Remediation with cyclodextrin: Recovery of the remedial agent by membrane filtration

Cyclodextrin‐enhanced flushing of contaminants from the subsurface is a promising innovative remediation technology. It will become more economically viable at more sites if methods can be developed to recover and reconcentrate the cyclodextrin solution after it has been flushed through an aquifer. The goal of this study was to determine if membrane technology is capable of meeting that need. Five membranes with different material properties were tested for this purpose in the laboratory. The results of these tests indicate that there are large differences both in the efficiency of these membranes to extract hydroxpropyl‐β‐cyclodextrin (HPCD) and their stability when exposed to trichloroethylene (TCE) at concentrations near aqueous solubility. Not only does the molecular weigh cutoff (MWCO) of a membrane determine if HPCD can be retained, but crucial selection criteria are the membrane's resistance and compatibility with TCE. Of the five membrane materials tested, only two (polymer composite membrane and polysulfone) met both these requirements. The polymer composite membrane (MPF‐44) showed reliable and stable HPCD recoveries (>95 percent) even when exposed to high TCE concentrations. The polysulfone membrane showed high HPCD recoveries, 88.5 ± 0.4 percent to 97 percent ±1 percent for ultrafiltration and nanofiltration membranes, respectively. However, membrane swelling and deterioration became a problem at high TCE concentrations (>1,000 mg/L). These problems diminished when the TCE concentration was less than 1 mg/L. Field tests demonstrated that batch mode treatment by ultrafiltration doubled the cyclodextrin concentration from 5 to 10 percent within three hours at a constant operating pressure of 13 psi. Under continuous single‐pass treatment conditions, cyclodextrin concentration also increased, although the rate of increase was much smaller than in batch mode. Overall, these tests showed that cyclodextrin recovery is possible under field conditions. © 2007 Wiley Periodicals, Inc.     

Emotional intelligence and individual performance: evidence of direct and moderated effects

We examined the direct and moderated effects of an ability‐based measure of emotional intelligence (MSCEIT© V2.0) on individual performance in a sample of business undergraduates. Controlling for general mental ability and personality, emotional intelligence explained unique incremental variance in performance ratings on only one of two measures of interpersonal effectiveness (public speaking effectiveness). However, the interaction of emotional intelligence with conscientiousness explained unique incremental variance both in public speaking and group behavior effectiveness, as well as academic performance (cumulative GPA). We conclude that the effects of emotional intelligence on performance are more indirect than direct in nature. Individuals must not only have emotional intelligence, but also must be motivated to use it. Copyright © 2006 John Wiley & Sons, Ltd.     

Stress among air traffic controllers: Occupational sources of coronary heart disease risk

This study attempts to assess the sources of occupational stress on air traffic controllers. It is based on data collected from a majority of air traffic controllers at a large U.K. airport. There are two unique methodological features described in this article. First, the use of the repertory grid technique as a method of generating work stressor variables, and second, the use of the multiple logistic equation as a coronary heart disease risk index.     

PLANNING FOR THE REHABILITATION OF GRAVEL PITS1

ABSTRACT: By field investigations and planning, it is profitable to rehabilitate gravel pits as recreational lakes in urban areas. Some of the important aspects to be considered are topography, soil, surface water and groundwater. A case study is presented and some general guidelines in the rehabilitation process are given. This kind of a use for derelict land is important at the present time as there is a growing demand for recreational lakes in urban areas.     

EVALUATION OF COPPER ACCUMULATION IN PART OF THE CALIFORNIA AQUEDUCT1

ABSTRACT: Copper sulfate has been used extensively in the California Aqueduct to control phytoplankton and the alga Cladophora. Since 1969 more than 250,000 pounds of copper sulfate has been added to a part of the aqueduct. Although copper sulfate is effective in controlling algae, copper tends to accumulate in the system in which it is applied. Samples of water, biota including plants, clams, and snails, as well as sediment were analyzed for copper. Results of these analyses showed that copper concentrations in the water, with three exceptions, were less than 10 micrograms per litre. Samples of plant tissue showed a 198 percent increase in copper concentration in the treated reach of the aqueduct, and clam tissue showed a 68 percent increase. Snails in the treated reach had 77 percent more copper than in the untreated reach whereas copper concentrations in the sediment doubled. None of the concentrations found are considered to be harmful to the biota.     

A METHOD FOR ESTIMATING SNOWFALL AMOUNTS1

ABSTRACT: Long-term climatic data from National Weather Service stations in six areas of the United States were utilized to develop regression equations relating a “snowfall index” parameter and air temperature. Nearly 200 stations, representing a wide range in physiographic and climatic conditions, were selected for analysis. Snowfall index is defined as the ratio of snowfall depth to precipitation. Using annual data, regression analysis indicated snowfall index to be significantly (α= 0.01) related to temperature for five of the six areas studied. Differences between equations were attributed to the effects of precipitation and temperature during non-snowfall periods. Mean monthly data were also considered and significant equations (α= 0.011, representing a family of similarly shaped curves, were obtained. The illustrated equations can be used for estimating mean monthly and annual snowfall amounts for stations having only temperature and precipitation measurements.     

Footstep-induced sediment displacement in the Grand Canyon

The Glen Canyon Dam has severely altered the riparian zone of the Colorado River in the Grand Canyon. One result of the controlled river discharge is more efficient prediction of water stages at the major rapids, leading to higher visitor use. Increased visitation results in heavy foot traffic, trampling along the river banks, erosion of the campsite soils, and the destruction of vegetation. Erosion occurs when the surfaces are roughened, exposing them to wind transport and runoff. In addition, each footstep physically displaces sand downhill.The results of a field experiment designed to measure the amount of sand displaced by footsteps show that each year trampling alone displaces 230 m³ of sand downslope and into the river. With the controlled river flow, no natural processes exist to replace the lost sediment.