Quantification of low levels of organochlorine pesticides using small volumes (<or=100 microl) of plasma of wild birds through gas chromatography negative chemical ionization mass spectrometry

A solid phase extraction and gas chromatography with negative chemical ionization mass spectrometry in scan mode (GC-NCI-MS) method was developed to identify and quantify for the first time low levels of organochlorine pesticides (OCs) in plasma samples of less than 100 microl from wild birds. The method detection limits ranged from 0.012 to 0.102 pg/microl and the method reporting limit from 0.036 to 0.307 pg/microl for alpha, gamma, beta and delta-hexachlorocyclohexane (HCH), heptachlor, aldrin, heptachlor epoxide, endosulfan I, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (p,p'-DDE), dieldrin, endrin, endosulfan-II, endrin-aldehyde and endosulfan-sulfate. Pesticide levels in small serum samples from individual Falco sparverius, Sturnella neglecta, Mimus polyglottos and Columbina passerina were quantified. Concentrations ranged from not detected (n/d) to 204.9 pg/microl for some OC pesticides. All levels in the food web in and around cultivated areas showed the presence of pesticides notwithstanding the small areas for agriculture existing in the desert of Baja California peninsula.     

Effects of Organic Material and Distribution of Fecal Coliforms in Chetumal Bay, Quintana Roo, México

Most wastewater from the city of Chetumal is discharged into the adjoining bay without treatment through a pluvial sewer system. The bay also receives a high volume of vegetal organic material from the River Río Hondo. The average of biochemical oxygen demand (BOD) was 32.26 mg l-1, it was low compared with other reports and should be indicative of self-depuration processes in Chetumal Bay. In the area most used by the public for recreational and fishing activities, concentrations of fecal coliforms above the limit established by Mexican Legislation were shown. The border between Mexico and Belize is Chetumal Bay, which recently was declared a protected area for manatees.     

Forests and global change: what can genetics contribute to the major forest management and policy challenges of the twenty-first century?

The conservation and sustainable use of forests in the twenty-first century pose huge challenges for forest management and policy. Society demands that forests provide a wide range of ecosystem services, from timber products, raw materials and renewable energy to sociocultural amenities and habitats for nature conservation. Innovative management and policy approaches need to be developed to meet these often-conflicting demands in a context of environmental change of uncertain magnitude and scale. Genetic diversity is a key component of resilience and adaptability. Overall, forest tree populations are genetically very diverse, conferring them an enormous potential for genetic adaptation via the processes of gene flow and natural selection. Here, we review the main challenges facing our forests in the coming century and focus on how recent progress in genetics can contribute to the development of appropriate practical actions that forest managers and policy makers can adopt to promote forest resilience to climate change. Emerging knowledge will inform and clarify current controversies relating to the choice of appropriate genetic resources for planting, the effect of silvicultural systems and stand tending on adaptive potential and the best ways to harness genetic diversity in breeding and conservation programs. Gaps in our knowledge remain, and we identify where additional information is needed (e.g., the adaptive value of peripheral populations or the genetic determinism of key adaptive traits) and the types of studies that are required to provide this key understanding.     

Effects of crowding due to habitat loss on species assemblage patterns

Terrestrial animals are negatively affected by habitat loss, which is assessed on a landscape scale, whereas secondary effects of habitat loss, such as crowding, are usually disregarded. Such impacts are inherently hard to address and poorly understood, and there is a growing concern that they could have dire consequences. We sampled birds throughout a deforestation process to assess crowding stress in an adjacent habitat remnant in the southern Brazilian Atlantic Forest. Crowding is expected of highly mobile taxa, especially given the microhabitat heterogeneity of Neotropical forests, and we hypothesized that the arrival of new individuals or species in refuges shifts assemblage patterns. We used point counts to obtain bird abundances in a before-after-control-impact design sampling of a deforestation event. Temporal changes in taxonomic and functional diversity were examined with metrics used to assess alpha and beta diversity, turnover of taxonomic and functional similarity, and taxonomic and functional composition. Over time increased abundance of some species altered the Simpson index and affected the abundance-distribution of traits in the habitat remnant. Taxonomic composition and functional composition changed in the remnant, and thus bird assemblages changed over time. Taxonomic and functional metrics indicated that fugitives affected resident assemblages in refuges, and effects endured >2 years after the deforestation processes had ceased. Dissimilarity of taxonomic composition between pre- and postdeforestation assemblages increased, whereas functional composition reverted to preimpact conditions. We found that ecological disruptions resulted from crowding and escalated into disruptions of species’ assemblages and potentially compromising ecosystem functioning. It is important to consider crowding effects of highly mobile taxa during impact assessments, especially in large-scale infrastructure projects that may affect larger areas than is assumed.     

