Economic appraisal and evaluation of UK waste minimisation clubs: proposals to inform the design of sustainable clubs

Waste minimisation clubs have been established for some 12 years in the UK. During that time, they have been significant driving forces in disseminating sustainable waste management practices in industry and commerce. Clubs have also demonstrated that they can achieve significant reductions in levels of waste. However, data on the economic benefits of these clubs remain scanty and disparate. In addition, no standard methodology has developed to assess whether the investment costs of clubs can be justified on grounds of either economic welfare or sustainable development, despite the theoretical advantages from doing so. Against this background, the paper considers the need for economic appraisal and evaluation of waste minimisation clubs and discusses how these methods could be applied to the creation of clubs that will be sustainable over time.     

Impact of sample preparation on mineralogical analysis of zero-valent iron reactive barrier materials

Permeable reactive barriers (PRBs) of zero-valent iron (Fe(0)) are increasingly being used to remediate contaminated ground water. Corrosion of Fe(0) filings and the formation of precipitates can occur when the PRB material comes in contact with ground water and may reduce the lifespan and effectiveness of the barrier. At present, there are no routine procedures for preparing and analyzing the mineral precipitates from Fe(0) PRB material. These procedures are needed because mineralogical composition of corrosion products used to interpret the barrier processes can change with iron oxidation and sample preparation. The objectives of this study were (i) to investigate a method of preparing Fe(0) reactive barrier material for mineralogical analysis by X-ray diffraction (XRD), and (ii) to identify Fe mineral phases and rates of transformations induced by different mineralogical preparation techniques. Materials from an in situ Fe(0) PRB were collected by undisturbed coring and processed for XRD analysis after different times since sampling for three size fractions and by various drying treatments. We found that whole-sample preparation for analysis was necessary because mineral precipitates occurred within the PRB material in different size fractions of the samples. Green rusts quickly disappeared from acetone-dried samples and were not present in air-dried and oven-dried samples. Maghemite/magnetite content increased over time and in oven-dried samples, especially after heating to 105 degrees C. We conclude that care must be taken during sample preparation of Fe(0) PRB material, especially for detection of green rusts, to ensure accurate identification of minerals present within the barrier system.     

English county councils and their agenda for waste minimisation

Minimisation is the top priority of the waste management hierarchy, which is one of the guiding principals for national solid waste management planning throughout the developed world. As such it should be encouraged as a means for reducing wastes which require treatment and disposal, whether they be household, commercial or industrial in source. This paper suggests that minimisation is not being given the necessary policy frameworks or legislation within which to develop in the UK, and questions whether minimisation is being afforded the respect and attention, from all levels, that is due the most preferable waste option according to the hierarchy. This theme is investigated by surveying the county councils of England as a representative sample of waste disposal authorities in England, and former waste regulation authorities. They are responsible for guiding local and district waste policy and are the regional waste planners in the UK. If they are not seriously taking on board the message of minimisation, then there is little chance that it will succeed without further legislative developments. Some 59% of English counties have a minimisation policy, whilst only 47% have participated in and supported a minimisation programme or trial within their region. The majority of these developments have occurred within the last three years, and 78% of counties who have participated in a programme have found it a successful venture. By 1999 79% of English counties will have been actively involved in a minimisation programme in their region, which is a positive scenario. This trend must continue if waste minimisation is to become the key theme of future sustainable waste management in the UK as was intended by declarations at the Rio '92 conference and in subsequent UK Government policy and strategy.     

