全文获取类型
收费全文 | 195篇 |
免费 | 0篇 |
国内免费 | 4篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 5篇 |
环保管理 | 11篇 |
综合类 | 37篇 |
基础理论 | 40篇 |
污染及防治 | 86篇 |
评价与监测 | 9篇 |
社会与环境 | 6篇 |
灾害及防治 | 2篇 |
出版年
2021年 | 3篇 |
2017年 | 1篇 |
2016年 | 6篇 |
2015年 | 4篇 |
2014年 | 3篇 |
2013年 | 14篇 |
2012年 | 6篇 |
2011年 | 20篇 |
2010年 | 13篇 |
2009年 | 16篇 |
2008年 | 8篇 |
2007年 | 8篇 |
2006年 | 17篇 |
2005年 | 15篇 |
2004年 | 14篇 |
2003年 | 8篇 |
2002年 | 7篇 |
2001年 | 1篇 |
2000年 | 6篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1965年 | 3篇 |
1964年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有199条查询结果,搜索用时 718 毫秒
21.
Determination of polyfluoroalkyl compounds in water and suspended particulate matter in the river Elbe and North Sea, Germany 总被引:1,自引:0,他引:1
Lutz Ahrens Merle Plassmann Zhiyong Xie Ralf Ebinghaus 《Frontiers of Environmental Science & Engineering in China》2009,3(2):152-170
The distribution of polyfluoroalkyl compounds (PFCs) in the dissolved and particulate phase and their discharge from the river
Elbe into the North Sea were studied. The PFCs quantified included C4-C8 perfluorinated sulfonates (PFSAs), 6:2 fluorotelomer sulfonate (6:2 FTS), C6 and C8 perfluorinated sulfinates (PFSiAs), C4-C12 perfluorinated carboxylic acids (PFCAs), perfluoro-3,7-dimethyl-octanoic acid (3,7m2-PFOA), perfluorooctane sulfonamide (FOSA), and n-ethyl perfluroctane sulfonamidoethanol (EtFOSE). PFCs were mostly distributed
in the dissolved phase, where perfluorooctanoic acid (PFOA) dominated with 2.9–12.5 ng/L. In the suspended particulate matter
FOSA and perfluorooctane sulfonate (PFOS) showed the highest concentrations (4.0 ng/L and 2.3 ng/L, respectively). The total
flux of ΣPFCs from the river Elbe was estimated to be 802 kg/year for the dissolved phase and 152 kg/year for the particulate
phase. This indicates that the river Elbe acts as a source of PFCs into the North Sea. However, the concentrations of perfluorobutane
sulfonate (PFBS) and perfluorobutanoic acid (PFBA) in the North Sea were higher than that in the river Elbe, thus an alternative
source must exist for these compounds. 相似文献
22.
We used the interdisciplinary model network REGFLUD to predict the actual mean nitrate concentration in percolation water at the scale of the Weser river basin (Germany) using an area differentiated (100 m × 100 m) approach.REGFLUD combines the agro-economic model RAUMIS for estimating nitrogen surpluses and the hydrological models GROWA/DENUZ for assessing the nitrate leaching from the soil.For areas showing predicted nitrate concentrations in percolation water above the European Union (EU) groundwater quality standard of 50 mg NO 3 -N/L,effective agri-environmental reduction measures need to be derived and implemented to improve groundwater and surface water quality by 2015.The effects of already implemented agricultural policy are quantified by a baseline scenario projecting the N-surpluses from agricultural sector to 2015.The REGFLUD model is used to estimate the effects of this scenario concerning groundwater and surface water pollution by nitrate.From the results of the model analysis the needs for additional measures can be derived in terms of required additional N-surplus reduction and in terms of regional prioritization of measures.Research work will therefore directly support the implementation of the Water Framework Directive of the European Union in the Weser basin. 相似文献
23.
We used the interdisciplinary model network REGFLUD to predict the actual mean nitrate concentration in percolation water at
the scale of the Weser river basin (Germany) using an area di erentiated (100 m 100 m) approach. REGFLUD combines the
agro-economic model RAUMIS for estimating nitrogen surpluses and the hydrological models GROWA/DENUZ for assessing the
nitrate leaching from the soil. For areas showing predicted nitrate concentrations in percolation water above the European Union (EU)
groundwater quality standard of 50 mg NO3-N/L, e ective agri-environmental reduction measures need to be derived and implemented
to improve groundwater and surface water quality by 2015. The e ects of already implemented agricultural policy are quantified by
a baseline scenario projecting the N-surpluses from agricultural sector to 2015. The REGFLUD model is used to estimate the e ects
of this scenario concerning groundwater and surface water pollution by nitrate. From the results of the model analysis the needs
for additional measures can be derived in terms of required additional N-surplus reduction and in terms of regional prioritization of
measures. Research work will therefore directly support the implementation of the Water Framework Directive of the European Union
in the Weser basin. 相似文献
24.
