全文获取类型
收费全文 | 1205篇 |
免费 | 63篇 |
国内免费 | 427篇 |
专业分类
安全科学 | 59篇 |
废物处理 | 84篇 |
环保管理 | 100篇 |
综合类 | 613篇 |
基础理论 | 222篇 |
污染及防治 | 457篇 |
评价与监测 | 74篇 |
社会与环境 | 47篇 |
灾害及防治 | 39篇 |
出版年
2024年 | 4篇 |
2023年 | 12篇 |
2022年 | 49篇 |
2021年 | 39篇 |
2020年 | 30篇 |
2019年 | 48篇 |
2018年 | 40篇 |
2017年 | 53篇 |
2016年 | 54篇 |
2015年 | 87篇 |
2014年 | 103篇 |
2013年 | 129篇 |
2012年 | 106篇 |
2011年 | 98篇 |
2010年 | 84篇 |
2009年 | 73篇 |
2008年 | 108篇 |
2007年 | 82篇 |
2006年 | 61篇 |
2005年 | 53篇 |
2004年 | 51篇 |
2003年 | 48篇 |
2002年 | 39篇 |
2001年 | 29篇 |
2000年 | 26篇 |
1999年 | 29篇 |
1998年 | 26篇 |
1997年 | 24篇 |
1996年 | 22篇 |
1995年 | 16篇 |
1994年 | 13篇 |
1993年 | 14篇 |
1992年 | 12篇 |
1991年 | 9篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1977年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有1695条查询结果,搜索用时 31 毫秒
931.
Zhiguang Zhou Yue Ren Jiazhi Chu Nan Li Sen Zhen Hu Zhao Shuang Fan Hui Zhang Pengjun Xu Li Qi Shuting Liang Bin Zhao 《环境科学学报(英文版)》2016,28(6):244-251
To assess the influence of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans(PCDD/Fs) on the environment in the vicinity of municipal solid waste incinerators(MSWIs), we determined the levels of PCDD/Fs in air and soil samples collected around a MSWI, which is the largest in China. The International Toxicity Equivalency Quantity(I-TEQ) concentrations of PCDD/Fs in air samples were from 0.0300 to 1.03 pg I-TEQ/m~3(0.445–13.6 pg/m~3), with an average of 0.237 pg I-TEQ/m~3, while in soil samples they ranged from 0.520 to 3.40 pg I-TEQ/g(2.41–88.7 pg/g) with an average of1.49 pg I-TEQ/g. The concentrations of PCDD/Fs in air and soil samples were comparable to other areas, and Pe CDFs were the dominant contributors, which was different from stack gas homologue patterns. Multivariate statistical analysis showed that PCDD/Fs emission from the MSWI did not directly affect the profiles of PCDD/Fs in air and soils, so that vehicles and unidentified emission sources should be considered. The daily inhalation levels of PCDD/Fs for children(0.0110 to 0.392 pg I-TEQ/(kg·day) and adults(0.00600 to 0.221 pg I-TEQ/(kg·day) near the MSWI were lower than the tolerable daily intake of 1.00 to 4.00 pg WHO-TEQ/(kg·day), but in winter the values were higher than in summer. These results can be used as basic data for assessing the risk of PCDD/Fs exposure in residents living around this MSWI, and more monitoring programs and studies should be carried out around MSWIs. 相似文献
932.
借助Rhizon间隙水采样技术、Unisense微电极技术,解析了物理扰动和摇蚊幼虫组合扰动对底泥微界面和微环境特征的协同作用.结果表明,组合扰动、生物扰动均导致溶解氧渗透深度(OPD)、总氧气交换速率(TOE)、含水率、总微生物活性显著增加,并保持在高于对照实验的水平.并且,组合扰动下,这些指标随着物理扰动强度增加而有所增加.对于Fe2+而言,组合扰动和生物扰动均导致Fe2+含量明显降低,且降低幅度明显大于对照实验.Fe2+、含水率、总微生物活性在底泥0~4 cm内受扰动影响变化幅度较大.这可能是内源磷形态转化的"活性区域".对组合扰动下OPD、TOE、Fe2+、含水率、总微生物活性与物理扰动强度进行曲线拟合.结果表明,各拟合方程均符合2阶多项式,且当扰动强度≥34 r·min-1,组合扰动对上述指标产生"跃变式"叠加作用.这种改造效应可能是内源磷形态转化的主要诱发机制. 相似文献
933.