WATERSHEDSS: A DECISION SUPPORT SYSTEM FOR WATERSHED-SCALE NONPOINT SOURCE WATER QUALITY PROBLEMS1

ABSTRACT: A significant portion of all pollutants entering surface waters (streams, lakes, estuaries, and wetlands) derives from non-point source (NPS) pollution and, in particular, agricultural activities. The first step in restoring a water resource is to focus on the primary water quality problem in the watershed. The most appropriate NPS control measures, which include best management practices (BMPs) and landscape features, such as wetlands and riparian areas, can then be selected and positioned to minimize or mitigate the identified pollutant(s). A computer-based decision sup. port and educational software system, WATERSHEDSS (WATER, Soil, and Hydro-Environmental Decision Support System), has been developed to aid managers in defining their water quality problems and selecting appropriate NPS control measures. The three primary objectives of WATERSHEDSS are (1) to transfer water quality and land treatment information to watershed managers in order to assist them with appropriate land management/land treatment decisions; (2) to assess NPS pollution in a watershed based on user-supplied information and decisions; and (3) to evaluate, through geographical information systems-assisted modeling, the water quality effects of alternative land treatment scenarios. WATERSHEDSS is available on the World Wide Web (Web) at http://h2osparc.wq.ncsu.edu .     

Nonpoint source pollution risk assessment in a watershed context

Nonpoint source pollution control requires assessment of the influence of dispersed runoff-contributing areas on downstream water quality. This evaluation must consider two separate phases: site-to-stream loading and downstream fluvial transport. Any model, combination of models, or procedure for making this assessment can be generalized to a simple spatial model or framework, which considers runoff or pollutant loading per unit area and down-stream attenuation, with drainage area as a scaling factor. This spatial model has a probabilistic interpretation and can be used in conjunction with a standard dilution model to give a probabilistic estimate of the impacts at the basin mouth of runoff from a specific upstream contributing area. It is illustrated by applying it to an assessment of the probability that various copper concentrations at the mouth of the urbanized South Platte River basin in Denver, Colorado, USA, will be exceeded as a result of runoff from a subbasin within the city. Determining the probability that a concentration of a pollutant at the basin mouth can be attributed to runoff from a discrete area within the basin is useful for targeting and risk assessment because it enables quantitative risk-based comparisons. The spatial framework is also useful for evaluating management and control options, since actions within the basin can be directly linked to water quality at a downstream point.     

ESTIMATION OF DRAINAGE AREAS IN A HOMOGENEOUS LANDSCAPE1

In areas where there is little or no topographic relief and where soils, vegetation, geologic structure and other factors are essentially uniform, identification of drainage basin boundaries is difficult or impossible. In such a homogeneous landscape, however, assumptions may be made that the hydrologic and geomorphic controls over drainage basin development are constant within the area. If this is true, it is suggested, the drainage area of a stream is related solely to the stream length and factors governing the length-area relationship are also constant. A simple formula based on these assumptions and the gravity model is proposed which can be used to estimate drainage divides in a homogeneous landscape.     

Causes of ambient toxicity in the Calleguas Creek watershed of southern California

A combination of toxicity tests, chemical analyses, andToxicity Identification Evaluations (TIEs) were used toinvestigate receiving water toxicity in the Calleguas Creekwatershed of southern California. Studies were conductedfrom 1995 through 1999 at various sites to investigatecauses of temporal variability of toxicity throughout thissystem. Causes of receiving water toxicity varied by siteand species tested. Investigations in the lower watershed(Revolon Slough, Santa Clara Drain, Beardsley Wash)indicated that toxicity of samples to the cladoceran Ceriodaphnia dubia due to elevated concentrations ofthe organophosphate pesticide chlorpyrifos, while causes ofintermittent toxicity to fathead minnows (Pimephalespromelas) and the alga Selanastrum capricornutum wereless clear. Investigations at sites in the middle and upperreaches of the watershed (Arroyo Simi and Conejo Creek)indicated that the pesticide diazinon was the probable causeof receiving water toxicity to Ceriodaphnia. Elevatedammonia was the cause of toxicity to fathead minnows in theupper watershed sites. Results of these and previousstudies suggest that biota are impacted by degraded streamquality from a variety of point and non-point pollutionsources in the Calleguas Creek watershed. Water qualityresource manager's efforts to identify contaminant inputsand implement source control will be improved with thefindings of this study.     

