Long-Term Air Quality Assessment: Modeling Sources Contribution and Scenarios In Ivrea And Torino Areas

An evaluation of the air quality based on the combined use of monitoring data, dynamic emission inventories, and three-dimensional modeling has been performed in an area in North West Italy. Yearly maps of the pollutants of most concern have been produced by means of an Eulerian modeling system, run for two nested domains. The system is based on MINERVE diagnostic meteorological model, TREFIC (TRaffic Emission Factors Improved Calculation) traffic emission module, and farm air quality regional chemical-transport model. The zooming approach has allowed to correctly reproduce local concentrations in the small urban area in the inner domain as well as to quantify the role played by selected local sources respect to distant ones. The study of the impact of the future car fleet, pointing out the expected improvement for nitrogen oxides and the persisting problem of PM, provides a rationale for air quality governance.     

A flux-based assessment of the effects of ozone on foliar injury, photosynthesis, and yield of bean (Phaseolus vulgaris L. cv. Borlotto Nano Lingua di Fuoco) in open-top chambers

Stomatal ozone uptake, determined with the Jarvis' approach, was related to photosynthetic efficiency assessed by chlorophyll fluorescence and reflectance measurements in open-top chamber experiments on Phaseolus vulgaris. The effects of O₃ exposure were also evaluated in terms of visible and microscopical leaf injury and plant productivity. Results showed that microscopical leaf symptoms, assessed as cell death and H₂O₂ accumulation, preceded by 3-4 days the appearance of visible symptoms. An effective dose of ozone stomatal flux for visible leaf damages was found around 1.33 mmol O₃ m⁻². Significant linear dose-response relationships were obtained between accumulated fluxes and optical indices (PRI, NDI, ΔF/F_m^′). The negative effects on photosynthesis reduced plant productivity, affecting the number of pods and seeds, but not seed weight. These results, besides contributing to the development of a flux-based ozone risk assessment for crops in Europe, highlight the potentiality of reflectance measurements for the early detection of ozone stress.     

Numerical simulation of scalar dispersion downstream of a square obstacle using gradient-transport type models

We present a numerical study of scalar transport released from a line source downstream of a square obstacle to investigate the capabilities and limitations of gradient-transport modeling in predicting atmospheric dispersion. The standard k–? and k–ω models and a Reynolds Stress Transport closure are employed and compared to predict the time-averaged turbulent flow field, while a standard gradient–diffusion model is initially adopted to relate the scalar flux to mean gradients of the concentration field. The analysis of two algebraic closures for turbulent scalar fluxes based on the generalized-gradient–diffusion hypothesis and its quadratic extension is also presented. In spite of the rather simple flow setup, where both the flow and the scalar fields can be assumed homogeneous in the spanwise direction, the analysis clarifies several critical issues concerning gradient-transport type models. We established the dominant role of predicted turbulent kinetic energy on scalar dispersion when a scalar diffusivity is employed, irrespectively of the Reynolds stress closure adopted for the averaged momentum equation. Moreover, the standard gradient–diffusion hypothesis failed to predict the streamwise component of the scalar flux, which is characterized by a counter-gradient-transport mechanism. Although the resulting contribution in the averaged scalar transport equation is small in the present flow configuration, this limitation can become severe for strongly inhomogeneous flows in the presence of point sources, where the spread of the scalar plume is essentially three-dimensional. The predictive capabilities of gradient-transport type modeling are found clearly improved using algebraic closures, which appear to represent a promising tool for predicting atmospheric dispersion in complex flows when unsteady transport mechanisms are not dominant.     

