The use of volcanic soil as mineral landfill liner--I. Physicochemical characterization and comparison with zeolites.

The main physicochemical characteristics of the volcanic soil of Southern Chile, with allophane as the main pedogenic mineral phase were analysed and compared with common zeolites (clinoptilolite) of the European market. The ultimate goal of this study was to test volcanic soil for the use as mineral landfill liner. The main results indicated that the clay and silt fractions together of the volcanic soil were between 38 and 54%. The buffering capacity of the volcanic soil was higher compared with the studied zeolites, whereas the cationic exchange capacity of the volcanic soil (between 5.2 and 6.5 cmol + kg(-1)) is of the same order of magnitude of the studied zeolites (between 9.7 and 11.4 cmol + kg(-1)). Moreover, the anionic exchange capacity of the volcanic soil was higher compared to the zeolites analysed. The hydraulic conductivity of the volcanic soil, measured in the laboratory at maximum proctor density, ranges between 5.16 x 10(-9) and 6.48 x 10(-9) m s(-1), a range that is comparable to the value of 4.51 x 10(-9) m s(-1) of the studied zeolite. The Proctor densities of the volcanic soil are in a lower range (between 1.11 and 1.15 g ml(-1)) compared with zeolites (between 1.19 and 1.34 g ml(-1)). The volcanic soil physicochemical characteristics are comparable to all the requirements established in the Austrian landfill directive (DVO, 2000). Therefore, the use as mineral landfill basal sealing of the analysed volcanic soil appears reasonable, having a pollutant adsorption capacity comparable to zeolites. It is of special interest for Southern Chile, because there are no alternative mineral raw materials for basal liners of landfills.     

Sustainability assessment of a giant bamboo plantation in Brazil: exploring the influence of labour,time and space

Bamboo presents physical and mechanical characteristics, which turn it an alternative option for product development, replacing native or reforested wood. The sustainability assessment of a Dendrocalamus Giganteus species plantation in Brazil through the emergy methodology evidences a great weight of renewable (30% sej/sej) and human labour contributions (33% sej/sej). These contributions account for the great interface with environment and to the intensive work, respectively. The transformity value of bamboo production is 2.42E + 04 sej/J. The influence human labour has on the total emergy flow and on indicators is evaluated by taking into account different country locations (Brazil, Australia and China). Thus, a different transformity value for labour is assumed for each country. A ranking based on emergy sustainability index (ESI) values shows that bamboo production in China was the first placed, followed by Brazil and Australia (values of 1.18, 0.50 and 0.09, respectively). The insertion of indirect renewability embedded in labour results in the ranking modification, leading to plantation in Brazil in the first place, followed by the Australian and Chinese ones. The relative position of the bamboo systems is visualized in the ternary diagram expressed in terms of emergy. In an attempt to explore the relationship between sustainability and time, a graphic of ESI vs. global productivity is discussed in terms of a prospective evaluation. Indirect support areas of the bamboo production are calculated as a way to evaluate the sustainability-space relationship.     

Going beyond the rhetoric: system-wide changes in universities for sustainable societies

In October 2008, the 5th Environmental Management for Sustainable Universities (EMSU) international conference was held in Barcelona, Spain. It dealt with the need to rethink how our higher educational institutions are facing sustainability. This special issue has been primarily derived from contributions to that conference. This issue builds upon related academic international publications, which have analysed how to use the critical position of universities to accelerate their pace of working to help to make the transition to truly SUSTAINABLE SOCIETIES!This issue focus is on the ‘softer’ issues, such as changes in values, attitudes, motivations, as well as in curricula, societal interactions and assessments of the impacts of research. Insights derived from the interplay of the ‘softer’ issues with the ‘harder’ issues are empowering academic leaders to effectively use leverage points to make changes in operations, courses, curricula, and research. Those changes are being designed to help their students and faculty build resilient and sustainable societies within the context of climate change, the Decade of Education for Sustainable Development (DESD), and the UN Millennium Development Goals (MDGs).The overall systems approach presented by Stephens and Graham provides a structured framework to systematize change for sustainability in higher education, by stressing on the one hand the need for “learning to learn” and on the other hand by integrating leadership and cultural aspects. The “niche” level they propose for innovative interactions between practitioners such as EMSU is exemplary developed by all of the other documents in this special issue. To highlight some of the key elements of the articles in this issue, there are proposals for new educational methods based in sustainability science, a set of inspirational criteria for SD research activities, new course ranking and assessment methods and results of psychological studies that provide evidence that participatory approaches are the most effective way to change values within university members in order to facilitate the development and sharing of new sustainability norms.     

