全文获取类型
收费全文 | 2670篇 |
免费 | 76篇 |
国内免费 | 23篇 |
专业分类
安全科学 | 123篇 |
废物处理 | 109篇 |
环保管理 | 809篇 |
综合类 | 257篇 |
基础理论 | 631篇 |
环境理论 | 1篇 |
污染及防治 | 568篇 |
评价与监测 | 157篇 |
社会与环境 | 79篇 |
灾害及防治 | 35篇 |
出版年
2023年 | 14篇 |
2022年 | 20篇 |
2021年 | 28篇 |
2020年 | 20篇 |
2019年 | 32篇 |
2018年 | 50篇 |
2017年 | 46篇 |
2016年 | 61篇 |
2015年 | 53篇 |
2014年 | 53篇 |
2013年 | 287篇 |
2012年 | 107篇 |
2011年 | 137篇 |
2010年 | 110篇 |
2009年 | 119篇 |
2008年 | 155篇 |
2007年 | 144篇 |
2006年 | 126篇 |
2005年 | 95篇 |
2004年 | 77篇 |
2003年 | 97篇 |
2002年 | 86篇 |
2001年 | 56篇 |
2000年 | 45篇 |
1999年 | 24篇 |
1998年 | 43篇 |
1997年 | 28篇 |
1996年 | 38篇 |
1995年 | 46篇 |
1994年 | 31篇 |
1993年 | 44篇 |
1992年 | 36篇 |
1991年 | 15篇 |
1990年 | 23篇 |
1989年 | 17篇 |
1988年 | 24篇 |
1987年 | 15篇 |
1986年 | 19篇 |
1985年 | 28篇 |
1984年 | 23篇 |
1983年 | 24篇 |
1982年 | 34篇 |
1981年 | 34篇 |
1980年 | 32篇 |
1979年 | 21篇 |
1978年 | 23篇 |
1977年 | 11篇 |
1976年 | 8篇 |
1974年 | 7篇 |
1972年 | 9篇 |
排序方式: 共有2769条查询结果,搜索用时 15 毫秒
931.
Changes in contaminant mass discharge from DNAPL source mass depletion: evaluation at two field sites 总被引:1,自引:0,他引:1
Brooks MC Wood AL Annable MD Hatfield K Cho J Holbert C Rao PS Enfield CG Lynch K Smith RE 《Journal of contaminant hydrology》2008,102(1-2):140-153
Changes in contaminant fluxes resulting from aggressive remediation of dense nonaqueous phase liquid (DNAPL) source zone were investigated at two sites, one at Hill Air Force Base (AFB), Utah, and the other at Ft. Lewis Military Reservation, Washington. Passive Flux Meters (PFM) and a variation of the Integral Pumping Test (IPT) were used to measure fluxes in ten wells installed along a transect down-gradient of the trichloroethylene (TCE) source zone, and perpendicular to the mean groundwater flow direction. At both sites, groundwater and contaminant fluxes were measured before and after the source-zone treatment. The measured contaminant fluxes (J; ML(-2)T(-1)) were integrated across the well transect to estimate contaminant mass discharge (M(D); MT(-1)) from the source zone. Estimated M(D) before source treatment, based on both PFM and IPT methods, were approximately 76 g/day for TCE at the Hill AFB site; and approximately 640 g/day for TCE, and approximately 206 g/day for cis-dichloroethylene (DCE) at the Ft. Lewis site. TCE flux measurements made 1 year after source treatment at the Hill AFB site decreased to approximately 5 g/day. On the other hand, increased fluxes of DCE, a degradation byproduct of TCE, in tests subsequent to remediation at the Hill AFB site suggest enhanced microbial degradation after surfactant flooding. At the Ft. Lewis site, TCE mass discharge rates subsequent to remediation decreased to approximately 3 g/day for TCE and approximately 3 g/day for DCE approximately 1.8 years after remediation. At both field sites, PFM and IPT approaches provided comparable results for contaminant mass discharge rates, and show significant reductions (>90%) in TCE mass discharge as a result of DNAPL mass depletion from the source zone. 相似文献
932.