Soil carbon dynamics in a Mediterranean forest during the Kyoto Protocol commitment periods

The purpose of the present work is to asses the possibility of detecting changes in soil organic carbon (SOC) at the end of the 5-years of the first Commitment Period (CP) of the Kyoto Protocol of the United Nation’s Framework Convention on Climate Change (1 January, 2008–31 December, 2012), by both direct measurement and the use of an opportunely evaluated SOC model, CENTURY. The investigated soil is young, developed since 28 years on virtually C-free spoil banks and under the influence of two managed forest stands, one a mix of English oak (Quercus robur L.) and Italian alder (Alnus cordata Loisel.) and the other pure English oak. The SOC stock of either stand was monitored since the time the stands were planted in 1981, and it was used together with other parameters for the model evaluation, while the future projections for the end of the first (2012) and second (2017) CP were made according to two extreme IPCC climatic scenarios: A1F1, the most dramatic, and B2, among the less impacting. Direct SOC measurements performed at the beginning and at the end of a time frame equivalent to a commitment period (2004–2008) had not shown significant variations in either stands. Compared to the 2008 SOC stock, in both stands the model shows variations at the end of the first CP from 0.7 to 1.8 Mg C ha⁻¹ for the A1F1 scenario and from 0.3 to 1.7 Mg C ha⁻¹ for the B2. These variations are within the standard deviations of the C stocks measured in 2008. On the contrary, at the end of the second CP, the modelled SOC increments range from 2.5 to 3.6 Mg C ha⁻¹ (A1F1) or from 1.9 to 3.4 Mg C ha⁻¹ (B2), indicating the possibility to detect the SOC changes by direct measurement, since the values well agree with the minimum detectable variation estimated for both sites in 3.3–4.5 Mg C ha⁻¹. This work shows that SOC stock changes measured directly in the field can be minimal at the end of both CPs, and that CENTURY well simulates the SOC dynamics of the stands. The use of such a model, validated at long-term experimental sites, hence represents an effective tool for estimating future changes in SOC amounts in support of direct measurements when a short period of time, such as the CP, is considered.     

Agricultural and green infrastructures: the role of non-urbanised areas for eco-sustainable planning in a metropolitan region

Non-Urbanised Areas (NUAs) are part of agricultural and green infrastructures that provide ecosystem services. Their role is fundamental for the minimization of urban pollution and adaptation to climate change. Like all natural ecosystems, NUAs are endangered by urban sprawl. The regulation of sprawl is a key issue for land-use planning. We propose a land use suitability strategy model to orient Land Uses of NUAs, based on integration of Land Cover Analysis (LCA) and Fragmentation Analysis (FA). With LCA the percentage of evapotranspiring surface is defined for each land use. Dimensions and densities of NUAs patches are assessed in FA. The model has been developed with Geographical Information Systems, using an extensive set of geodatabases, including orthophotos, vectorial cartographies and field surveys. The case of the municipality of Mascalucia in Catania metropolitan area (Italy), characterized by a considerable urban sprawl, is presented.     

Pyrolysis of WEEE plastics using catalysts produced from fly ash of coal gasification

Catalytic pyrolysis of thermoplastics extracted from waste electrical and electronic equipment (WEEE) was investigated using various fly ash-derived catalysts. The catalysts were prepared from fly ash by a simple method that basically includes a mechanical treatment followed by an acid or a basic activation. The synthesized catalysts were characterized using various analytical techniques. The results showed that not treated fly ash (FA) is characterized by good crystallinity, which in turn is lowered by mechanical and chemical treatment (fly ash after mechanical and acid activation, FAMA) and suppressed almost entirely down to let fly ash become completely amorphous (fly ash after mechanical and basic activation FAMB). Simultaneously, the surface area resulted increased. Subsequently, FA, FAMB and FAMA were used in the pyrolysis of a WEEE plastic sample at 400°C and their performance were compared with thermal pyrolysis at the same temperature. The catalysts principally improve the light oil yield: from 59 wt.% with thermal pyrolysis to 83 wt.% using FAMB. The formation of styrene in the oil is also increased: from 243 mg/g with thermal pyrolysis to 453 mg/g using FAMB. As a result, FAMB proved to be the best catalyst, thus producing also the lowest and the highest amount of char and gas, respectively.

