Occurrence and volatility of several trace elements in pulverized coal boiler

The contents of eight trace elements(Mn, Cr, Pb, As, Se, Zn, Cd, Hg) in raw coal, bottom ash and fly ash were measured in a 220 t/h pulverized coal boiler. Factors affecting distribution of trace elements were investigated, including fly ash diameter, furnace temperature, oxygen content and trace elements‘ characters. One coefficient of Meij was also improved to more directly show element enrichment in combustion products. These elements may be classified into three groups according to their distribution: Group 1. Hg, which is very volatile. Group 2: Pb, Zn, Cd, which are partially volatile. Group 3: Mn, which is hardly volatile. Se may be located between groups 1 and 2. Cr has properties of both group ! and 3. In addition, the smaller diameter of fly ash, the more relative enrichment of trace elements (except Mn). The fly ash showed different adsorption mechanisms of trace elements and the volatilization of trace elements rises with furnace temperature. Relative enrichments of trace elements(except Mn and Cr) in fly ash are larger than that in bottom ash. Low oxygen content can not always improve the volatilization of trace elements. Pb is easier to form chloride than Cd during coal combustion. Trace elements should be classified in accordance with factors.     

定量风险评价标准探讨

围绕定量评价标准对风险的度量和制定风险评价标准的基本原则等方面的进展和存在的问题进行了初步的探讨，分析归纳了国处有着的个人风险和社会风险标准，提出具有重大危害性的工业设施对员工或公众造成的风险，不应显著高于人们在日常生活中接触到其他风险；每年１０＾－６的死亡风险是可以忽略不计的个人风险水平等观点。     

街道峡谷地面源污染物扩散规律的风洞试验研究

在风洞中１／２５０街道峡谷模型的底板内释放示踪气体，通过对浓度分布特征的观测，分析了街道峡谷 面湖泊污染物的扩散过程及其与街道建筑物结构，风向及排放源强度等因素之间的关系，探讨了中性边界层风洞模拟微尺度湍流扩散过程的相似准则与相似参数，为建立街道峡谷地面源污染物扩散模型提供了物理基础。     

南水北调中线陕西水源区污染源排放时空变化特征

基于2008—2012年污染源环境统计数据,采用Spearman秩相关系数法等分析南水北调中线陕西水源区污废水及污染物年排放总量变化趋势,借助ArcGIS空间分析功能表征水源区污染源排放的空间分布特征。结果表明:2008—2012年水源区污废水和NH_3-N年排放总量呈显著上升趋势,COD、As、Pb、Cd、Cr和Hg年排放总量呈抛物线型变化,总体上COD、Pb、Cd年排放总量增加,As、Cr和Hg年排放总量降低。水源区污废水及污染物排放量空间差异明显,污废水、COD和NH_3-N排放涉及流域所有区县,其排放量从干流到流域边缘呈现较明显的梯度变化,即位于流域中心或地级市行政中心的区县排放量明显高于位于流域边缘的区县;As、Pb、Cd、Cr和Hg排放量呈现明显的区域分布,主要分布在勉县等8个区县。     

Spatial succession modeling of biological communities: a multi-model approach

Strong spatial correlation may exist in the spatial succession of biological communities, and the spatial succession can be mathematically described. It was confirmed by our study on spatial succession of both plant and arthropod communities along a linear transect of natural grassland. Both auto-correlation and cross-correlation analyses revealed that the succession of plant and arthropod communities exhibited a significant spatial correlation, and the spatial correlation for plant community succession was stronger than arthropod community succession. Theoretically it should be reasonable to infer a site's community composition from the last site in the linear transect. An artificial neural network for state space modeling (ANNSSM) was developed in present study. An algorithm (i.e., Importance Detection Method (IDM)) for determining the relative importance of input variables was proposed. The relative importance for plant families Gramineae, Compositae and Leguminosae, and arthropod orders Homoptera, Diptera and Orthoptera, were detected and analyzed using IDM. ANNSSM performed better than multivariate linear regression and ordinary differential equation, while ordinary differential equation exhibited the worst performance in the simulation and prediction of spatial succession of biological communities. A state transition probability model (STPM) was proposed to simulate the state transition process of biological communities. STPM performed better than multinomial logistic regression in the state transition modeling. We suggested a novel multi-model framework, i.e., the joint use of ANNSSM and STPM, to predict the spatial succession of biological communities. In this framework, ANNSSM and STPM can be separately used to simulate the continuous and discrete dynamics.     

基于荷载试验的空心板桥加固效率分析

基于3座预应力混凝土空心板桥在试验荷载下加固前后荷载试验及理论计算得出的板底平均应力和挠度结果,对比粘贴碳纤维筋加固、简支转连续加固和粘贴钢板加固3种方法对简支预应力空心板桥结构的力学性能的提升效果.结果表明,粘贴碳纤维筋加固及粘贴钢板加固方法对结构刚度有轻微提高,对结构的延性及承载力有一定的提高;简支转连续加固方法在...     

大型水利水电工程实施占用耕地补偿制度的思考

本文在分析长江三峡工程用地特点的基础上。对大型水利水电工程实施耕地补偿制度中的问题和困难进行调查研究，认为应从新的视角来认识大型水利水电工程的耕地占补平衡问题。进而探索耕地补偿制度实施的新途径和新方式。应在耕地总量动态平衡政策适当调整的基础上．将“以地补地”和“缴费补地”的方式相结合。既通过土地整理．在提商土地质量的前提下增加耕地的有效面积：又要落实耕地开垦费．扶持库区的土地整理。从而使库区的耕地占补制度顺利实施。     

综合资源立法是资源可持续利用的法律保证

资源的有效保护和永续利用在我国可持续发展战略中占有十分重要的地位。本文分析了我国资源法制建设中存在的问题，阐述了综合资源立法在资源法制建设体系中的意义。     

南盘江流域近30年季节性干旱时空分布特征

根据南盘江流域22个水文站、雨量站31 a（1979~2009年）的逐月降水资料,选用标准化降水指数（SPI）为研究指标,以11~3月为研究时段,统计近30 a来5个月时间尺度的干旱站次,分析南盘江流域季节性干旱特征;以11~3月5个月时间尺度的SPI多年平均值为指标,进行空间插值,分析南盘江流域干旱的空间分布特征。结果表明：（1）从年际上看,SPI总体上30 a来（1980~2009年）呈下降趋势,气象干旱加剧;从年代际上看,1995年以后气象干旱程度有加剧趋势;（2）南盘江流域各个地区都会发生不同程度的气象干旱,旱情总体上由南向北递增,东北部各站点11~3月的降水占全年的比例相对较小,流域内东北部干旱最严重;（3）南盘江流域冬春连旱较严重,应加强水利工程建设,为防旱、抗旱做好相应的准备措施     

危险化学品活性反应危害及混配危险的规则研究(Ⅴ)

第十四类有机酸 活性特点: 羧酸是具有HO-C=O官能团的有机物.在羧酸中,碳原子以SP2杂化成键,羟基氧的孤电子对与碳氧双键相共轭,使得C-O键加强,O-H键减弱,从而羧基中的氢可以离解,并且离解后形成的羧基负离子由于共轭加强,更增加了羧基负离子的稳定性,因而羧酸具有弱酸性.同时,也正是由于共轭而使羧基碳的亲电能力减弱,只与较强的亲核试剂(如金属烷氧化物)发生反应.