Graft Copolymers, for Erodible Resins, from α-Hydroxyacids Oligomers Macromonomers and Acrylic Monomers

Environmental concerns result in a progressive withdrawal of antifouling paints containing organotin derivatives. The nature of the binders is critical with regard to the erosion of the protecting film through factors such as bond cleavage, dissolution, and diffusion of the degradation products. The versatility of acrylic polymers, due to the possibility of varying their chemical structure had conducted, in the first stage, to combine different types of repeating units in the macromolecular backbone. Formulation and evaluation, in natural sites, of these binders, with a well-defined hydrophobic/hydrophilic balance and with hydrolyzable pendant groups, have shown the possibility to prepare new organotin free resins which can be formulated and which are erodible in seawater over a long period (more than 2 years). A further step has been engaged with the development of graft copolymers containing biocompatible and hydrolyzable oligomers of -hydroxyacids. Their preparation requires the synthesis of -methacryloyloxyoligo--hydroxyacid macromonomers. Copolymers prepared from a mixture of the macromonomer and of an alkyl ester of acrylic acid were formulated with a biocide and deposited on a plate. Their ability to release cuprous oxide, as a model molecule, has been checked and quantified by the inductively coupled plasma analytical method. The uptake of water in the paint, which is enhanced by the hydrolysis of -hydroxyacid oligomers, as determined by the enzymatic measurement of liberated L-lactic acid, conducts to the polymer erosion and to a protecting bioactive surface.     

Motivating workers in emerging countries: universal tools and local adaptations

Two case studies are presented of highly successful factories operating in emerging countries. Sgs‐Thomson in Morocco and Danone in Mexico provide exemplars of ways in which corporate cultures can promote productive, efficient, and interpersonally supportive communities by building upon deep‐seated local values that give these communities special meaning to members. In Morocco, Islamic norms and values combined with Total Quality Management values to transform Sgs‐Thomson's factory culture. In Mexico, norms and values regarding family and the pursuit of a higher moral purpose underpinned a workplace transformation combining economic and social progress. This essay also develops the implications of these cases for the dissemination, adoption, and malleability of global management practices. Copyright © 2002 John Wiley & Sons, Ltd.     

Surface roughness prediction in milling based on tool displacements

In this paper, an experimental device using non-contact displacement sensors for the investigation of milling tool behaviour is presented. It enables the recording of high frequency tool vibrations during milling operations. The aim of this study is related to the surface topography prediction using tool displacements and based on tool center point methodology. From the recorded signals and the machining parameters, the tool deformation is modeled. Then, from the calculated deflection, the surface topography in 3D can be predicted. In recent studies, displacements in XY plane have been measured to predict the surface topography in flank milling. In this article, the angular deflection of the tool is also considered. This leads to the prediction of surfaces obtained in flank milling as well as in end milling operations. Validation tests were carried out: the predicted profiles were compared to the measured profile. The results show that the prediction corresponds well in shape and amplitude with the measurement.     

The first definitive Asian spinosaurid (Dinosauria: Theropoda) from the early cretaceous of Laos

Spinosaurids are among the largest and most specialized carnivorous dinosaurs. The morphology of their crocodile-like skull, stomach contents, and oxygen isotopic composition of the bones suggest they had a predominantly piscivorous diet. Even if close relationships between spinosaurids and Middle Jurassic megalosaurs seem well established, very little is known about the transition from a generalized large basal tetanuran to the specialized morphology of spinosaurids. Spinosaurid remains were previously known from the Early to Late Cretaceous of North Africa, Europe, and South America. Here, we report the discovery of a new spinosaurid theropod from the late Early Cretaceous Savannakhet Basin in Laos, which is distinguished by an autapomorphic sinusoidal dorsosacral sail. This new taxon, Ichthyovenator laosensis gen. et sp. nov., includes well-preserved and partially articulated postcranial remains. Although possible spinosaurid teeth have been reported from various Early Cretaceous localities in Asia, the new taxon I. laosensis is the first definite record of Spinosauridae from Asia. Cladistic analysis identifies Ichthyovenator as a member of the sub-clade Baryonychinae and suggests a widespread distribution of this clade at the end of the Early Cretaceous. Chilantaisaurus tashouikensis from the Cretaceous of Inner Mongolia, and an ungual phalanx from the Upper Jurassic of Colorado are also referred to spinosaurids, extending both the stratigraphical and geographical range of this clade.     