Mugu Lagoon is an estuary in southern California, listed as impaired for mercury. In 2005, we examined mercury cycling at ten sites within at most four habitats. In surface water (unfiltered and filtered) and pore water, the concentration of total mercury was correlated with methylmercury levels (R2=0.29, 0.26, 0.27, respectively, p<0.05), in contrast to sediments, where organic matter and reduced iron levels were most correlated with methylmercury content (R2=0.37, 0.26, respectively, p<0.05). Interestingly, levels for percent methylmercury of total mercury in sediments were higher than typical values for estuarine sediments (average 5.4%, range 0.024-38%, n=59), while pore water methylmercury Kd values were also high (average 3.1, range 2.0-4.2l kg(-1), n=39), and the estimated methylmercury flux from sediments was low (average 1.7, range 0.14-5.3ng m(-2) day(-1), n=19). Mercury levels in predatory fish tissue at Mugu are >0.3ppm, suggesting biogeochemical controls on methylmercury mobility do not completely mitigate methylmercury uptake through the food web. 相似文献
933.
Stieb DM Burnett RT Smith-Doiron M Brion O Shin HH Economou V 《Journal of the Air & Waste Management Association (1995)》2008,58(3):435-450
Air quality indices currently in use have been criticized because they do not capture additive effects of multiple pollutants, or reflect the apparent no-threshold concentration-response relationship between air pollution and health. We propose a new air quality health index (AQHI), constructed as the sum of excess mortality risk associated with individual pollutants from a time-series analysis of air pollution and mortality in Canadian cities, adjusted to a 0-10 scale, and calculated hourly on the basis of trailing 3-hr average pollutant concentrations. Extensive sensitivity analyses were conducted using alternative combinations of pollutants from single and multipollutant models. All formulations considered produced frequency distributions of the daily maximum AQHI that were right-skewed, with modal values of 3 or 4, and less than 10% of values at 7 or above on the 10-point scale. In the absence of a gold standard and given the uncertainty in how to best reflect the mix of pollutants, we recommend a formulation based on associations of nitrogen dioxide, ozone, and particulate matter of median aerodynamic diameter less than 2.5 microm with mortality from single-pollutant models. Further sensitivity analyses revealed good agreement of this formulation with others based on alternative sources of coefficients drawn from published studies of mortality and morbidity. These analyses provide evidence that the AQHI represents a valid approach to formulating an index with the objective of allowing people to judge the relative probability of experiencing adverse health effects from day to day. Together with health messages and a graphic display, the AQHI scale appears promising as an air quality risk communication tool. 相似文献
934.
Traffic and meteorological impacts on near-road air quality: summary of methods and trends from the Raleigh Near-Road Study 总被引:2,自引:0,他引:2
Baldauf R Thoma E Hays M Shores R Kinsey J Gullett B Kimbrough S Isakov V Long T Snow R Khlystov A Weinstein J Chen FL Seila R Olson D Gilmour I Cho SH Watkins N Rowley P Bang J 《Journal of the Air & Waste Management Association (1995)》2008,58(7):865-878
A growing number of epidemiological studies conducted worldwide suggest an increase in the occurrence of adverse health effects in populations living, working, or going to school near major roadways. A study was designed to assess traffic emissions impacts on air quality and particle toxicity near a heavily traveled highway. In an attempt to describe the complex mixture of pollutants and atmospheric transport mechanisms affecting pollutant dispersion in this near-highway environment, several real-time and time-integrated sampling devices measured air quality concentrations at multiple distances and heights from the road. Pollutants analyzed included U.S. Environmental Protection Agency (EPA)-regulated gases, particulate matter (coarse, fine, and ultrafine), and air toxics. Pollutant measurements were synchronized with real-time traffic and meteorological monitoring devices to provide continuous and integrated assessments of the variation of near-road air pollutant concentrations and particle toxicity with changing traffic and environmental conditions, as well as distance from the road. Measurement results demonstrated the temporal and spatial impact of traffic emissions on near-road air quality. The distribution of mobile source emitted gas and particulate pollutants under all wind and traffic conditions indicated a higher proportion of elevated concentrations near the road, suggesting elevated exposures for populations spending significant amounts of time in this microenvironment. Diurnal variations in pollutant concentrations also demonstrated the impact of traffic activity and meteorology on near-road air quality. Time-resolved measurements of multiple pollutants demonstrated that traffic emissions produced a complex mixture of criteria and air toxic pollutants in this microenvironment. These results provide a foundation for future assessments of these data to identify the relationship of traffic activity and meteorology on air quality concentrations and population exposures. 相似文献
935.
