COMPARISON OF TWO PESTICIDE LEACHING INDICES1

ABSTRACT: Agriculture is the leading cause of regional‐scale non‐point source (NPS) pollution in the world today. Indices of pesticide leaching in the vadose zone are well suited for estimating the spatial accumulation and distribution of NPS pollutants in the near surface. In this study the Attenuation Factor (AF) and the Leaching index (Li) are used to assess the near‐surface leaching potential for 32 important agrochemicals for world average agricultural soil properties and recharge rates. The AF and Li indices both require the same input data and appear to work well for nonpolar chemicals. In the effort reported here the AF and Li indices produced similar results for the 32 agrochemicals. Pesticides with high and moderate leaching potential are identified. The AF estimates were more constant than the Li estimates for changes in the compliance depth and recharge rate. The AF index is simpler to use than the Li index and, therefore, is more likely to be employed in the future for screening/ranking agrochemicals relative to regional‐scale NPS ground water vulnerability.     

Quantification of Extinction Risk: IUCN's System for Classifying Threatened Species

Abstract: The International Union for Conservation of Nature (IUCN) Red List of Threatened Species was increasingly used during the 1980s to assess the conservation status of species for policy and planning purposes. This use stimulated the development of a new set of quantitative criteria for listing species in the categories of threat: critically endangered, endangered, and vulnerable. These criteria, which were intended to be applicable to all species except microorganisms, were part of a broader system for classifying threatened species and were fully implemented by IUCN in 2000. The system and the criteria have been widely used by conservation practitioners and scientists and now underpin one indicator being used to assess the Convention on Biological Diversity 2010 biodiversity target. We describe the process and the technical background to the IUCN Red List system. The criteria refer to fundamental biological processes underlying population decline and extinction. But given major differences between species, the threatening processes affecting them, and the paucity of knowledge relating to most species, the IUCN system had to be both broad and flexible to be applicable to the majority of described species. The system was designed to measure the symptoms of extinction risk, and uses 5 independent criteria relating to aspects of population loss and decline of range size. A species is assigned to a threat category if it meets the quantitative threshold for at least one criterion. The criteria and the accompanying rules and guidelines used by IUCN are intended to increase the consistency, transparency, and validity of its categorization system, but it necessitates some compromises that affect the applicability of the system and the species lists that result. In particular, choices were made over the assessment of uncertainty, poorly known species, depleted species, population decline, restricted ranges, and rarity; all of these affect the way red lists should be viewed and used. Processes related to priority setting and the development of national red lists need to take account of some assumptions in the formulation of the criteria.     

A finite element method to solve a population dynamics stage-structured model of intertidal barnacles

Many marine organisms are fixed or highly sedentary as adults but the adult population may be strongly dependent on the oceanic transport of planktonic larvae. In order to assess interactions between oceanographic and biological processes that determine the population dynamics of marine organisms with a sessile adult phase restricted to the coastline and a planktonic larval phase, we present a stage-structured finite element model for the barnacle Balanus glandula that inhabits the rocky intertidal zone of central California, USA.     

Current status and challenges of remediating petroleum‐derived PAHs in soils: Nigeria as a case study for developing countries

Polycyclic aromatic hydrocarbons (PAHs) are among the world's most significant environmental organic contaminants because of their carcinogenic properties. PAHs are widely distributed globally as a result of releases from numerous natural and anthropogenic activities. Consequently, several PAH monitoring studies have been conducted and remediation approaches explored. This article aims to provide the current status of PAH distribution in Nigeria's oil and gas industrial region in relation to the technologies adopted for PAH remediation. Ideally, the findings will provide insight into the challenges in managing organic contaminants derived from petroleum exploration activities in developing countries with Nigeria as a case study.     

Environmental remediation processes by zero valence copper: reaction mechanisms

Environmental Science and Pollution Research - Recent studies have shown Cu(0) as a promising material for the removal of organic and inorganic pollutants. However, there is no review addressing...     