Barnacles: Possible indicators of zinc pollution?

Barnacles [Balanus balanoides (L.), Elminius modestus Darwin, Lepas anatifera (L.)] from several different sites were found to accumulate the heavy metal zinc. The majority of the zinc was deposited in the tissues associated with the gut, and the level of zinc in soft body tissue generally reflected well the level of zinc in the immediate sea-water environment. The zinc accumulated in the gut tissues was in the form of discrete granules, mainly within the parenchyma cells which surround the gut. These granules probably exist as an insoluble zinc salt. A comparison of the zinc level in barnacles with those recorded for some other marine organisms indicates the possible usefulness of barnacles as indicators of zinc pollution.     

Efficiency of energy delivery systems: II. Estimating energy costs of capital equipment

Procedures are developed and summarized that allow the calculation of the energy required to manufacture and install capital equipment, such as the material needed for a coalfired power plant. Three methods are available, each with certain strengths and weaknessess The first uses both literature value and national manufacturing statistics, the second uses a previously developed technique that disaggregates energy use according to how much each industry buys from all other industries, and the third technique is based on the average national relation between energy use and dollar flow. The most important differences between estimates of energy use by the different techniques relates to the inclusion or exclusion of labor and indirect expenditures rather than to differences in the data bases of the three techniques.     

Cracking the code: the genesis, use and future of the Code of Conduct

This paper reflects on the genesis of the Code of Conduct for the International Red Cross and Red Crescent Movement and Non-Governmental Organizations (NGOs) in Disaster Relief, on the tenth anniversary of its adoption. The origins, usage and future of the code are examined with respect to three debates, current at the time of its inception, namely: the debate about the core content of humanitarianism; the debate about coherence and the consensual nature of the humanitarian community; and the debate about the need for, and the ability to demonstrate, accountability. The paper concludes that although the Code of Conduct was very much a product of its time, its content remains relevant today. However, its future application hinges on the capacity of those who purport to follow it to realise true accountability, and on proving that the code, written essentially for natural disasters, is relevant to contemporary complex emergencies.     

The application of the psychological contract to workplace safety

INTRODUCTION: Psychological contracts of safety are conceptualized as the beliefs of individuals about reciprocal safety obligations inferred from implicit or explicit promises. Although the literature on psychological contracts is growing, the existence of psychological contracts in relation to safety has not been established. The research sought to identify psychological contracts in the conversations of employees about safety, by demonstrating reciprocity in relation to employer and employee safety obligations. The identified safety obligations were used to develop a measure of psychological contracts of safety. METHOD: The participants were 131 employees attending safety training sessions in retail and manufacturing organizations. Non-participant observation was used to collect the data during safety training sessions. Content analysis was used to analyze the data. Categories for coding were established through identification of language markers that demonstrated contingencies or other implied obligations. RESULTS: Direct evidence of reciprocity between employer safety obligations and employee safety obligations was found in statements from the participants demonstrating psychological contracts. A comprehensive list of perceived employer and employee safety obligations was compiled and developed into a measure of psychological contracts of safety. A small sample of 33 safety personnel was used to validate the safety obligations. CONCLUSIONS AND IMPACT ON INDUSTRY: Implications of these findings for safety and psychological contract research are discussed.