Distribution of total and methylmercury in different ecosystem compartments in the Everglades: implications for mercury bioaccumulation

We analyzed Hg species distribution patterns among ecosystem compartments in the Everglades at the landscape level in order to explore the implications of Hg distribution for Hg bioaccumulation and to investigate major biogeochemical processes that are pertinent to the observed Hg distribution patterns. At an Everglade-wide scale, THg concentrations were significantly increased in the following order: periphyton相似文献   

Temporal Changes in Allele Frequencies and a Population's History of Severe Bottlenecks

Monitoring temporal changes in genetic variation has been suggested as a means of determining if a population has experienced a demographic bottleneck. Simulations have shown that the variance in allele frequencies over time ( F ) can provide reasonable estimates of effective population size ( N_e ). This relationship between F and N_e suggests that changes in allele frequencies may provide a way to determine the severity of recent demographic bottlenecks experienced by a population. We examined allozyme variation in experimental populations of the eastern mosquitofish ( Gambusia holbrooki ) to evaluate the relationship between the severity of demographic bottlenecks and temporal variation in allele frequencies. Estimates of F from both the fish populations and computer simulations were compared to expected rates of drift. We found that different methods for estimating F had little effect on the analysis. The variance in estimates of F was large among both experimental and simulated populations experiencing similar demographic bottlenecks. Temporal changes in allele frequencies suggested that the experimental populations had experienced bottlenecks, but there was no relationship between observed and expected values of F . Furthermore, genetic drift was likely to be underestimated in populations experiencing the most severe bottlenecks. The weak relationship between F and bottleneck severity is probably due to both sampling error associated with the number of polymorphic loci examined and the loss of alleles during the bottlenecks. For populations that may have experienced severe bottlenecks, caution should be used in making evolutionary interpretations or management recommendations based on temporal changes in allele frequencies.     

自适应神经网络在确定落煤残存瓦斯量中的应用

落煤残存瓦斯量的确定是采掘工作面瓦斯涌出量预测的重要环节，它直接影响着采掘工作面瓦斯涌出量预测的精度，并与煤的变质程度、落煤粒度，原始瓦斯含量、暴露时间等影响因素呈非线性关系，人工神经网络具有表示任意非线性关系和学习的能力，是解决复杂非线性，不确定性和时变性问题的新思想和新方法，基于此，作提出自适应神经网络的落煤残丰瓦斯量预测模型，并结合不同矿井落煤残存瓦斯量的实际测定结果进行验证研究，结果表明，自适应调整权值的变步长BP神经网络模型预测精度高，收敛速度快，该预测模型的应用可为采掘工作面瓦斯涌出量的动态预测提供可靠的基础数据，为采掘工作面落煤残存瓦斯量的确定提出了一种全新的方法和思路。     

Sustainability metrics for the business enterprise

Sustainable development poses challenges and opportunities to the development and management of business and technological systems. Most significantly, sustainability moves beyond meeting an economic and environmental bottom line to a triple bottom line of integrated economic, environmental, and social factors. Over 30 years there has been a paradigm shift that has led to the greening of industrial practices with regards to the environment. As evidence continues to demonstrate linkages between environmental causes and effects, problem-solving techniques have been developed to meet both economic and environmental goals along with metrics to measure environmental performance. Today, sustainable development presents another paradigm shift and adds social considerations as a third element to the bottom line. This article describes the evolution from greening to sustaining and outlines the implication of developing metrics in the sustainable development context.© 1999 John Wiley & Sons, Inc.     

A flexible spatio-temporal model for air pollution with spatial and spatio-temporal covariates

The development of models that provide accurate spatio-temporal predictions of ambient air pollution at small spatial scales is of great importance for the assessment of potential health effects of air pollution. Here we present a spatio-temporal framework that predicts ambient air pollution by combining data from several different monitoring networks and deterministic air pollution model(s) with geographic information system covariates. The model presented in this paper has been implemented in an R package, SpatioTemporal, available on CRAN. The model is used by the EPA funded Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air) to produce estimates of ambient air pollution; MESA Air uses the estimates to investigate the relationship between chronic exposure to air pollution and cardiovascular disease. In this paper we use the model to predict long-term average concentrations of \(\text {NO}_{x}\) in the Los Angeles area during a 10 year period. Predictions are based on measurements from the EPA Air Quality System, MESA Air specific monitoring, and output from a source dispersion model for traffic related air pollution (Caline3QHCR). Accuracy in predicting long-term average concentrations is evaluated using an elaborate cross-validation setup that accounts for a sparse spatio-temporal sampling pattern in the data, and adjusts for temporal effects. The predictive ability of the model is good with cross-validated \(R^2\) of approximately \(0.7\) at subject sites. Replacing four geographic covariate indicators of traffic density with the Caline3QHCR dispersion model output resulted in very similar prediction accuracy from a more parsimonious and more interpretable model. Adding traffic-related geographic covariates to the model that included Caline3QHCR did not further improve the prediction accuracy.     