Residues of legacy organochlorine pesticides and DDT metabolites in highly consumed fish from the polluted Guanabara Bay,Brazil: distribution and assessment of human health risk

Abstract

Organochlorine (OCP) pesticides were determined in samples of sardine (Sardinella brasiliensis), whitemouth croaker (Micropogonias furnieri), and mullet (Mugil liza) from Guanabara Bay (state of Rio de Janeiro, Brazil). OCP concentrations and fish consumption were linked with acceptable daily intake values in order to assess the human health risk for the Brazilian population. The total concentrations of OCPs (Σ OCP) was 6.6?ng/g f.w., 7.5?ng/g f.w., and 2.8?ng/g f.w. for sardines, corvina, and mullet, respectively. There was a significant difference (P?<?0.05) among the species related to o,p’-DDD and o,p’-DDT concentrations. Both DDT-related compounds were 5 and 76 times more abundant in sardines than in whitemouth croaker and mullet. Newly discovered DDT metabolite, o-Cl-DDMU, was frequently detected in the fish. None of the samples exceeded the maximum limits for acceptable levels of OCP residues. According to the data of average intake of Brazilian population, none of three species exceeded toxicological parameter. The investigated fishes are considered as safe for human consumption in regard to exposure of the studied OCPs. However, fish may be a intake source of OCP metabolites such as o-Cl-DDMU whose toxicity is still unknown.     

Effect of the Incorporation of Lysozyme on the Properties of Jackfruit Starch Films

Jackfruit starch based biodegradable films containing lysozyme were characterized for their antimicrobial activity, thickness, solubility, water vapor permeability and mechanical properties. The biodegradable films had good appearance and antimicrobial activity against Micrococcus lysodeikticus. The thickness of the biodegradable films were not affected by the variation in pH, but the addition of lysozyme increased the thickness, the thickest films being those with the highest lysozyme concentrations. The variation in pH of the filmogenic solutions affected the solubility of the biodegradable films, water solubility being greatest at pH 7.0 and with the highest lysozyme concentration. The permeability of the biodegradable films was increased by incorporating lysozyme. The lysozyme concentration and pH variation caused changes in the mechanical properties. The addition of 8% lysozyme increased the tensile strength and Young’s modulus for all the pH values studied. With respect to the release of antimicrobial activity, the diffusion of lysozyme was shown to follow Fickian transport mechanism.     

Policy-adaptation for a smarter and more sustainable EU electricity distribution industry: a foresight analysis

The European Union (EU) transition to a smarter and more sustainable electricity sector is driven by climate change adaptation and technological developments. For the electricity distribution industry, this has contributed to a growing need to understand how these network monopolies should adapt their role, activities, and responsibilities for a redesigned electricity market, given the growth of distributed generation, and the increased control and monitoring capabilities. Considering this, a foresight study on business model innovation, technological adaptation, and market design policy alternatives is presented. A Policy Delphi method was applied, involving two iterative survey rounds and 207 European experts, which assessed 57 policy alternatives. The results highlight adaptation challenges for implementing new technologies and business practices. Experts support innovation and transition to new roles, and innovative services, while warranting that core electricity distribution activities are secured. This shift in roles is expected to be achieved through research and development (R&D) support policies, innovation friendly regulatory frameworks, and concerted actions at the EU and Member States level. The results provide policy-adaptation guidelines for electricity distribution industry stakeholders.     

Pharmacopollution and Household Waste Medicine (HWM): how reverse logistics is environmentally important to Brazil

Pharmacopollution is a public health and environmental outcome of some active pharmaceutical ingredients (API) and endocrine-disrupting compounds (EDC) dispersed through water and/or soil. Its most important sources are the pharmaceutical industry, healthcare facilities (e.g., hospitals), livestock, aquaculture, and households (patients’ excretion and littering). The last source is the focus of this article. Research questions are “What is the Household Waste Medicine (HWM) phenomenon?”, “How HWM and pharmacopollution are related?”, and “Why is a reverse logistic system necessary for HWM in Brazil?” This article followed the seven steps proposed by Rother (2007) for a systematic review based on the Cochrane Handbook and the National Health Service (NHS) Center for Reviews Dissemination (CDR) Report. The HWM phenomenon brings many environmental, public health, and, social challenges. The insufficient data is a real challenge to assessing potential human health risks and API concentrations. Therefore, the hazard of long-term exposure to low concentrations of pharmacopollutants and the combined effects of API mixtures is still uncertain. HWM are strongly related to pharmacopollution, as this review shows. The Brazilian HWM case is remarkable because it is the fourth pharmaceutical market (US$ 65,971 billion), with a wide number of private pharmacies and drugstores (3.3: 10,000 pharmacy/inhabitants), self-medication habits, and no national take-back program. The HWM generation is estimated in 56.6 g/per capita, or 10,800 t/year. The absence of a reverse logistics for HWM can lead to serious environmental and public health challenges. The sector agreement for HWM is currently under public consultation.