Application to the Port of Sines of a new tool for risk assessment in port navigation

This paper describes a first approach on the risk assessment in port navigation using GUIOMAR, an integrated system for port and coastal engineering modelling developed at the National Civil Engineering Laboratory (LNEC), Portugal, using a GIS software environment. A set of automatic procedures was designed to include a new methodology based on the amplitude of the wave-induced vertical movement of a ship along its trajectory. In this methodology, the risk in port navigation is assessed on the basis of a combination of the probability of exceedance of a pre-set threshold for the ship??s vertical movements and its consequences. To test the new procedures, a set of sea wave records obtained at the Sines wave-buoy from 1988 to 2002 was transferred into Sines Port using two numerical models of sea wave propagation and deformation (SWAN and DREAMS), included in the GUIOMAR system. The numerical model WAMIT was used for estimating the wave-induced ship??s vertical movements inside the port. By applying the new procedures, automatic generation of risk maps was carried out for navigation in the vicinity of the West breakwater of the Port of Sines. The recent developments contribute towards a more versatile and efficient GUIOMAR system, which results in a more adequate tool to support decision-making processes in port and coastal management.     

Risk assessment of coastal flood in a site of special scientific interest

The Canary Islands have a long coastline with varying levels of exposure to severe sea conditions. Frequent states of alert and emergency in some parts of their coastline are commonly related to the occurrence of extreme wave conditions. Among the phenomena directly driven by the waves when reaching the shore are the wave run-up and overtopping. Both the study of the flood level, including its variability, and the associated risks are key tools in the planning and management of coastal zones. The aim of this research is to examine the probability of occurrence of run-up events capable of exceeding different topographical levels, for estimating the risk level associated with flooding of the different areas in which the Boca Barranco Beach can be divided, in terms of their nature and use. This beach is located on the island of Gran Canaria, Spain, and is part of the site of scientific interest of Jinámar. A large wave dataset is used as input to a high-resolution numerical model for propagating offshore wave conditions to shallow waters in the study area. Furthermore, the morphology of the study area is reproduced by combining different bathymetric databases. Finally, the probability of occurrence of different levels of run-up and the corresponding levels of consequences are assigned, to assess the flood risk in the different areas of the beach, which are presented in a risk map of flooding in the study area.     

Synthesis of grafted natural pozzolan with 3-aminopropyltriethoxysilane: preparation,characterization, and application for removal of Brilliant Green 1 and Reactive Black 5 from aqueous solutions

Environmental Science and Pollution Research - Natural pozzolan is an amorphous silicate-based material of volcanic origin. In this work, the natural pozzolan was modified by using...     

A roadmap for the conservation of freshwater mussels in Europe

Europe has a long history of human pressure on freshwater ecosystems. As pressure continues to grow and new threats emerge, there is an urgent need for conservation of freshwater biodiversity and its ecosystem services. However, whilst some taxonomic groups, mainly vertebrates, have received a disproportionate amount of attention and funds, other groups remain largely off the public and scientific radar. Freshwater mussels (Bivalvia, Unionida) are an alarming example of this conservation bias and here we point out six conceptual areas that need immediate and long-term attention: knowledge, threats, socioeconomics, conservation, governance and education. The proposed roadmap aims to advance research, policy and education by identifying the most pressing priorities for the short- and long-term conservation of freshwater mussels across Europe.     

Assessing the diurnal variability of pharmaceutical and personal care products in a full-scale activated sludge plant

An intensive sampling campaign has been carried out in a municipal wastewater treatment plant (WWTP) to assess the dynamics of the influent pharmaceutical active compounds (PhAC) and musks. The mass loadings of these compounds in wastewater influents displayed contrasting diurnal variations depending on the compound. The musks and some groups of PhACs tended to follow a similar diurnal trend as compared to macropollutants, while the majority of PhACs followed either the opposite trend or no repeatable trend. The total musk loading to the WWTP was 0.74 ± 0.25 g d⁻¹, whereas the total PhAC mass loading was 84.7 ± 63.8 g d⁻¹. Unlike the PhACs, the musks displayed a high repeatability from one sampling day to the next. The range of PhAC loadings in the influent to WWTPs can vary several orders of magnitude from one day or week to the next, representing a challenge in obtaining data for steady-state modelling purposes.     