R/S法的土石坝施工期沉降规律及预警标准研究

为提高施工期土石坝沉降安全性,研究其具有复杂非线性特征的施工期沉降规律和相应的预警标准。基于国内某在建高土石坝的沉降数据,采用R/S法分析坝体不同高程测点、同高程测点和同测点不同时期沉降数据的Hurst指数及分形维数,提出评价坝体施工期沉降安全性的预警标准。结果表明:各测点的Hurst指数最小值为0.763,坝内各处沉降仍处于快速增长阶段;坝体下部比上部、中部比下游堆石区沉降能更快趋于稳定,且坝体下部的沉降速率已经渐趋平缓。     

民营企业安全文化模型及其实证分析

针对民营企业特点,基于交互安全文化模型,建立民营企业安全文化模型并辨识 关键元素,以赛轮金宇股份有限公司为例进行实证分析。在广泛参考国内外相关研究的 基础上,设计调查问卷,运用粗糙集ROSETTA软件对测量结果进行属性简约,最终确定 15个安全文化元素;借助MATLAB,采用熵权法确定各元素权重,然后进行可拓综合评价 。评价结果表明该企业的“高层管理者重视”一项得分为4.82,水平较高,整体文化等 级属于“良”,级别特征变量j*=3.138 1。“创造安全舒适的工作环境”、“建立合理 的奖惩制度”、“定期进行应急演练”3个方面得分偏低,是安全文化建设需要重点加 强的方面。     

Re-creating missing population baselines for Pacific reef sharks

Sharks and other large predators are scarce on most coral reefs, but studies of their historical ecology provide qualitative evidence that predators were once numerous in these ecosystems. Quantifying density of sharks in the absence of humans (baseline) is, however, hindered by a paucity of pertinent time-series data. Recently researchers have used underwater visual surveys, primarily of limited spatial extent or nonstandard design, to infer negative associations between reef shark abundance and human populations. We analyzed data from 1607 towed-diver surveys (>1 ha transects surveyed by observers towed behind a boat) conducted at 46 reefs in the central-western Pacific Ocean, reefs that included some of the world's most pristine coral reefs. Estimates of shark density from towed-diver surveys were substantially lower (<10%) than published estimates from surveys along small transects (<0.02 ha), which is not consistent with inverted biomass pyramids (predator biomass greater than prey biomass) reported by other researchers for pristine reefs. We examined the relation between the density of reef sharks observed in towed-diver surveys and human population in models that accounted for the influence of oceanic primary productivity, sea surface temperature, reef area, and reef physical complexity. We used these models to estimate the density of sharks in the absence of humans. Densities of gray reef sharks (Carcharhinus amblyrhynchos), whitetip reef sharks (Triaenodon obesus), and the group "all reef sharks" increased substantially as human population decreased and as primary productivity and minimum sea surface temperature (or reef area, which was highly correlated with temperature) increased. Simulated baseline densities of reef sharks under the absence of humans were 1.1-2.4/ha for the main Hawaiian Islands, 1.2-2.4/ha for inhabited islands of American Samoa, and 0.9-2.1/ha for inhabited islands in the Mariana Archipelago, which suggests that density of reef sharks has declined to 3-10% of baseline levels in these areas.     

Trends in agriculture in the LEASEQ watersheds, 1975-1995. Lake Erie Agricultural Systems for Environmental Quality

County-level agricultural statistics were aggregated at the watershed level to provide estimates of trends in land use and agricultural management in the Maumee and Sandusky River watersheds during the period 1975-1995. Average farm size increased by 40% or more, but the number of farms decreased by nearly 40%; the total land area in agriculture also decreased, but only by about 7%. Conservation tillage increased from virtually nothing to nearly 50% of cropland in corn (Zea mays L.) and soybean [Glycine max (L.) Merr.]; most of the change is due to adoption of no-till soybean. The Conservation Reserve Program has enrolled more than 75,000 hectares, but this represents less than 5% of total farmland. The great majority of land classified as highly erodible has been placed under treatment during the study period. Cropland in soybean has increased; land in wheat (Triticum aestivum L.) and hay has decreased. Cropland in corn has decreased in the Maumee watershed and increased slightly in the Sandusky watershed. Average per-hectare yields of corn, soybean, wheat, and hay have increased by 10 to 40%. Fertilizer phosphorus sales increased until about 1980 and have declined significantly since then; fertilizer nitrogen follows a similar but less pronounced pattern. The decreases are more substantial in the Maumee watershed than in the Sandusky. Manure use for fertilizer has also declined significantly.     

Aerosol chemical and optical properties during the Mt. Zirkel Visibility Study

Aerosol chemical and optical properties were measured near the Mt. Zirkel Wilderness Area in northwestern Colorado. Six-hour PM2.5 (particles with aerodynamic diameters less than 2.5 microm) mass concentrations and PM2.5 dry particle light scattering at 550 nm averaged 4.6 microg m(-3) and 8.6 Mm(-1), respectively. Sulfates, organic carbon, and geological material were the principle components of particle mass and light scattering. Hygroscopic growth was consistent with that expected for ammonium sulfate aerosols. Size distributions derived from three-wavelength (i.e., 450, 550, and 700 nm) nephelometer data were similar to those measured in other remote areas of the western USA. Quasi-dry chemical light scattering efficiencies derived using Mie theory were 3.6 m2 g(-1) for organic carbon, 2.5 m2 g(-1) for sulfates (ammonium sulfate and ammonium bisulfate), 2.6 m2 g(-1) for ammonium nitrate, and 1.76 m2 g(-1) for geological material. These values are lower than but consistent with previously reported results. Realistic efficiencies could not be derived using the multiple linear regression (MLR) approach.