Source-separated municipal solid waste compost application to Swiss chard and basil

A growth room experiment was conducted to evaluate the bioavailability of Cu, Mn, Zn, Ca, Fe, K, Mg, P, S, As, B, Cd, Co, Cr, Hg, Mo, Na, Ni, Pb, and Se from a sandy loam soil amended with source-separated municipal solid waste (SSMSW) compost. Basil (Ocimum basilicum L.) and Swiss chard (Beta vulgaris L.) were amended with 0, 20, 40, and 60% SSMSW compost to soil (by volume) mixture. Soils and compost were sequentially extracted to fractionate Cu, Pb, and Zn into exchangeable (EXCH), iron- and manganese-oxide-bound (FeMnOX), organic-matter (OM), and structurally bound (SB) forms. Overall, in both species, the proportion of Cu, Pb, and Zn levels in different fractions followed the sequence: SB > OM > FeMnOX > EXCH for Cu; FeMnOX = SB > OM > EXCH for Pb; and FeMnOX > SB = EXCH > OM for Zn. Application of SSMSW compost increased soil pH and electrical conductivity (EC), and increased the concentration of Cu, Pb, and Zn in all fractions, but not EXCH Pb. Basil yields were greatest in the 20% treatment, but Swiss chard yields were greater in all compost-amended soils relative to the unamended soil. Basil plants in 20 or 40% compost treatments reached flowering earlier than plants from other treatments. Additions of SSMSW compost to soil altered basil essential oil, but basil oil was free of metals. The results from this study suggest that mature SSMSW compost with concentrations of Cu, Pb, Mo, and Zn of 311, 223, 17, and 767 mg/kg, respectively, could be used as a soil conditioner without phytotoxic effects on agricultural crops and without increasing the normal range of Cu, Pb, and Zn in crop tissue. However, the long-term effect of the accumulation of heavy metals in soils needs to be carefully considered.     

Targeted Application of Seasonal Load Duration Curves Using Multivariate Analysis in Two Watersheds Flowing Into Lake Houston1

Teague, Aarin, Philip B. Bedient, and Birnur Guven, 2011. Targeted Application of Seasonal Load Duration Curves Using Multivariate Analysis in Two Watersheds Flowing Into Lake Houston. Journal of the American Water Resources Association (JAWRA) 47(3):620‐634. DOI: 10.1111/j.1752‐1688.2011.00529.x Abstract: Water quality is a problem in Lake Houston, the primary source of drinking water for the City of Houston, Texas, due to pollutant loads coming from the influent watersheds, including Spring Creek and Cypress Creek. Statistical analysis of the historic water quality data was developed to understand the source characterization and seasonality of the watershed. Multivariate analysis including principal component, cluster, and discriminant analysis provided a custom seasonal assessment of the watersheds so that loading curves may be targeted for season specific pollutant source characterization. The load duration curves have been analyzed using data collected by the U.S. Geologic Survey with corresponding City of Houston water quality data at the sites to characterize the behavior of the pollutant sources and watersheds. Custom seasons were determined for Spring Creek and Cypress Creek watersheds and pollutant source characterization compared between the seasons and watersheds.     

Exclusion of citrullinaemia in the first trimester of pregnancy by direct assay of argininosuccinate synthetase in chorionic villi

Citrullinaemia was presumed to be excluded in a fetus at risk by the direct assay of argininosuccinate synthetase in chorionic villi. The diagnosis was confirmed after amniocentesis by normal argininosuccinate synthetase activity in the cultured amniotic fluid cells and by a normal citrulline concentration in the amniotic fluid. The prediction of a normal fetus was confirmed at term by the birth of a non-citrullinaemic boy.     

Treatment of carbofuran-bearing synthetic wastewater using UASB process

In the present study, fate of carbofuran in anaerobic environments and the adverse effects of carbofuran on conventional anaerobic systems were evaluated. Carbofuran degradation studies were carried out in batch reactors with varying carbofuran concentrations of 0 to 270.73 mg/L corresponding to a sludge-loading rate (SLR) of 2.12 x 10(-6) to 3.83 x 10(-3) g of carbofuran/g of volatile suspended solids (VSS)/d. Carbofuran concentration was reduced to undetectable levels at the end of 8 and 13 days in the batch reactors operated with a SLR of 2.12 x 10(-6) and 3.33 x 10(-5) g of carbofuran/g of VSS/d, respectively. Performances of two anaerobic reactors i.e. upflow anaerobic sludge blanket (UASB) and modified UASB (with tube settlers) were evaluated in the presence and absence of carbofuran using synthetic wastewater. In the absence of carbofuran, the soluble chemical oxygen demand (COD) removal efficiency in the conventional UASB reactor at 8 h and 6 h hydraulic retention time (HRT) was nearly 88% and 76%, respectively, whereas in modified UASB reactor it was increased to 90% at 8 h HRT and 78% at 6 h HRT. When 28 mg/L (SLR of 1.19 x 10(-2) g of carbofuran/g of VSS/d) of carbofuran was introduced in the reactors, the COD removal efficiency was reduced to 41% and 44% in conventional and modified UASB reactors respectively. However, the reactor could maintain around 80% COD removal efficiency at a carbofuran concentration of 7.84 mg/L (SLR of 3.64 x 10(-3) g of carbofuran/g of VSS/d). The reactor efficiency was also measured in terms of specific acetoclastic methanogenic activity (SMA). The toxic effect of carbofuran was reversible to a certain extent. Carbofuran removal efficiency in the conventional UASB reactor at carbofuran concentrations of 7, 13 and 28 mg/L were 40 +/- 3%, 27 +/- 3%, and 11 +/- 3%, respectively. In modified UASB reactor, carbofuran removal efficiency was almost uniform at 7 and 13 mg/L but it was reduced nearly by 56% at 28 mg/L. The major metabolite of carbofuran i.e. 3-keto carbofuran was found in all the reactors.     

