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221.
TOPHAZOP: a knowledge-based software tool for conducting HAZOP in a rapid, efficient yet inexpensive manner 总被引:3,自引:0,他引:3
Faisal I. Khan S. A. Abbasi 《Journal of Loss Prevention in the Process Industries》1997,10(5-6):333-343
Hazard and operability (HAZOP) studies constitute an essential step in the risk analysis of any chemical process industry and involve systematic identification of every conceivable abnormal process deviation, its causes and abnormal consequences. These authors have recently proposed optHAZOP as an alternative procedure for conducting HAZOP studies in a shorter span of time than taken by conventional HAZOP procedure, with greater accuracy and effectiveness [Khan, F. I. and Abassi, S. A., optHAZOP. An effective and efficient technique for hazard identification and assessment Journal of Loss Prevention in the Process Industries, 1997, 10, 191–204]. optHAZOP consists of several steps, the most crucial one requires use of a knowledge-based software tool which would significantly reduce the requirement of expert man-hours and speed up the work of the study team. TOPHAZOP (Tool for OPTmizing HAZOP) has been developed to fulfil this need.
The TOPHAZOP knowledge-base consists of two main branches: process-specific and general. The TOPHAZOP framework allows these two branches to interact during the analysis to address the process-specific aspects of HAZOP analysis while maintaining the generality of the system. The system is open-ended and modular in structure to make easy implementation and/or expansion of knowledge. The important features of TOPHAZOP and its performance on an industrial case study are described. 相似文献
222.
Liang Chen Syed H. Imam Sherald H. Gordon Richard V. Greene 《Journal of Polymers and the Environment》1997,5(2):111-117
Starch-PVOH cast films were prepared with and without crosslinking agent (hexamethoxymethylmelamine) in the absence of plasticizer.
Moisture absorption in films without crosslinking agent at a low relative humidity was similar to that of PVOH and increased
as the relative humidity increased. Films with crosslinking agent showed moisture absorption linearly proportional to the
relative humidity. Significant improvement in resistance to water disintegration for crosslinked starch-PVOH films was observed.
While the tensile strength decreased with increased relative humidity, crosslinking significantly improved the tensile strength.
Increased PVOH content improved elongation of films even when the relative humidity was 80% or higher. Biodegradation studies
revealed that the degradation rate was negatively correlated with the PVOH content in films and crosslinking generated more
converged degradation curves.
Names are necessary to report factually on available data; however, the USDA neither guarantees nor warrants the standard
of the product, and the use of the name by USDA implies no approval of the product to the exclusion of others that may also
be suitable. 相似文献
223.
Aaron I. Packman Andrea Marion Mattia Zaramella Cheng Chen Jean-François Gaillard Denis T. Keane 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):433-442
Hyporheic exchange is known to provide an important control on nutrient and contaminant fluxes across the stream-subsurface
interface. Similar processes also mediate interfacial transport in other permeable sediments. Recent research has focused
on understanding the mechanics of these exchange processes and improving estimation of exchange rates in natural systems.
While the structure of sediment beds obviously influences pore water flow rates and patterns, little is known about the interplay
of typical sedimentary structures, hyporheic exchange, and other transport processes in fluvial/alluvial sediments. Here we
discuss several processes that contribute to local-scale sediment heterogeneity and present results that illustrate the interaction
of overlying flow conditions, the development of sediment structure, pore water transport, and stream-subsurface exchange.
Layered structures are shown to develop at several scales within sediment beds. Surface sampling is used to analyze the development
of an armor layer in a sand-and-gravel bed, while innovative synchrotron-based X-ray microtomography is used to observe patterns
of grain sorting within sand bedforms. We show that layered bed structures involving coarsening of the bed surface increase
interfacial solute flux but produce an effective anisotropy that favors horizontal pore water transport while limiting vertical
penetration. 相似文献
224.