936.
Compost impacts on dissolved organic carbon and available nitrogen and phosphorus in turfgrass soil 总被引:1,自引:0,他引:1
Wright AL Provin TL Hons FM Zuberer DA White RH 《Waste management (New York, N.Y.)》2008,28(6):1057-1063
Compost application to turfgrass soils may increase dissolved organic C (DOC) levels which affects nutrient dynamics in soil. The objectives of this study were to investigate the influence of compost source and application rate on soil organic C (SOC), DOC, NO(3), and available P during 29 months after a one-time application to St. Augustinegrass [Stenotaphrum secundatum (Walt.) Kuntze] turf. Compost sources had variable composition, yet resulted in few differences in SOC, DOC, and NO(3) after applied to soil. Available NO(3) rapidly decreased after compost application and was unaffected by compost source and application rate. Available P increased after compost application and exhibited cyclical seasonal patterns related to DOC. Compost application decreased soil pH relative to unamended soil, but pH increased during the course of the study due to irrigation with sodic water. Increasing the compost application rate increased SOC by 3 months, and levels remained fairly stable to 29 months. In contrast, DOC continued to increase from 3 to 29 months after application, suggesting that compost mineralization and growth of St. Augustinegrass contributed to seasonal dynamics. Dissolved organic C was 75%, 78%, and 101% greater 29 months after application of 0, 80, and 160 Mg compostha(-1), respectively, than before application. Impacts of composts on soil properties indicated that most significant effects occurred within a few months of application. Seasonal variability of SOC, DOC, and available P was likely related to St. Augustinegrass growth stages as well as precipitation, as declines occurred after precipitation events. 相似文献
937.
Richard M. Bennett Ken G. Willis 《Journal of Environmental Planning and Management》2008,51(4):511-523
This paper applies an attribute-based stated choice experiment approach to estimate the value that society places on changes to the size of the badger population in England and Wales. The study was undertaken in the context of a rising incidence of bovine tuberculosis (bTB) in cattle and the government's review of current bTB control policy. This review includes consideration of culling badgers to reduce bTB in cattle, since badgers are thought to be an important wildlife reservoir for the disease. The design of the CE involved four attributes (size of badger population, cattle slaughtered due to bTB, badger management strategy and household tax) at four levels with eight choice sets of two alternatives presented to respondents. Telephone interviews were undertaken with over 400 respondents, which elicited their attitudes and preferences concerning badgers, bTB in cattle and badger management strategies. The study estimated a willingness to pay of £0.10 per household per year per 100,000 badgers and £1.52 per household per year per 10,000 cattle slaughtered due to bTB which aggregated to £22 per badger and £3298 per bTB slaughtered animal for all households in England and Wales. Management strategy toward badgers had a very high valuation, highlighting the emotive issue of badger culling for respondents and the importance of government policy towards badgers. 相似文献
938.