Ralf Schulz Maike Hauschild Markus Ebeling Jakob Nanko-Drees Joem Wogram Mathias Liess 《Chemosphere》1998,36(15):3071-3082
A field method is described, which allows the qualitative estimation of pesticide contamination in the edgeof-field runoff. The method employs cheap and easy-to-use runoff sampling bottles, which were installed in an agricultural stream catchment over a period of three growing seasons. During this time 18 runoff events were detected, in nine of which insecticide contamination was measured (maximum concentrations: lindane 0.7 μg l−1 and 12.7 μg kg−1, parathion 20 μg l−1 and 728 μg kg−, fenvalerate 18.4 μg 1-1 and 924 μg kg−1). These insecticides were detected mainly as particle-bound chemicals. On about 80 % of the occasions the presence or absence of runoff measured in the field was in agreement with a simulation of runoff presence or absence using the runoff model KINEROS. 相似文献
25.
Organic residue decomposition: The minicontainer-system a multifunctional tool in decomposition studies 总被引:1,自引:0,他引:1
Gerhard Eisenbeis Ralf Lenz Thomas Heiber 《Environmental science and pollution research international》1999,6(4):220-224
The Minicontainer-test, first described by Eisenbeis (1993), was designed to study the kinetics of organic residue decomposition
at a microsite level. It is derived from the litterbag technique and consists of polyethylene minicontainers (volume about
1.5 cm3) filled with a test substrate (litter, straw, cellulose, etc.). The minicontainers (MCs) are closed at either end with plastic
gauze discs of variable mesh size (e.g. 20 μm, 250 μm, 500 μm or 2 mm). A definite number of such units are inserted into
PVC-bars, which can be implanted into the soil horizontally or vertically, or be exposed on the soil surface horizontally.
The bars are very stable and can be exposed in different environments for months to years. If required, the bars can be removed
temporarily and stored, e.g. during soil cultivation. Should fresh litter be used, two phases of decomposition can be distinguished:
a fast initial phase, which can be mainly related to the effect of leaching, and a second slow phase depending mainly on the
activity of soil organisms and litter quality. Several questions can be addressed to investigations using MCs, e.g. 1) parts
of the soil fauna which are involved in decomposition (nematodes, microarthropods, and smaller specimens of the macrofauna,
e.g. enchytraeidae, diplopods and dipteran larvae) can be extracted from the litter substrate using a miniscale high gradient
extractor, 2) the organic mass loss of litter can be determined, 3) microbial biomass (Cmic, Nmic) can be assessed by fumigation extraction and 4) microbial activity (respiration) in the test substrate can also be assessed
by use of standardised methods. Compared to litterbag studies, the larger number of small replicate units improves the statistical
evaluation. Until today the Minicontainer-test has been applied in forestry and agriculture, e.g. studying the effects of
liming, soil restoration and the application of insecticides, e.g. Diflubenzuron (Dimilin) and Btk (Bacillus thuringiensis var.kurstaki). 相似文献
26.
With the advancement of computational systems and the development of model integration concepts, complexity of environmental model systems increased. In contrast to that, theory and knowledge about > environmental systems as well as the capability for environmental systems analyses remained, to a large extent, unchanged. As a consequence, model conceptualization, data gathering, and validation, have faced new challenges that hardly can be tackled by modellers alone. In this discourse-like review, we argue that modelling with reliable simulations of human-environmental interactions necessitate linking modelling and simulation research much stronger to science fields such as landscape ecology, community ecology, eco-hydrology, etc. It thus becomes more and more important to identify the adequate degree of complexity in environmental models (which is not only a technical or methodological question), to ensure data availability, and to test model performance. Even equally important, providing problem specific answers to environmental problems using simulation tools requires addressing end-user and stakeholder requirements during early stages of problem development. In doing so, we avoid modelling and simulation as an end of its own. 相似文献
27.