T. D. Blackall M. R. Theobald C. Milford K. J. Hargreaves E. Nemitz L. J. Wilson J. Bull P. J. Bacon K. C. Hamer S. Wanless M. A. Sutton 《Water, Air, & Soil Pollution: Focus》2004,4(6):279-285
Ammonia emissions from two contrasting seabird colonies in Scotland were measured, based on the determination of atmospheric concentrations downwind of the colonies. Atmospheric concentrations of ammonia (NH3) across the downwind plume were compared with the inverse application of a Gaussian dispersion model (ID) to calculate the modelled NH3 emission that would generate the measured cross-wind-integrated plume concentration. In parallel, a tracer gas (sulphur hexafluoride, SF6) was released from the colonies with air samples taken to allow determination of SF6 concentrations. On the basis of the known emission rate of SF6, the magnitude of ammonia emissions was estimated by the cross-wind-integrated tracer ratio (TR) of NH3/SF6 concentrations. Coupled with data on annual bird attendance, the measurements indicate annual emissions from the Isle of May and the Bass Rock of 18 and 132 tonnes NH3-N year–1, respectively. The measured NH3 emissions were compared with estimates of seabird nitrogen excretion to estimate the proportion of excreted N that is volatilised as NH3 (FNr). The emission estimates of the two methods compared favourably, giving 4 and 6 kg NH3-N h–1 (FNr = 15%) for the Isle of May for the ID and TR methods, respectively, and 21 and 25 kg NH3-N h–1 (FNr = 50%) for the Bass Rock for the ID and TR methods, respectively. The results provide the first measurement-based estimates to allow regional up scaling of ammonia emissions from seabirds. 相似文献
225.
M. R. Theobald U. Dragosits C. J. Place J. U. Smith M. Sozanska L. Brown D. Scholefield A. Del Prado J. Webb P. G. Whitehead A. Angus I. D. Hodge D. Fowler M. A. Sutton 《Water, Air, & Soil Pollution: Focus》2004,4(6):135-142
The distribution and impacts of different nitrogen pollutants are inextricably linked. To understand the problem fully, the interactions between the different pollutants need to be taken into account. This is particularly important when it comes to abatement techniques, since measures to reduce emissions of one nitrogen pollutant can often lead to an increase in another. This project represents a step towards greater understanding of these issues by linking together new and existing nitrogen flux models into a larger framework. The modelling framework has been constructed and some of the nitrogen flows between fields, farms and the atmosphere have been modelled for a UK study area for typical farm management scenarios. 相似文献
226.
Steven N. Chillrud Richard F. Bopp James M. Ross Damon A. Chaky Sidney Hemming Edward L. Shuster H. James Simpson Frank Estabrooks 《Water, Air, & Soil Pollution: Focus》2004,4(2-3):469-482
Radionuclide, radiogenic lead isotope and trace metal analyses on fine-grained sediment cores collected along 160 km of the upper and tidal Hudson River were used to examine temporal trends of contaminant loadings and to develop radiogenic lead isotopes both as a stratigraphic tool and as tracers for resolving decadal particle transport fluxes. Very large inputs of Cd, Sb, Pb, and Cr are evident in the sediment record, potentially from a single manufacturing facility. The total range in radiogenic lead isotope ratios observed in well-dated cores collected about 24 km downstream of the plant is large (e.g., maximum difference in 206Pb/207Pb is 10%), characterized by four major shifts occurring in the 1950s, 1960s, 1970s and 1980s. The upper Hudson signals in Cd and radiogenic lead isotopes were still evident in sediments collected 160 km downstream in the tidal Hudson. The large magnitude and abrupt shifts in radiogenic lead isotope ratios as a function of depth provide sensitive temporal constraints that complement information derived from radionuclide analyses to significantly improve the precision of dating assignments. Application of a simple dilution model to data from paired cores suggests much larger sediment inputs in one section of the river than previously reported, suggesting particle influxes to the Hudson have been underestimated. 相似文献
227.