Langer P Kocan A Tajtáková M Rádiková Z Petrík J Koska J Ksinantová L Imrich R Hucková M Chovancová J Drobná B Jursa S Bergman A Athanasiadou M Hovander L Gasperíková D Trnovec T Seböková E Klimes I 《Chemosphere》2007,70(1):110-118
In polluted district of Michalovce in East Slovakia (POLL) and two districts with background pollution (BCGR) 2046 adults (834 males and 1212 females aged 20-75 years) were examined. Serum levels of thyrotropin (TSH), free thyroxine (FT4), total triiodothyronine (TT3) and antithyroperoxidase antibodies (TPOab) were estimated by electrochemiluminiscent assay and also these of 15 polychlorinated biphenyl congeners (PCBs), p,p'-DDE, p,p'-DDT, hexachlorobenzene (HCB) and hexachlorocyclohexane were measured by high resolution gas chromatography/mass spectrometry. In addition, also dioxins, furans, coplanar- and mono-ortho-PCBs as well as selected hydroxylated and methylsulphonated PCBs and DDE metabolites were measured by appropriate methods based on gas chromatography/mass spectrometry principle. In POLL significantly higher levels of all organochlorines were found than these in BCGR. When pooled values from both areas were stratified in terms of PCBs level and treated as continuous variables, positive association of PCBs with FT4 and TT3 was found, the latter two being also mutually associated. However, within the category of PCBs level <530 ng/glipid (n=232) the association between PCBs and both the FT4 (p<0.09) and TT3 (p<0.03) was negative and any association of these was not found within the category of PCBs level of 531-1000 ng/g (n=691). In contrast, in the category of 531-2000 ng/g (n=1307) positive association appeared between PCBs and FT4 (p<0.001) as well as TT3 (p<0.05). Highly significant association of PCBs with FT4 (p<0.001) was further found in the categories with PCBs level of 1001-101414 ng/g (n=1307) and 2001-101414 (n=1123), while significant association with TT3 was observed only in the category of 531-2000 ng/g. Such findings suggest possible threshold level in positive effect of PCBs on FT4 and TT3 level which seems to be individual and located somewhere around the PCBs level of 1000 ng/g. However, highly significant negative association of both FT4 and TT3 with TSH was found in each of above indicated PCBs categories. Considerable difference in FT4 and TT3 level between large groups of subjects with the same range of PCBs level was also found suggesting different individual susceptibility to the effects of organochlorines. Among a total of 26 cases from POLL with very low TSH level (<0.5 mU l(-1)) 13 cases showed very high level of PCBs, FT4 and TT3, thus supporting a hypothesis on a novel sporadic form of high PCBs related peripheral subclinical hyperthyroidism possibly resulting from the long-term disruption of equilibrium between bound and free thyroxine in plasma by high PCBs level followed by a striking inhibition of TSH release from the pituitary. 相似文献
939.
Light nonaqueous-phase liquids (LNAPLs) such as gasoline and diesel fuel are among the most common causes of soil and groundwater contamination. Dissolution and subsequent advective transport of LNAPL components can negatively impact water supplies, while biodegradation is thought to be an important sink for this class of contaminants. We present a laboratory investigation of the effect of a water-table fluctuation on dissolution and biodegradation of a multi-component LNAPL (85% hexadecane, 5% toluene, 5% ethylbenzene, and 5% 2-methylnapthalene on a molar basis) in a pair of similar model aquifers (80 cm x 50 cm x 3 cm), one of which was subjected to a water-table fluctuation. Water-table fluctuation resulted in LNAPL and air entrapment below the water table, an increase in the vertical extent of the LNAPL source zone (by factor 6.7), and an increase in the volume of water passing through the source zone (by factor ~18). Effluent concentrations of dissolved LNAPL components were substantially higher and those of dissolved nitrate lower in the model aquifer where a fluctuation had been induced. Thus, water-table fluctuation led to enhanced biodegradation activity (28.3 mmol of nitrate consumed compared to 16.3 mmol in the model without fluctuation) as well as enhanced dissolution of LNAPL components. Despite the increased biodegradation, fluctuation led to increased elution of dissolved LNAPL components from the system (by factors 10-20). Hence, water-table fluctuations in LNAPL-contaminated aquifers might be expected to result in increased exposure of downgradient receptors to LNAPL components. Accordingly, water-table fluctuations in contaminated aquifers are probably undesirable unless the LNAPL is of minimal solubility or the dissolved-phase plume is not expected to reach a receptor due to distance or the presence of some form of containment. 相似文献
940.
Uranium removal from groundwater via in situ biostimulation: Field-scale modeling of transport and biological processes 总被引:1,自引:0,他引:1
Yabusaki SB Fang Y Long PE Resch CT Peacock AD Komlos J Jaffe PR Morrison SJ Dayvault RD White DC Anderson RT 《Journal of contaminant hydrology》2007,93(1-4):216-235
During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to identify the dominant transport and biological processes controlling uranium mobility during biostimulation, and determine field-scale parameters for these modeled processes. The coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes based on the 2002 field experiment, that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of the bioavailable Fe(III) mineral threshold for the onset of sulfate reduction, and rates for the Fe(III), U(VI), and sulfate terminal electron accepting processes. 相似文献