High frequency CO2 and wind speed measurements were used to examine the urban baseline eddy covariance CO2 flux and analyse the CO2 rich plume from a local power station. A reliable relationship between high frequency CO2 maxima and the rate of CO2 emission at the power station was established. This relationship was shown to be highly dependant on wind speed. The ensemble mean plume was found to be Gaussian in horizontal profile with a width dependant on wind speed. The relationship between peak CO2 mixing ratio and averaging time was shown to be a simple power law with a time exponent of approximately 0.5. The large, short pulses in CO2 mixing ratio in the power plant plume were found to have an approximately Lorentzian shape. These pulses generated negative vertical eddy flux measurements so data from the plume sector were necessarily excluded from the flux baseline results. The plume-excluded flux had a similar magnitude and variability to those reported in other urban CO2 flux studies despite this site not being ideal due to the proximity of roughness elements to the measurement point. 相似文献
28.
Organophosphorus flame retardants and plasticizers in the atmosphere of the North Sea 总被引:1,自引:0,他引:1
Möller A Xie Z Caba A Sturm R Ebinghaus R 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3660-3665
Air samples collected in the German part of the North Sea from March to July 2010 were investigated for organophosphorus compounds (OPs) being applied as flame retardants and plasticizers. The ∑8OPs concentration ranged from 110 to 1400 pg m−3 while tris(2-chloroisopropyl) phosphate (TCPP) dominated all samples with individual concentrations up to 1200 pg m−3. The highest concentrations were observed in continental air masses showing the high influence of industrialized regions including production sites on atmospheric emissions and concentrations. The occurrence of OPs even in oceanic/Arctic air masses shows that OPs can undergo long-range atmospheric transport. Dry particle-bound deposition fluxes from 9 to 240 ng m−2 d−1 for ∑8OPs were estimated leading to a minimum annual flux of 710 ± 580 kg y−1 OPs into the German North Sea. This study presents the first occurrence of OPs in the marine atmosphere together with important information on their long-range transport potential. 相似文献
29.
Dechlorane Plus (DP) has been determined in surface sediments from three Chinese coastal bays, e.g. Jiaozhou, Sishili and Taozi Bay in North China. DP concentrations ranged from <1.2 to 187 pg g−1 dry weight (dw) (mean: 24.7 pg g−1 dw) in Jiaozhou Bay, <1.2 to 135 pg g−1 dw (mean 69.9 pg g−1 dw) in Sishili Bay and <1.2 to 66.7 pg g−1 dw (mean: 40.4 pg g−1 dw) in Taozi Bay, respectively. Additionally, two dechlorinated species were quantified, which accounted for 0.6-5.1% of the ∑DP concentration.The fsyn values (syn-isomer/(syn- + anti-isomer)) in sediments from Jiaozhou Bay (mean 0.29) were close to the technical DP mixture (0.2-0.4), probably indicating local inputs of DP. In contrast, sediments in Sishili and Taozi Bay showed much lower fsyn values (mean 0.16). During transportation the DP isomers are subject to stereo selective degradation which partly resulted in the relative enrichment of anti-DP in coastal sediments. 相似文献
30.
Quantification of nitrate leaching from German forest ecosystems by use of a process oriented biogeochemical model 总被引:1,自引:0,他引:1
Kiese R Heinzeller C Werner C Wochele S Grote R Butterbach-Bahl K 《Environmental pollution (Barking, Essex : 1987)》2011,159(11):3204-3214
Simulations with the process oriented Forest-DNDC model showed reasonable to good agreement with observations of soil water contents of different soil layers, annual amounts of seepage water and approximated rates of nitrate leaching at 79 sites across Germany. Following site evaluation, Forest-DNDC was coupled to a GIS to assess nitrate leaching from German forest ecosystems for the year 2000. At national scale leaching rates varied in a range of 0–>80 kg NO3–N ha−1 yr−1 (mean 5.5 kg NO3–N ha−1 yr−1). A comparison of regional simulations with the results of a nitrate inventory study for Bavaria showed that measured and simulated percentages for different nitrate leaching classes (0–5 kg N ha−1 yr−1:66% vs. 74%, 5–15 kg N ha−1 yr−1:20% vs. 20%, >15 kg N ha−1 yr−1:14% vs. 6%) were in good agreement. Mean nitrate concentrations in seepage water ranged between 0 and 23 mg NO3–N l−1. 相似文献