A solution containing 35SO4 2- and 3H2O was applied to four plots (5 × 5 m) in a boreal coniferous forest in the Laflamme Lake watershed, Québec, under two contrasting conditions: in summer (plots 1 and 2), and on the snowpack before snowmelt (plots 3 and 4). The transit of both these tracers in the soil solution was then followed through a network of soil lysimeters located at different depths. Four months after the summer application, 3H2O had infiltrated the whole soil profile at plot 1, while 35SO4 2- was only observed in the LFH and Bhf horizons. A 35SO4 2- budget calculated from mid-August to November indicated that 89 and 10.6% of the added 35SO4 2- was retained within the LFH and the Bhf layers, respectively. Fifteen months later, the added 35SO4 2- was distributed in the following proportions within the soil horizons: LFH (73.7%), Bhf (11.8%) and Bf (12.8%), for a total retention rate of 98.3%. The superficial penetration of 3H2O at plot 2 was indicative of a major lateral water movement that prevented the calculation of a 35SO4 2- budget. This situation also was observed at plot 4 during snowmelt. At plot 3, 3H2O moved freely through the soil profile and a significant fraction of the added 35SO4 2- reached the B horizons, where it was presumably adsorbed on aluminum (Al) and ferric (Fe) oxides. The 35SO4 2- budget for plot 3 from March to November indicated that 87% of the added 35SO4 2- was retained within the soil profile, with most being retained in the B horizons (LFH = 33.1%, Bhf = 33.1%, Bf = 20.8%). The contrasting retention patterns of 35SO4 2- within the soil profile following the summer addition and snowmelt likely was caused by the contrastingsoil temperatures and soil solution residence times within the differentsoil layers. The persistence of 35SO4 2- in the soil solution of the entire profile long after the initial tracer infiltration, and the relative temporal stability of specific activity of SO4 2-, point to the establishment of an isotopic equilibrium between the added 35SO4 and the active S-containing reservoirs within a given soil horizon. Overall, the results clearly illustrate the very strong potential for 35SO4 2- retention and recycling in forest soils. 相似文献
228.
Miskewitz R. J. Hires R. I. Su T. L. Korfiatis G. P. Sidhoum M. 《Water, Air, & Soil Pollution: Focus》2004,4(4-5):45-54
A 50 ha known contaminated site in Bayonne, New Jersey, U.S.A. is permitted to receive up to 3 × 106 m3 of sediment dredged from navigation channels in the New York/New Jersey Harbor. Much of the sediment is expected to contain low to moderate concentrations of industrial and agricultural chemicals, including Polychlorinated Biphenyls (PCBs). The dredged material brought to the site is stabilized with cement and then placed as a capping and grading layer. The flux of PCBs from drying stabilized dredged material has been estimated from measurements of PCB air concentrations at two heights above the ground along with micrometeorological observations. A statistically significant gradient in PCB concentrations has been consistently measured in the first 3 m above the ground. Observed PCB fluxes were highest over freshly placed stabilized dredged sediment and decreased as it cured. The highest flux observed in this study was 7214 ng/m2/h, but during subsequent sampling intervals at the same site, the flux estimates decreased by an order of magnitude over a 5-day interval. 相似文献
229.
An Erratum has been published for this article in Remediation 14(4) 2004, 141. The selection of remediation options for the management of unacceptable risks at contaminated sites is hindered by insufficient information on their performance under different site conditions. Therefore, there is a need to define “operating windows” for individual remediation options to summarize their performance under a variety of site conditions. The concept of the “operating window” has been applied as both a performance optimization tool and decision support tool in a number of different industries. Remediation‐option operating windows could be used as decision support tools during the “options appraisal” stage of the Model Procedures (CLR 11), proposed by the Environment Agency (EA) for England and Wales, to enhance the identification of “feasible remediation options” for “relevant pollutant linkages.” The development of remediation‐option operating windows involves: 1) the determination of relationships between site conditions (“critical variables”) and option performance parameters (e.g., contaminant degradation or removal rates) and 2) the identification of upper‐ and lower‐limit values (“operational limits”) for these variables that define the ranges of site conditions over which option performance is likely to be sufficient (the “operating window”) and insufficient (the “operating wall”) for managing risk. Some research has used case study data to determine relationships between critical variables and subsurface natural attenuation (NA) process rates. Despite the various challenges associated with the approach, these studies suggest that available case study data can be used to develop operating windows for monitored natural attenuation (MNA) and, indeed, other remediation options. It is envisaged that the development of remediation‐option operating windows will encourage the application of more innovative remediation options as opposed to excavation and disposal to landfill and/or on‐site containment, which remain the most commonly employed options in many countries. © 2004 Wiley Periodicals, Inc. 相似文献
230.
Ali M Alhemood Ashraf M Genaidy Richard Shell Michael Gunn Christin Shoaf 《International journal of occupational safety and ergonomics》2004,10(4):303-318
In this study, a survey instrument was developed to measure safety climate. A review of the scientific literature as well as consultation with an expert panel was used to determine the survey's dimensions. Next, the survey was administered, first as a pilot study (n = 15) and then as a full scale study (n = 229), to employees of the City of Cincinnati Department of Public Works. The psychometric integrity of the survey was assessed according to validity, reliability and utility criteria. Results are presented and discussed. 相似文献