Are bioplastics an ecofriendly alternative to fossil fuel plastics?

Environmental Chemistry Letters - More than 390 million tons of fossil fuel plastics have been produced in 2022, and plastic pollution has become a major health issue for humans and ecosytems....     

生命周期评价与社会影响

生命周期评价(LCA)在提供数据、管理工具、软件和方法论中再加之更精确的测定方面已经取得了巨大的进步,然而与此同时仍然还有许多问题要解决.许多这些问题涉及到LCA方法在世界范围内的推广,以及这些方法如何通过建立数据库和按当地需要定制管理工具而适应发展中国家.     

Northeast Arctic cod population persistence in the Lofoten-Barents Sea system under fishing.

Population growth, and hence the population's persistence, is affected by several factors such as climate, species interaction, and harvesting pressure. Proper resource management requires an understanding of these factors. We apply techniques based upon age-structured population matrices to analyze estimated stock sizes derived from annual bottom trawl sampling in the winter feeding area of northeast Arctic cod (Gadus morhua L.) from 1981 to 2003. We run generalized additive models to explain population growth rate by different explanatory variables. Cod population growth was found to be positively related to the abundance of capelin (Mallotus villosus Miller), negatively related to the number of cannibalistic cod with a two-year lag, and marginally positively related to the winter North Atlantic Oscillation index (NAO). This model remains true independently from the population status (i.e., fished or non-fished). Capelin abundance is the main variable that to some degree can be adjusted in order to maintain the population size at a given level of cod harvesting. Our results point to the importance of managing conjointly cod and capelin stocks.     

Sterol production and phytosterol bioconversion in two species of heterotrophic protists, Oxyrrhis marina and Gyrodinium dominans

The kinetics and efficiency of sterol production and bioconversion of phytosterols in two heterotrophic protists Oxyrrhis marina and Gyrodinium dominans were examined by feeding them two different algal species (Rhodomonas salina and Dunaliella tertiolecta) differing in sterol profiles. R. salina contains predominantly brassicasterol (?99%) and <2% cholesterol. The major sterols in D. tertiolecta are ergosterol (45–49%), 7-dehydroporiferasterol (29–31%) and fungisterol (21–26%). O. marina fed R. salina metabolized dietary brassicasterol to produce 22-dehydrocholesterol and cholesterol. O. marina fed D. tertiolecta metabolized dietary sterols to produce cholesterol, 22-dehydrocholesterol, brassicasterol and stigmasterol. G. dominans fed either R. salina or D. tertiolecta metabolized dietary sterols to make cholesterol, brassicasterol and a series of unknown sterols. When protists were fed R. salina, which contains cholesterol, the levels of cholesterol were increased to a magnitude of nearly 5- to 30-fold at the phytoplankton-heterotrophic protist interface, equivalent to a production of 172.5 ± 16.2 and 987.7 ± 377.7 ng cholesterol per mg R. salina carbon consumed by O. marina and G. dominans, respectively. When protists were fed D. tertiolecta, which contains no cholesterol, a net production of cholesterol by the protists ranged from 123.2 ± 30.6 to 871.8 ± 130.8 ng per mg algal C consumed. Cholesterol is not only the dominant sterol, but a critical precursor for many physiologically functional biochemicals in higher animal. As intermediates, these heterotrophic protists increase the amount of cholesterol at the phytoplankton–zooplankton interface available to higher trophic levels relative to zooplankton feeding on algae directly.     

Pollution-Adjusted Productivity Changes: Extending the Färe–Primont Index with an Illustration with French Suckler Cow Farms

Environmental Modeling & Assessment - Several approaches have been proposed in the literature to compute technical efficiency indices that account for bad outputs. The literature is, however,...     

Effect of wearing hearing protectors on the audibility of railway warning signals – an experimental study

The effect of wearing hearing protectors on the audibility of warning signals has been evaluated for three specific railway-related jobs: track workers, train drivers and platform agents. Masked thresholds were measured in the laboratory, on railway agents with normal hearing, using warning signals and background noises typical of each job. Out of the 36 situations tested in total, statistical analyses showed that wearing earplugs improves the perception in 11 situations, deteriorates the perception in 10 situations and has no significant effect in 15 situations (as compared to no hearing protector). The deteriorations essentially concern signals which have no (or not enough) energy in the low-frequency range (ff相似文献