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841.
The paper describes a programme to develop the profile of major accident risk across a large multi national oil company. It describes the concepts, tools and processes for constructing the risk profile and some of the key learnings from the exercise. 相似文献
842.
Francisco Ferreira Hugo Tente Pedro Torres Sérgio Cardoso José M. Palma-Oliveira 《Environmental monitoring and assessment》2000,65(1-2):443-450
The environmental decision-making process is related with the interpretation of data both in spatial and temporal dimensions. This paper presents a methodology that integrates the time-space framework of air quality data to infer the temporal pattern and spatial variability that could be interpreted for environmental decision purposes. Variograms that accommodate time and space lags were used for the analysis and proved to be effective. Its environmental meaning, in particular its relationship with traffic patterns is discussed. Data from air quality monitoring stations located in the central part of Lisbon were used in this study. It describes a strategy to identify the type of vehicles responsible for certain pollutant levels, particularly for nitrogen oxides, and discusses the application of new air quality European legislation to the city of Lisbon, Portugal. 相似文献
843.
844.
Extraction of labile metals from solid media is environmentally more meaningful than a total digestion. A variety of reagents
have been introduced in the literature, but dilute HCl has received the greatest attention. We compare metal concentrations
liberated by a dilute HCl leach with the sum of the 3-step optimized (standardized) BCR sequential extraction procedure. This
is the first study to compare these procedures over a range of grain sizes. Road-deposited sediments from 10 sites in Honolulu
were fractionated into six grain size classes. Aliquots of individual fractions were digested with dilute HCl, the 3-step
BCR procedure (‘labile’), and a 4-acid (total) procedure. Results indicated that the weighted labile concentrations of Al,
Cu, Fe, Mn, Ni, Pb and Zn were statistically greater than those from the dilute HCl leach. However, regression analysis indicated
strong statistically significant relationships between the two partial extraction procedures for all metals. On a whole-sample
basis, the toxicity classifications for anthropogenic-enhanced metals (Cu, Pb and Zn) were similar between extractions. Taken
together, results suggest that the application of dilute HCl to solid media provides a rapid, cost-effective, and environmentally
meaningful approach for contaminant monitoring. 相似文献
845.
Artificial neural network based carbon monoxide persistence models for episodic urban air quality management 总被引:1,自引:0,他引:1
This paper describes the development of artificial neural network (ANN) based carbon monoxide (CO) persistence (ANNCOP) models
to forecast 8-h average CO concentration using 1-h maximum predicted CO data for the critical (winter) period (November–March).
The models have been developed for three 8-h groupings of 10 p.m. to 6 a.m., 6 a.m. to 2 p.m. and 2–10 p.m., at two air quality control regions (AQCRs) in Delhi city, representing an urban intersection and an arterial road consisting
heterogeneous traffic flows. The result indicates that time grouping of 2–10 pm is dominantly affected by inversion conditions and peak traffic flow. The ANNCOP model corresponding to this grouping predicts
the 8-h average CO concentrations within the accuracy range of 68–71%. The CO persistence values derived from ANNCOP model
are comparable with the persistence values as suggested by the Environmental Protection Agency (EPA), USA. This work demonstrates
that ANN based model is capable of describing winter period CO persistence phenomena. 相似文献
846.
Cozzi F Adami G Barbieri P Reisenhofer E Bovenzi M 《Environmental monitoring and assessment》2008,144(1-3):389-401
The aim of this study was to measure the concentration of some metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Ti) in PM(10) samples collected in one urban and one industrial site and to assess that PM(10) total mass measurement may be not sufficient as air quality index due to its complex composition. Metals were determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and differential pulsed anodic stripping voltammetry (DPASV). The measured concentrations were used to calculate the content of metals in the PM(10) total mass, and to estimate the enrichment factors and the correlations between PM(10), metal concentrations and meteorological data for the two sites. The mean PM10 concentration during the sampling period in the urban site exceeded the annual European Union (EU) standard (40 microg/m(3)) and, for some sampling days, the daily EU standard (50 microg/m(3)) was also exceeded. In opposite, both EU standards were never exceeded in the industrial site. The overall metal content was nearly double in the industrial site compared to the urban one, and the mean Ni concentration exceeded the EU annual limit value (10 ng/m(3)). The metals with the highest enrichment factor were Cd, Cu, Ni and Pb for both sites, suggesting a dominant anthropogenic source for these metals. Metal concentrations were very low and typical of rural background during Christmas holidays, when factories were closed. PM(10) total mass measurement is not a sufficient air quality index since the metal content of PM(10) is not related to its total mass, especially in sites with industrial activities. This measurement should be associated with the analysis of toxic metals. 相似文献
847.
