全文获取类型
收费全文 | 4942篇 |
免费 | 440篇 |
国内免费 | 1942篇 |
专业分类
安全科学 | 458篇 |
废物处理 | 235篇 |
环保管理 | 348篇 |
综合类 | 3293篇 |
基础理论 | 762篇 |
污染及防治 | 1452篇 |
评价与监测 | 287篇 |
社会与环境 | 294篇 |
灾害及防治 | 195篇 |
出版年
2024年 | 18篇 |
2023年 | 123篇 |
2022年 | 318篇 |
2021年 | 260篇 |
2020年 | 252篇 |
2019年 | 191篇 |
2018年 | 213篇 |
2017年 | 248篇 |
2016年 | 259篇 |
2015年 | 294篇 |
2014年 | 390篇 |
2013年 | 501篇 |
2012年 | 434篇 |
2011年 | 412篇 |
2010年 | 335篇 |
2009年 | 342篇 |
2008年 | 356篇 |
2007年 | 330篇 |
2006年 | 351篇 |
2005年 | 262篇 |
2004年 | 172篇 |
2003年 | 176篇 |
2002年 | 144篇 |
2001年 | 135篇 |
2000年 | 129篇 |
1999年 | 126篇 |
1998年 | 87篇 |
1997年 | 70篇 |
1996年 | 70篇 |
1995年 | 78篇 |
1994年 | 66篇 |
1993年 | 52篇 |
1992年 | 34篇 |
1991年 | 29篇 |
1990年 | 17篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 10篇 |
1986年 | 6篇 |
1985年 | 2篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1976年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有7324条查询结果,搜索用时 15 毫秒
211.
选取沙丁胺醇(salbutamol,SAL)为目标污染物,研究了3种碳纳米管(CNTs,单壁碳纳米管SCNT、羟基衍生化多壁碳纳米管MWNT-OH和羧基衍生化多壁碳纳米管MWNT-COOH)对有机污染物在模拟太阳光照下降解的影响;并且研究了CNTs与天然水体中光活性物质三价铁离子(Fe3+)的相互作用.结果表明,3种CNTs能够通过竞争吸收光子,即光屏蔽作用抑制SAL光解;同时又能通过光致激发产生单线态氧(1O2)促进光解反应,两种作用机制同时存在,在绝大多数情况下,抑制作用占主导地位.此外,CNTs还能通过静电吸附作用使水体中的光活性物质Fe3+失活,从而影响有机污染物在天然水体中的光化学行为. 相似文献
212.
微生物对汞矿区农田土壤汞甲基化的影响 总被引:2,自引:1,他引:1
为研究典型汞矿区农田土壤中汞的甲基化作用,实验以受汞污染的旱田土壤和稻田土壤为对象,分别进行灭菌,促进硫酸盐还原菌(SRB)活性处理,抑制SRB活性处理以及促进铁还原菌(FeRB)活性处理,分析非微生物作用和微生物作用对土壤甲基汞(MeHg)生成的影响.结果表明,促进SRB活性处理的土壤MeHg生成量最高,其中旱田土MeHg增量为0.15~0.38μg·kg~(-1),稻田土壤MeHg增量为1~2μg·kg~(-1);抑制SRB活性处理和促进FeRB活性处理的MeHg增量较小,最高值仅为0.025μg·kg~(-1).相比于旱田土壤,稻田土壤具有更高的汞甲基化能力,其MeHg生成量是旱田土壤的4~9倍.土壤SRB数量与MeHg生成量具有相同的变化趋势,二者具有显著的正相关性(R~2=0.57,P0.01).因此,该研究区土壤汞甲基化作用主要是微生物汞甲基化作用,且主要的汞甲基化细菌是SRB.此外,稻田是农田中MeHg生成的活跃地区,在评估和控制MeHg对人体健康危害时需要重点关注. 相似文献
213.
