Objective Evaluation of Emergency Plans for Oxidant Control

Emergency plans for oxidant controls provide the basis for taking preventive action to protect public health. Historic oxidant data (1970 to Sept. 1974) from the South Coast Air Basin (SCAB), were evaluated to assess episode characteristics in an area where emergency strategies are most likely to be enforced. These findings, together with an objective study of a test case episode (June 1974) using a photochemical air quality simulation model, suggest that the currently conceived emergency plans for oxidant control are unlikely to be effective. It is concluded that, because of the chemical and mefeorofogfcal complexities of the episodes, they are extremely difficult both to predict and concurrently to control over their short-lived duration.     

A Model for Uptake of Pollutants by Vegetation

A mass transfer approach is used in developing a practical mathematical model of gaseous pollutant uptake by leaves in which a series of resistances is summed across a concentration difference. The body of information presented in this paper is directed to plant pathologists or physiologists in the field of vegetal-pollutant effects and to people interested in the natural removal of air pollutants by vegetation. Correlations are given to calculate the aerodynamic and the stomatal resistances to uptake, while both a qualitative investigation and quantitative estimates are made of the mesophyllic resistance. The factors which control the aerodynamic resistance, r_a, are leaf size and wind speed, while the leaf physiology is the determinant of the stomatal resistance, r_s . It is noted that the chemical reaction rate and pollutant diffusivity in the mesophyll control the mesophyllic resistance, r_m, though the overall gas phase mesophyllic resistance, Hr_m, is strongly a function of pollutant solubility in water. Finally, the overall model is compared to earlier experimental work on vegetal uptake of SO₂.     

Economics and Alternatives for Sulfur Removal from Coke Oven Gas

Two processes are currently being employed in North America for the desulfurization of coke oven gas, the Vacuum Carbonate System, and the Stretford System. A third, the Sulfi-ban Process, which was recently announced, now has several plants scheduled for construction. Overall operating requirements for each of these processes are considered in detail. Emphasis is placed on an identification of power and steam requirements, the types and amounts of solid and/or liquid waste streams produced together with methods for their treatment, and the net desulfurization efficiencies achieved by each process. Detailed estimates of capital and operating costs for desulfurization are considered, and equipment needs for environmental control requirements are discussed.     

The Change of Concentration Standard Deviations with Distance

Calculations of pollutant concentrations at various downwind and crosswind distances from an elevated point source are frequently based on diffusion models and parameter values contained in Turner’s Workbook of Atmospheric Dispersion Estimates.1 These calculations can be made much more speedily on a computer or on a currentgeneration, programmable desk calculator, if the values of the horizontal and vertical standard deviations of plume concentrations distributions are stated explicitly as a mathematical function of downwind distance. The alternative is to read the values from Turner’s Figures 3-2 and 3-3 and input them into the calculation for each individual value of downwind distance.     

Results of Field Measurements of Industrial Particulate Sources and Electrostatic Precipitator Performance

This paper presents results of source size distribution measurements over the size range from 0.1 μm to 5 μm for six classes of particulate sources and fractional efficiency measurements on five full scale electrostatic precipitators and one pilot scale precipitator. The precipitators all showed moderately high to high particulate collection efficiencies for particles having diameters larger than a few micrometers or smaller than a few hundredths of a micrometer and a minimum in collection efficiency for particles having diameters of a few tenths of a micrometer.     

Product Guide/1975

Measurements conducted on full-scale hazardous waste incinerators have occasionally shown a relationship between carbon monoxide (CO) emissions and emissions of toxic organic compounds. In this study, four mixtures of chlorinated C₁ and C₂ hydrocarbons were diluted in commercial-grade heptane and burned in a water-cooled turbulent flame reactor (TFR) under two different excess air levels. No correlation between CO and organic emissions could be discerned. Reasons for this lack of observable correlations are discussed in terms of combustion and chemical reaction kinetic theory.     

Variance Design and Air Pollution Control

Confronted with shortages of low sulfur content residual fuel oil and, consequently, faced with the threat of social and economic upheaval, several air pollution control authorities in the Northeastern states were forced to relax hard-won air quality standards during the winter of 1972. The authorities did so by granting variances to their sulfur content standards for residual fuel oil. This paper examines the institutional characteristics of these variance policies from an economic incentive standpoint. After setting up desirable structural criteria for institutional design of such crisis policies, the authors examine the experience of the winter of 1972 and arrive at policy guidelines which recommend themselves for consideration in future periods of fuel oil shortages.     

Status and Problems of Regenerable Flue Gas Desulfurization Processes

Fourteen sulfur and/or sulfuric acid producing regenerate FGD processes were discussed at the 1974 FGD Symposium in Atlanta. During the period elapsed since then, considerable status change has occurred on many of these regenerable processes. Other regenerable processes which were not as well known during 1974 have surfaced in 1975. The problems of obtaining reducing gases (hydrogen sulfide, carbon monoxide, and hydrogen) for the reduction of sulfur dioxide product streams to elemental sulfur have become severe due to shortages of natural gas or other petroleum based feedstock. A new sulfur producing process which employs CO and H₂ directly (rather than the H₂S required for liquid and vapor base Claus reactions) is gaining attention. This paper discusses briefly: (1) the announced status of the many regenerable FGD processes, (2) the problem of reductant gas supply, and (3) the effect on FGD processes of using coal based reducing gas instead of reformed natural gas.     

Characterization of Particulates from Power Plants

The emphasis on participate control from industrial processes has been shifted recently towards fine particulates, having diameters less than 3 microns. There exists an urgent need for more scientific information of fine particle characterization.^1,2 Coal and oil fired power plants are among the largest anthropogenic point sources of particulate matter.³ Limited knowledge is available on particle size distribution and trace metal composition in power plant emissions.^4-7 The morphological properties of particle emissions have been largely neglected. In this report we present some information on particle characteristics for an oil-fired and coal-fired power plant.     

An Integrated Program to Achieve Maximum Performance of Electrostatic Precipitators

The objective of this paper is to describe the Tennessee Valley Authority's efforts and plans in designing an operating and maintenance program that will ensure maximum performance of the electrostatic precipitators at our power generating stations. Detailed operating and maintenance manuals are being prepared for each plant for the use of plant personnel. These manuals include instructions on operation, maintenance, and testing of the precipitators. Instructions on internal and external equipment inspections to be performed during unit operation, emergency and scheduled outages, and problem diagnostic procedures are included to help the plant personnel solve problem areas. Performance curves are included in the manuals which show the effect of gas volume flow, gas temperature, gas resistivity, coal changes, and loss of transformer-rectifier sets on the precipitator performance. In addition, opacity monitors that record continuous opacity readings are being installed at all our plants to assist the plant in monitoring precipitator performance. Full-time operating and maintenance crews are being organized at the plants to monitor and maintain the precipitator and ash-removal systems. Also, a staff of technical personnel is being organized at the central office to provide technical advice and assistance in design, operation, and maintenance problems and liaison and coordination for all the plants concerning the precipitators. Periodic precipitator field inspections, performance and operating parameter optimization testing, and review of the equipment operating logs are made by the central office technical personnel. Recommendations and technical assistance are then furnished to the plant with regard to the precipitator overall performance and operating characteristics.