Spatial Relationships Between Water Quality and Pesticide Application Rates in Agricultural Watersheds

Pesticide applications to agricultural lands in California, USA, are reported to a central data base, while data on water and sediment quality are collected by a number of monitoring programs. Data from both sources are geo-referenced, allowing spatial analysis of relationships between pesticide application rates and the chemical and biological condition of water bodies. This study collected data from 12 watersheds, selected to represent a range of pesticide usage. Water quality parameters were measured during six surveys of stream sites receiving runoff from the selected watershed areas. This study had three objectives: to evaluate the usefulness of pesticide application data in selecting regional monitoring sites, to provide information for generating and testing hypotheses about pesticide fate and effects, and to determine whether in-stream nitrate concentration was a useful surrogate indicator for regional monitoring of toxic substances. Significant correlations were observed between pesticide application rates and in-stream pesticide concentrations (p < 0.05) and toxicity (p < 0.10). In-stream nitrate concentrations were not significantly correlated with either the amount of pesticides applied, in-stream pesticide concentrations, or in-stream toxicity (all p > 0.30). Neither total watershed area nor the area in which pesticide usage was reported correlated significantly with the amount of pesticides applied, in-stream pesticide concentrations, or in-stream toxicity (all p > 0.14). In-stream pesticide concentrations and effects were more closely related to the intensity of pesticide use than to the area under cultivation.     

Response of the predatorRhizophagus grandis to host plant derived chemicals inDendroctonus micans larval frass in wind tunnel experiments (Coleoptera: Rhizophagidae,Scolytidae)

Summary Adults of the predatory beetleRhizophagus grandis are strongly attracted to both adult and larval frass of its specific prey,Dendroctonus micans, in walking bioassays. Spruce bark and resin are relatively unattractive. Solvent extracts of larval frass that were attractive toR. grandis adults in a flight wind tunnel contained a mixture of monoterpenes of host plant origin. A synthetic mixture of these monoterpenes, (+)—-pinene, (–)—-pinene, -phellandrene,dl limonene and 3-carene, was responsible for 70–80% of the activity of the most attractive extract. We suggest that a blend of monoterpenes in frass acts as a kairomone forR. grandis but that attraction to monoterpenes is only the first of a sequence of behavioural responses that ensures successful host location and identification.     

Distribution of uranium contamination in weathered fractured saprolite/shale and ground water

The objective of this study was to determine how structure, stratigraphy, and weathering influence fate and transport of contaminants (particularly U) in the ground water and geologic material at the Department of Energy (DOE) Environmental Remediation Sciences Department (ERSD) Field Research Center (FRC). Several cores were collected near four former unlined adjoining waste disposal ponds. The cores were collected, described, analyzed for U, and compared with ground water geochemistry from surrounding multilevel wells. At some locations, acidic U-contaminated ground water was found to preferentially flow in small remnant fractures weathering the surrounding shale (nitric acid extractable U [U(NA)] usually < 50 mg kg(-1)) into thin (<25 cm) Fe oxide-rich clayey seams that retain U (U(NA) 239 to 375 mg kg(-1)). However, greatest contaminant transport occurs in a 2 to 3 m thick more permeable stratigraphic transition zone located between two less permeable, and generally less contaminated zones consisting of (i) overlying unconsolidated saprolite (U(NA) < 0.01 to 200 mg kg(-1)) and (ii) underlying less-weathered bedrock (U(NA) generally < 0.01 to 7 mg kg(-1)). In this transition zone, acidic (pH < 4) U-enriched ground water (U of 38 mg L(-1)) has weathered away calcite veins resulting in greater porosity, higher hydraulic conductivity, and higher U contamination (U(NA) 106 to 745 mg kg(-1)) of the weathered interbedded shale and sandstone. These characteristics of the transition zone produce an interval with a high flux of contaminants that could be targeted for remediation.