Rainwater contains substantial bacteria and rain is an efficient pathway for the dissemination of bacteria from the atmosphere to land and water surfaces.However,quantitative information on rainwater bacteria is very limited due to the lack of a reliable method.In this study,the epifluorescence microscopy enumeration with the LIVE/DEAD BacLight Bacterial Viability Kit stain was verified to quantify the abundance of viable and non-viable bacterial cells in rainwater,with the 4',6-diamidino-2-phenylindole(DAPI) stain for the reference of total cell counts.Results showed that the total counts of bacterial cells by LIVE/DEAD BacLight staining were consistent with those by DAPI staining,and the average detection efficiency was(109 ± 29)%.The ratio of cell count with glutaraldehyde fixation to that without fixation was(106 ± 5)%on average.The bacterial concentration in negative control was usually an order of magnitude lower than that in rainwater samples.However,in case of small precipitation,the abundance in negative control could be more than that in rainwater samples.These results indicate that the enumeration with LIVE/DEAD BacLight bacterial viability assay coupled with glutaraldehyde fixation and careful negative control investigation is an approach applicable to the measurement of the concentration and viability of bacterial cells in rainwater. 相似文献
214.
Atrazine, a widely used herbicide, is increasing the agricultural production effectively, while also causing great environmental concern. Efficient atrazine-degrading bacterium is necessary to removal atrazine rapidly to keep a safe environment. In the present study, a new atrazine-degrading strain ZXY-1, identified as Pseudomonas, was isolated. This new isolated strain has a strong ability to biodegrade atrazine with a high efficiency of 9.09 mg/L/hr.Temperature, p H, inoculum size and initial atrazine concentration were examined to further optimize the degradation of atrazine, and the synthetic effect of these factors were investigated by the response surface methodology. With a high quadratic polynomial mathematical model(R~2= 0.9821) being obtained, the highest biodegradation efficiency of 19.03 mg/L/hr was reached compared to previous reports under the optimal conditions(30.71°C, pH 7.14, 4.23%(V/V) inoculum size and 157.1 mg/L initial atrazine concentration).Overall, this study provided an efficient bacterium and approach that could be potentially useful for the bioremediation of wastewater containing atrazine. 相似文献
215.
Engineered oxide nanoparticles (NPs) are widely applied in insulators, catalyzers, paints, cosmetic products, textiles and semiconductors. Their attachment on cell membrane may lead to cytotoxicity. The effects of Al2O3, Fe2O3, SiO2, TiO2 and ZnO NPs on membrane integrity and fluidity were studied using giant or small unilamellar vesicles in this study. Al2O3 and SiO2 NPs disrupted the oppositely charged membrane, indicating the important role of electrostatic attraction. However, Fe2O3, TiO2 and ZnO NPs did not cause serious membrane disruption as Al2O3 and SiO2 NPs. Membrane fluidity was evaluated by the generalized polarity (GP) values of Laurdan fluorescent emission. SiO2 NPs induce the membrane gelation of both positively and negatively charged membrane. Al2O3 and ZnO NPs induced the gelation of the oppositely charged membrane, but did not cause obvious membrane gelation to the like charged membrane. The phospholipid molecular structural changes after NP exposure were analyzed by Fourier transform infrared (FT-IR) spectroscopy. FT-IR spectra revealed the hydrogen bond formation between NPs and the carbonyl/phosphate groups of phospholipids. Al2O3 and SiO2 NPs showed strongest evidence of hydrogen bonding on their FT-IR spectra. It was consistent with the microscopic observation and fluorescent data that Al2O3 and SiO2 NPs caused more serious membrane disruption and gelation. This study on membrane damage provides further knowledge on the cytotoxicity of nanomaterials and the safety of NP application. 相似文献
216.
217.
218.
A simple approach to enhance the photocatalytic activity of red phosphorus(P) was developed.A mechanical ball milling method was applied to reduce the size of red P and to deposit graphene quantum dots onto red P. The product was characterized by scanning electron microscopy, transmission electron microscopy, contact angle measurements, zeta-potential measurements, X-ray diffraction and UV–vis absorption spectroscopy. The product exhibited high visible-light-driven photocatalytic performance in the photodegradation of rhodamine B. 相似文献
219.
220.
目的识别除湿机的性能状态和预测吸附剂的剩余寿命。方法针对除湿机故障过程缓变的特点,提出一种基于数据驱动的遗传神经网络模型。首先,为解决设备失效程度划分模糊的问题,由5个热力参数组成反映吸附剂劣化程度的特征向量,关联分析得到除湿机的5类故障模式。其次,利用遗传神经网络建立状态参数和故障模式的映射关系。最后,对表征设备吸附能力的主参数进行外推预测。结果训练好的诊断网络可准确地识别出设备的劣化程度及其演变过程,预测网络的预测精度非常高。结论该方法可有效地实现对除湿机的故障诊断与预测。。 相似文献