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Adaptations to semi-terrestrial life in embryos of East African mangrove crabs: a comparative approach

In this experimental study, we compared the embryonic respiration rate in air and water of six East African sesarmid species with intertidal, supratidal and arboreal habits, to highlight possible adaptations in embryonic metabolism to their different lifestyles. The embryos of all analysed crabs showed bimodal respiration, but we did not find a trend towards an enhanced embryonic oxygen uptake in air from the intertidal to the arboreal and supratidal species. However, the late-stage embryos of the most land-adapted species, Chiromantes spp., showed an enhanced metabolism when immersed in sea water that we interpreted as an adaptive recovery mechanism to cope with the storage of by-products due to marine-based metabolic pathways during long emersion periods. Thus, we showed that the embryos of land-adapted species, although still strongly water dependent, are well adapted to semi-terrestrial habitats and represent a minor limiting factor for females, which are not restricted in their emersion period by the oxygen requirements of their embryos.     

From landfill to water,land and life: The creation of the Centre for stone materials aimed at secondary processing

This paper focuses on the creation of a Centre for the recycling of stone materials. The Centre will be able to offer a range of activities amongst which is the improvement of the production chain of the Orosei Marble district in Sardinia, Italy. Several companies operate within the marble producing area, specializing in both quarrying and stone processing. They have formed a Consortium in order to rehabilitate an area of more than 17 ha. The restoration will be carried out through an environmentally sustainable procedure. The area was previously used as a landfill for waste deriving from marble quarrying and processing. At that time unshaped blocks of various sizes (which are unsuitable to block-cutter sawing), waste deriving from both block sawing and slab/strip cutting (such as broken slabs, strips, tiles) and microfine dust from filter presses of water treatment plants were representing an environmental problem. The local administration was struggling to find new areas which could be used for landfills, resulting in an additional cost for the landfill, ultimately affecting the variable production costs. The project involves the building of a venue to be used for temporary storage, treatment of wastes produced by both quarrying and primary processing, in order to make them suitable as secondary raw materials. The project also deals with the catch basin hydrology of the area involved in the project, the building of a multifunctional centre, the landscaping and other environmental features such as vehicle traffic and slopes greening.     

Environmental comparison of draught animal and tractor power

The environmental impacts of moving to different traction power sources have not been well studied in either developing countries or modern agriculture. This study assesses the environmental impact of the transition from animal to tractor power and vice versa. Three different scenarios are analyzed: a developing country context where draught animal power (DAP) is actually in use; a similar context where DAP is replaced by mechanical traction; and a developed country scenario where mechanical traction is replaced by DAP. The impact assessment focuses on global warming (GW) and primary energy consumption (PEC). The DAP system refers to an Indonesian case study where Peranakan Ongole cattle are used for work, together with the production of milk and meat, and fed with two forage-supplying alternatives. The mechanical traction system considers the cases of a two-wheel tractor (2WT) and a rear-wheel-drive tractor (4WT). In the first scenario, assessing DAP impacts for plowing through process subdivision and indirect impacts allocation to co-products, DAP has a consistent advantage regarding energy consumption, while for CO₂eq emissions, performance is better only in the case of 2WT. In the second scenario, considering product equivalent systems, substituting DAP with tractor power and maintaining the same DAP livestock farming more than doubles the impact; only with the introduction of modern, specialized livestock farming is a reduction achieved. In the third scenario, replacing mechanical traction with DAP results in a greater than three-fold increase in impact for PEC and more than 17 times increase for GW. Further work on the influence of system definition and the socio-economic background would improve the estimates produced in this study.     

A Quantile Regression Approach to Evaluate Factors Influencing Residential Indoor Radon Concentration

Indoor radon concentrations depend on building characteristics such as building materials, ventilation and water supply. In this paper, a quantile regression approach is proposed to evaluate the effect of some buildings factors potentially influencing indoor radon concentration. Many of the considered factors, such as soil connection, age of construction and being a single family building, are found to have a statistically significant effect; however, this is far from being constant across the entire support of indoor radon concentration. A potential impact due to geological and geo-physical reasons is also found using the altitude of building locations as a surrogate variable. In addition, a clear local spatial effect is detected by a spatial autoregression approach.