Coupling check dams with large wood retention structures in clean water

Environmental Fluid Mechanics - The performance of a rake for large wood retention has been analysed in clean water and for the case of a slit check dam. An experimental investigation was conducted...     

Development and modelling of realistic retrofitted Nature-based Solution scenarios to reduce flood occurrence at the catchment scale

Decentralized Nature-based Solutions such as Urban Green Infrastructures (UGI) are increasingly promoted to reduce flooding in urban areas. Many studies have shown the effectiveness of flood control of UGI at a plot or neighbourhood level. Modelling approaches that extrapolate their flood reducing impact to larger catchment scales are often based on a simplistic assumption of different percentages of UGI implementation. Additionally, such approaches typically do not consider the suitable space for UGI and potential implementation constraints. This study proposes a scenario development and modelling approach for a more realistic upscaling of UGI based on empirical insights from a representative neighbourhood. The results from this study, conducted in the metropolitan area of Costa Rica, show that upscaling the full potential for UGI could significantly reduce surface runoff, peak flows, and flood volumes. In particular, the permeable pavement has the highest potential for flood reducing in public space while cisterns perform best at the property level. These results can guide the formation of policies that promote UGI.Supplementary InformationThe online version of this article (10.1007/s13280-020-01493-8) contains supplementary material, which is available to authorized users.     

Sensitivity of Landsat‐Scale Energy Balance to Aerodynamic Variability in Mountains and Complex Terrain

The speed and direction of air flow through complex terrain are difficult to define. Both impact sensible and latent heat flux exchanges at the surface. Evapotranspiration (ET) models such as Mapping EvapoTranspiration at high Resolution with Internalized Calibration (METRIC?) estimate ET as a residual of the surface energy process and are thus sensitive to aerodynamics, including terrain‐induced impacts on roughness governing convective heat transfer (H). There is a need to explore the sensitivities of H estimation and thereby ET estimation to wind speed and terrain roughness in mountainous areas and to determine the merit of operating complex mesoscale wind field models in conjunction with the energy balance process. A sensitivity analysis is explored in METRIC where we increased wind speed in proportion to a relative elevation parameter and we increased aerodynamic roughness to assimilate impacts of relative terrain roughness, estimated in proportion to standard deviation of elevation within a 3 km locality. These aerodynamic modifications increased convective heat transfer in complex terrain and reduced estimated ET. In other sensitivity runs, we reduced estimated wind speed on estimated leeward slopes. Estimated ET with and without these sensitivity adjustments is shown for mountainous areas of Montana and Nevada. Changes in ET ranged from little change (<5%) for lower slopes to about 30% reductions on windward slopes and 25% increases on leeward slopes for some mid to high elevations in the Montana application.     

Evaluating the impact of extreme temperature based indices in the 2003 heatwave excessive mortality in Portugal

This paper analyses the impact of the 2003 European heatwave on excessive human mortality in Portugal, a country that presents a relatively high level of exposure to heatwave events. A total of 2399 excessive deaths are estimated in continental Portugal, which implies an increase of 58% over the expected deaths. When these values are split by gender, it is seen that women increase (79%), was considerably higher than that recorded for men (41%). The increment of mortality due to this heatwave was detected for all the 18 districts of the country, but its magnitude was significantly higher in the inner districts close to the Spanish border. When we split by gender all districts reveal significant mortality increments for women, while the impact in men's excess deaths is not significant over 3 districts. Several temperature derived indices were used and evaluated in their capacity to explain, at the regional level, the excessive mortality (ratio between observed and expected deaths) by gender. It is shown that the best relationship is found for the total exceedance of extreme days, an index combining the length of the heatwave and its intensity. Both variables hold a linear relationship with r = 0.79 for women and a poorer adjustment (r = 0.50) for men. Additionally, availability of mortality data split by age also allowed obtaining detailed information on the structure of the population in risk, namely by showing that statistically significant increments are concentrated in the last three age classes (45–64, 65–74 and 75 or more). The use of air conditioning systems in some Portuguese hospitals had a major impact on the decrease (up to 40%) in excessive mortality values. A finer approach is relevant for prevention strategies, since it allows to identify better the target population of any preventive strategy regional and national authorities may be interested to implement.