Respiration induced by substrate and bacteria diversity after application of diuron,hexazinone, and sulfometuron-methyl alone and in mixture

Abstract

After application, herbicides often reach the soil and affect non-target soil microorganisms, decreasing their population, diversity or affecting metabolic activity. Therefore, laboratory studies were performed to evaluate the effects of diuron, hexazinone and sulfometuron-methyl alone and mixed upon carbon transformation by soil microorganisms in clayey and sandy soils and the effect on bacterial diversity and structure. Control treatment without herbicide application was also performed. Sub-samples from the control and herbicide treatments (10?g – in triplicate) were collected before herbicide application and 7, 14, 28 and 42?days after treatment (DAT), then 1?mL of ¹⁴C-glucose solution was applied. The released ¹⁴CO₂ was trapped in 2?M NaOH solution and the radioactivity was analyzed by liquid scintillation counting (LSC), 12?h after glucose application. The effect of herbicides on bacterial diversity was evaluated by T-RFLP. The experiment was conducted in a complete randomized design. Hexazinone did not affect ¹⁴CO₂ evolution. Diuron showed a greater ¹⁴CO₂ evolution in sandy and clayey soil, while sulfometuron-methyl led to an increase in sandy soil, at 42 DAT. A greater evolution of carbon was observed in the treatment with herbicide mixture in sandy soil, compared with the same treatment in clayey soil or control. However, the herbicide mixture application did not affect the soil biological activity measured by the respiration rate induced by substrate. On the other hand, the herbicide mixtures affected the bacterial diversity in both soils, being the strongest effect to diuron and sulfometuron-methyl in clayey soil and hexazinone in sandy soil.     

Median lethal concentration of formaldehyde and its genotoxic potential in bullfrog tadpoles (Lithobates catesbeianus)

In order to avoid that contaminated frog farms animals escaping in the environment and become potential vector of emergent diseases, studies with disinfection protocol are strictly necessary. The formaldehyde is one of the compounds tested in fungal disinfection protocols and also used in aquaculture. This study aimed to determine the median lethal concentration (LC_50–96h) of formaldehyde in bullfrog tadpoles and to evaluate the possible genotoxic effects in acute exposition. Accordingly, the animals were exposed to formaldehyde in the concentrations of 6, 9, 12, 15, and 18 mg L^?1, and after 96 h blood samples were drawn for the micronucleus (MN) test. The LC_50–96h was 10.53 mg L^?1, and the MN frequency increased in proportion to the formaldehyde concentrations, with an estimated frequency in the negative control being 1.35 MN/individual. We concluded that formaldehyde is genotoxic to tadpoles of bullfrogs in the tested concentrations, and the choice of this chemical should be contemplated before its use in animals in captivity.     

Uptake,translocation, and control of trumpet flower (Tecoma stans) with aminocyclopyrachlor

To gain a better understanding of the physiology of the herbicide aminocyclopyrachlor in young plants of trumpet flower, the uptake and translocation were evaluated after the application of herbicide. This was determined by treating individual leaves with formulated herbicides plus ¹⁴C-aminocyclopyrachlor after the application of the formulated herbicide. This experiment used a randomized experimental design with three replications. In addition, field studies were conducted to assess the effectiveness of foliar applications of aminocyclopyrachlor in association with metsulfuton-methyl. The plant absorbed 20% of the herbicide applied. The translocation percentage did not surpass 5% of the total amount applied. Only 1% of the herbicide applied was translocated to the roots. Rate of 40 + 13 g a.i. 100 L^?1 of aminocyclopyrachlor+metsulfuron-methyl was effective to control T. stans.     

Effects of land-use changes on landslides in a landslide-prone area (Ardesen, Rize, NE Turkey)

Various natural hazards such as landslides, avalanches, floods and debris flows can result in enormous property damages and human casualties in Eastern Black Sea region of Turkey. Mountainous topographic character and high frequency of heavy rain are the main factors for landslide occurrence in Ardesen, Rize. For this reason, the main target of the present study is to evaluate the landslide hazards using a sequence of historical aerial photographs in Ardesen (Rize), Turkey, by Photogrammetry and Geographical Information System (GIS). Landslide locations in the study area were identified by interpretation of aerial photographs dated in 1973 and 2002, and by field surveys. In the study, the selected factors conditioning landslides are lithology, slope gradient, slope aspect, vegetation cover, land class, climate, rainfall and proximity to roads. These factors were considered as effective on the occurrence of landslides. The areas under landslide threat were analyzed and mapped considering the landslide conditioning factors. Some of the conditioning factors were investigated and estimated by employing visual interpretation of aerial photos and topographic data. The results showed that the slope, lithology, terrain roughness, proximity to roads, and the cover type played important roles on landslide occurrence. The results also showed that degree of landslides was affected by the number of houses constructed in the region. As a consequence, the method employed in the study provides important benefits for landslide hazard mitigation efforts, because a combination of both photogrammetric techniques and GIS is presented.