, sufficient to close the poverty gap. The co‐benefits of PES implementation include the creation of employment opportunities in the conservancy and provision of social services. There is however a need to mitigate the negative effects of PES, including the widening inequality in income between PES and non‐PES households and the leakages resulting from the displacement of settlements and livestock to currently un‐subdivided pastoral commons.     

Pyrene mineralization by Mycobacterium sp. strain KMS in a barley rhizosphere

To determine whether the soil Mycobacterium isolate KMS would mineralize pyrene under rhizosphere conditions, a microcosm system was established to collect radioactive carbon dioxide released from the labeled polycyclic aromatic hydrocarbon. Microcosms were designed as sealed, flow-through systems that allowed the growth of plants. Experiments were conducted to evaluate mineralization of 14C-labeled pyrene in a sand amended with the polycyclic aromatic hydrocarbons degrading Mycobacterium isolate KMS, barley plants, or barley plants with roots colonized by isolate KMS. Mineralization was quantified by collecting the 14CO2 produced from 14C-labeled pyrene at intervals during the 10-d incubation period. Roots and foliar tissues were examined for 14C incorporation. Mass balances for microcosms were determined through combustion of sand samples and collection and quantification of 14CO2 evolved from radiolabeled pyrene. No pyrene mineralization was observed in the sterile control systems. Greater release of 14CO2 was observed in the system with barley colonized by KMS than in microcosms containing just the bacterium inoculum or sterile barley plants. These findings suggest that phytostimulation of polycyclic aromatic hydrocarbons mineralization could be applied in remediation schemes.     

Habitat Acquisition Strategies for Grassland Birds in an Urbanizing Landscape

Habitat protection for grassland birds is an important component of open space land acquisition in suburban Chicago. We use optimization decision models to develop recommendations for land protection and analyze tradeoffs between alternative goals. One goal is to acquire (and restore if necessary) as much grassland habitat as possible for a given budget. Because a viable habitat for grassland birds consists of a relatively large core area with additional parcels of grassland habitat nearby, the second goal is to minimize total pairwise distance between newly protected parcels and large existing reserves. We also use the concept of an effective grassland habitat area, which considers influences that neighboring land covers have on grassland habitat suitability. We analyze how the parcels selected for protection change as total protected effective area is traded off against total distance. As area is weighted more heavily, the selected parcels are scattered and unconnected. As total distance is weighted more heavily, the selected parcels coalesce around core reserves but protect less area. The differences in selected parcels as we change the objective function weights are caused by the differences in price per unit of effective habitat area across parcels. Parcels located in close proximity to the existing cores have relatively high prices per hectare of effective grassland area as a consequence of high restoration costs and adverse influences from roads, urban areas and/or forestland. As a result, these parcels have lower priority for selection when the area objective is weighted more heavily for a given budget.     

Controls on catchment-scale patterns of phosphorus in soil, streambed sediment, and stream water

Many models of phosphorus (P) transfer at the catchment scale rely on input from generic databases including, amongst others, soil and land use maps. Spatially detailed geochemical data sets have the potential to improve the accuracy of the input parameters of catchment-scale nutrient transfer models. Furthermore, they enable the assessment of the utility of available, generic spatial data sets for the modeling and prediction of soil nutrient status and nutrient transfer at the catchment scale. This study aims to quantify the unique and joint contribution of soil and sediment properties, land cover, and point-source emissions to the spatial variation of P concentrations in soil, streambed sediments, and stream water at the scale of a medium-sized catchment. Soil parent material and soil chemical properties were identified as major factors controlling the catchment-scale spatial variation in soil total P and Olsen P concentrations. Soil type and land cover as derived from the generic spatial database explain 33.7% of the variation in soil total P concentrations and 17.4% of the variation in Olsen P concentrations. Streambed P concentrations are principally related to the major element concentrations in streambed sediment and P delivery from the hillslopes due to sediment erosion. During base flow conditions, the total phosphorus (<0.45 microm) concentrations in stream water are mainly controlled by the concentrations of P and the major elements in the streambed sediment.     

建筑产品与生命周期思考

生命周期理念,在与建筑和建设部门的关系中,特别应该进行建筑产品分析、在提高建筑物能源效率并为经济繁荣有所贡献的时候,这些产品发挥着基本的作用,已经做出的要算披露,在从自然索取的物质资源和产生的垃圾总量中,有一半来自建筑部门,为了对建筑产品的影响进行和理并把综降到最低,就必须利用生命周期的方法对所产生的影响进生检测,本文评论了生命周期理念并思考了最新的发展.材料与可持续建筑,环境产品宣言,所体现的能源以及北方与南言建筑产品评估中产生的差异,都是要讨论的话题.