Anaerobic treatment of atrazine bearing wastewater.

Performance of mixed microbial anaerobic culture in treating synthetic waste-water with high Chemical Oxygen Demand (COD) and varying atrazine concentration was studied. Performance of hybrid reactors with wood charcoal as adsorbent, with a dose of 10 g/l and 40 g/l, along with the microbial mass was also studied. All the reactors were operated in sequential mode with Hydraulic Retention Time (HRT) of 5 days. In all the cases, COD removal after 5 days was found to be above 81%. Initial COD was above 1,000 mg/l. From a hybrid reactor COD removal after 2 days was observed to be 90%. Atrazine reduction after 5 days by microbial mass alone was 43.8%, 40% and 33.2% with an initial concentration of 0.5, 1.0 and 2.0 mg/l respectively. MLSS on all the cases were almost same. Increasing MLSS concentration by about 2 fold did not increase the atrazine removal efficiency significantly. Maximum atrazine removal was observed to be 64% from the hybrid reactor with 10 g/l of wood charcoal and 69.4% from the reactor with 40 g/l of wood charcoal. Atrazine removal from the hybrid reactors after 15 days were observed to be 35.7% and 38.7%, which showed that the higher dose of wood charcoal in hybrid reactor did not improve the atrazine removal efficiency significantly. Specific methanogenic activity test showed no inhibitory effect of atrazine on methane producing bacteria. The performance of anaerobic microorganisms in removing atrazine with no external carbon source and inorganic nitrogen source was studied in batch mode. With an initial concentration of 1.0 mg/l, reduction of atrazine by the anaerobic microorganisms in absence of external carbon source after 35 days was observed to be 61.8% where as in absence of external carbon and inorganic nitrogen source the reduction was only 44.2% after 150 days. Volatilization loss of atrazine was observed to be insignificant.     

Hydrologic analysis for coastal wetland restoration

Increasing recognition of the value of tidal wetlands has led to interest in how to restore and enhance areas that have been modified by human activity. The policy of recognizing restoration or enhancement as mitigation for destruction of other wetlands is controversial. Once policy questions are separated from technical questions, the steps in a successful project are straightforward A key element in the design of a successful project is quantitative hydraulic and hydrologic analysis of alternatives. Restoration projects at two sites in California used a combination of empirical geomorphic relationships, numerical modeling, and verification with field observations. Experience with these and other wetland restoration projects indicates the importance of longterm postproject monitoring, inspection, and maintenance     

The Potential of Brazil's Forest Sector for Mitigating Global Warming under the Kyoto Protocol

Activities in Brazil's forest sector have substantial potential for mitigating global warming as well as additional environmental and other benefits. Silvicultural plantations of different types, reduced impact logging, and deforestation avoidance all have potential mitigation roles. The magnitude of the annual emission from recent rates of deforestation in Amazonia presents an opportunity for carbon (C) benefits through reducing current rates of deforestation. Measures related to Amazonian deforestation have greater potential carbon benefits than do options such as plantation silviculture, but much depends on how benefits are calculated. Procedures are needed for assessing the environmental and social impacts of Clean DevelopmentMechanism (CDM) projects.     

Negotiations after the sale: The roots and ramifications of conflict in an acquisition

This paper presents a case study of negotiations over the combination of a small manufacturing firm into a multi-billion dollar conglomerate following its 'white knight' acquisition. It focuses on the strategic and tactical conflicts between the two firms and traces these to the party's emotional reactions to the combination. Feeling of loss versus gain in the two firms, each party's sense of uncertainty and threat, and their moves toward proactive versus reactive control in the combination are analysed to identify the roots of strategic conflict. These feelings, plus incompatibilities in the two company's managements, business systems, corporate cultures, and goals for combination ramify in conflict in the negotiations themselves. The paper concludes with a more generic model illustrating contextual features of combinations that shape human reactions and conflicts in negotiations after the sale.     

Evaluating the respiratory bioaccessibility of nickel in soil through the use of a simulated lung fluid

Simulated lung fluids are solutions designed to mimic the composition of human interstitial lung fluid as closely as possible. Analysis of mineral dusts using such solutions has been used to evaluate the respiratory bioaccessibility of various elements for which solubility in the lungs is a primary determinant of reactivity. The objective of this study was to employ simulated lung fluid analysis to investigate the respiratory bioaccessibility of nickel in soils. Current occupational guidelines in Australia regulate nickel compounds in terms of water solubility, though this may not be an accurate estimation of the total nickel that will dissociate in the lungs. Surface soils were collected from the city of Kalgoorlie in Western Australia, the site of an operational nickel smelter and metal mining activities. The fraction of the samples less than 10 μm was extracted from the soil, and it was this sub-10-μm fraction that was found to hold most of the total nickel present in the soil. The fine fraction was analyzed using a simulated lung fluid (modified Gamble’s solution) to isolate the nickel phases soluble in the lungs. In addition, a sequential extraction was employed to compare the bioaccessible fraction to those dissolved from different binding forms in the soil. In all samples, the simulated lung fluid extracted more nickel than the two weakest leaches of the sequential extraction combined, providing a more representative nickel bioaccessibility value than the current water leach method.