Spatial and temporal variation of particulate matter and gaseous pollutants in 26 cities in China 总被引:2,自引:0,他引:2
Fahe Chai Jian Gao Zhenxing Chen Shulan Wang Yuechong Zhang Jingqiao Zhang Hefeng Zhang Yaru Yun Chun Ren 《环境科学学报(英文版)》2014,26(1):75-82
O3and PM2.5were introduced into the newly revised air quality standard system in February 2012, representing a milestone in the history of air pollution control, and China's urban air quality will be evaluated using six factors(SO2, NO2, O3, CO, PM2.5and PM10) from the beginning of 2013. To achieve the new air quality standard, it is extremely important to have a primary understanding of the current pollution status in various cities. The spatial and temporal variations of the air pollutants were investigated in 26 pilot cities in China from August 2011 to February 2012, just before the new standard was executed. Hourly averaged SO2, NO2and PM10were observed in 26 cities, and the pollutants O3, CO and PM2.5were measured in 15 of the 26 cities. The concentrations of SO2and CO were much higher in the cities in north China than those in the south. As for O3and NO2, however, there was no significant diference between northern and southern cities. Fine particles were found to account for a large proportion of airborne particles, with the ratio of PM2.5to PM10ranging from 55% to 77%. The concentrations of PM2.5(57.5 μg/m3) and PM10(91.2 μg/m3) were much higher than the values(PM2.5: 11.2 μg/m3; PM10 : 35.6 μg/m3) recommended by the World Health Organization. The attainment of the new urban air quality standard in the investigated cities is decreased by 20% in comparison with the older standard without considering O3, CO and PM2.5, suggesting a great challenge in urban air quality improvement, and more eforts will to be taken to control air pollution in China. 相似文献
934.
935.
This study describes the degradation of nitrogen-heterocyclic compounds (NHCs) by anodic oxidation and electro-Fenton. Using indole as a model nitrogen-heterocyclic compound, the removal of indole reached 68% and 97% by anodic oxidation and electro-Fenton, respectively, while the decay of TOC was 15% and 38% correspondingly. By the analysis of ultraviolet-visible spectra and liquid chromatography/mass spectrum, the degradation mechanism of indole by electro-Fenton was proposed as hydroxyl oxidation and anodic oxidation. The degradation of other NHCs including quinoline, isoquinoline and pyridine by anodic oxidation and electro-Fenton revealed the same sequence: quinoline approximately equal isoquinoline > indole > pyridine. A significant correlation between ln k (natural logarithm of rate constants) and E(LUMO) (the energy of the lowest unoccupied molecular orbit) was obtained by quantitative structure-activity relationship analysis. Degradation of coking plant wastewater showed the removal of COD and TOC were 42% and 22% respectively after 180 min treatment by electro-Fenton. 相似文献
936.
在(35±1)℃条件下,采用IC厌氧反应器对天津大港垃圾焚烧厂垃圾渗滤液进行处理,研究了COD的去除效果、容积负荷、沼气产量和污泥的颗粒化,分析了循环比、上升流速对反应器的影响.结果表明,厌氧反应器经60 d的启动运行后,达到300 m3/d的设计水量,进水容积负荷达到17.7 kg COD/(m3·d),水力停留时间3.7d,COD去除率高于80%,出水挥发酸(VFA)低于l 500 mg/L,平均每去除1 kg COD产沼气0.42 m3,适宜的上升流速和循环比为2.0 ~5.0 m/h、8∶1 ~20∶1.启动结束后,厌氧消化污泥明显出现颗粒化,颗粒污泥的沉降速度达到了67.5 ~ 96.0 m/h,0.3~1.0 mm的颗粒污泥量占有74%. 相似文献
938.
939.
采用双氰胺甲醛缩聚物混凝去除水中酸性红B染料的研究 总被引:1,自引:0,他引:1
以双氰胺和甲醛为原料制备了聚合双氰胺甲醛,并对其进行红外光谱表征.采用聚合双氰胺甲醛与硫代硫酸钠共同作用对酸性红B染料溶液进行混凝脱色实验.对比了单独使用聚合双氰胺甲醛,以及聚合双氰胺甲醛与硫代硫酸钠共同作用的脱色效果.探讨了硫代硫酸钠和聚合双氰胺甲醛的用量以及pH值对脱色率的影响.结果表明,投加硫代硫酸钠可以明显地提高聚合双氰胺甲醛的脱色率,增大絮凝范围,使絮凝剂对pH值的变化有很强的适应性,pH值为7~12的范围内,脱色率均能维持在96%以上.此外,还对混凝脱色的机理进行了研究. 相似文献
940.