Metal pollution assessment of sediment and water in the Shur River 总被引:13,自引:0,他引:13
Karbassi AR Monavari SM Nabi Bidhendi GR Nouri J Nematpour K 《Environmental monitoring and assessment》2008,147(1-3):107-116
Intensified industrialization and human activities have resulted in the release of various contaminants into the environment. Among them, heavy metals are often present as a result of mining, milling and industrial manufacturing. In the present investigation, bulk concentrations Pb, Cd, Zn, Cu, Fe, Ca and Al in Shur River (Iran) bed sediments and water around the Sarcheshmeh copper mine were measured from several sample locations. In addition, partitioning was assessed to determine the proportions of metals in different forms. The degree of sediment contamination was evaluated using an Enrichment Factor (EF) and geo-accumulation index (I (geo)) and a newly developed pollution index (I (POLL)). Elevated metals in sediment and water were found to be correlated with areas of the river that were proximal to direct and indirect mining activities. Cadmium and Zn showed the highest pollution index. Cluster analysis was performed in order to assess heavy metal interactions between water and sediment. Chemical partitioning studies revealed that organic metallic bonds were not significantly present in the sediment of the Shur River. 相似文献
848.
Singh R Singh AP Singh MP Kumar A Varshney CK 《Environmental monitoring and assessment》2008,144(1-3):43-51
Isoprene is most dominant volatile organic compounds (VOC) emitted by many plants. In this study 40 common Indian plant species were examined for isoprene emission using dynamic flow through enclosure chamber technique. Isoprene emission rates of plants species were found to vary from undetectable to 69.5 microg g(-1) h(-1) (Madhuca latifolia). Besides, an attempt has been made to evaluate suitability of 80 common Indian plant species for planting programmes. Out of 80 species, 29 species were moderate to high emitters (10 to < or =25 microg g(-1) h(-1)), 12 species were low emitter emitters (1 to < or =10 microg g(-1) h(-1)) and remaining 39 species were found to be negligible or non emitters (<1 microg g(-1) h(-1)) of isoprene. About 50% plant species selected for planting programmes in India were found to be moderate to high emitters of isoprene. 相似文献
849.
Foran J. Brosnan T. Connor M. Delfino J. DePinto J. Dickson K. Humphrey H. Novotny V. Smith R. Sobsey M. Stehman S. 《Environmental monitoring and assessment》2000,62(2):147-167
The International Life SciencesInstitute (ILSI) Risk Science Institute (RSI) convenedan expert panel of scientists to developrecommendations for a comprehensive monitoring programfor the Croton and Catskill/Delaware watersheds, whichprovide drinking water to New York City's residents. This effort was conducted as part of efforts topreserve and enhance the quality of New York City'sreservoir system through a watershed protectionprogram. The panel developed recommendations for astrategic framework on which to construct a monitoringprogram. As part of this activity, the paneldetermined whether existing monitoring activities weredeficient and, where activities were deficient, thepanel developed recommendations for additionalinformation that should be collected.The panel recommended the development and use of anintegrated approach to watershed monitoring, whichdraws on modeling, risk-based planning and analysis,statistical sampling and design, and basic compliancemonitoring. The approach should be designed toprovide an assessment of natural and anthropogenicsources of stress to the system as well as anassessment of water quality trends in response tostresses acting in concert, both over the long termand over the five-year New York City Memorandum ofAgreement (MOA) assessment time frame. It should alsoprovide an assessment of the human health andenvironmental risks posed by a variety of stressors,and the impact of management actions implemented toameliorate stressors. 相似文献
850.