Geomechanical analysis of the Naylor Field,Otway Basin,Australia: Implications for CO2 injection and storage

A geomechanical assessment of the Naylor Field, Otway Basin, Australia has been undertaken to investigate the possible geomechanical effects of CO₂ injection and storage. The study aims to evaluate the geomechanical behaviour of the caprock/reservoir system and to estimate the risk of fault reactivation. The stress regime in the onshore Victorian Otway Basin is inferred to be strike–slip if the maximum horizontal stress is calculated using frictional limits and DITF (drilling induced tensile fracture) occurrence, or normal if maximum horizontal stress is based on analysis of dipole sonic log data. The NW–SE maximum horizontal stress orientation (142°N) determined from a resistivity image log is broadly consistent with previous estimates and confirms a NW–SE maximum horizontal stress orientation for the Otway Basin.An analytical geomechanical solution is used to describe stress changes in the subsurface of the Naylor Field. The computed reservoir stress path for the Naylor Field is then incorporated into fault reactivation analysis to estimate the minimum pore pressure increase required to cause fault reactivation (ΔP_p).The highest reactivation propensity (for critically-oriented faults) ranges from an estimated pore pressure increase (ΔP_p) of 1 MPa to 15.7 MPa (estimated pore pressure of 18.5–33.2 MPa) depending on assumptions made about maximum horizontal stress magnitude, fault strength, reservoir stress path and Biot's coefficient. The critical pore pressure changes for known faults at Naylor Field range from an estimated pore pressure increase (ΔP_p) of 2 MPa to 17 MPa (estimated pore pressure of 19.5–34.5 MPa).     

Understanding levels and trends of BDE-47 in the UK and North America: an assessment of principal reservoirs and source inputs

Despite increasing interest in the occurrence of Polybrominated diphenyl ethers (PBDEs) in the environment, there has been only limited effort expended to identify principal source input reservoirs and pathways into the environment. Taking a single congener BDE-47, an important component of the penta commercial product, we have estimated principal contemporary reservoirs and emissions in two regions with very different historical use patterns. In North America, production and use of the penta-product has been rising steadily for the last 20 years, whilst in the UK, use has been restricted over the last 10 years, and most recently, there has been an EU ban on use. Mass balance models have been applied using our contemporary emission estimates to predict environmental levels. Results highlight that contemporary emissions to air can account for contemporary air concentrations but cannot account for measured concentrations in principal reservoirs such as soils and sediments. Future efforts are needed to improve our knowledge of the stocks of PBDEs in use, and emission factors from those stocks, to better understand/predict past and likely future trends.     

Monitoring and evaluation in UK low-carbon community groups: benefits,barriers and the politics of the local

In the UK, there now exist hundreds of low-carbon community groups (LCCGs) that aim to decrease collective resource consumption and/or generate renewable energy through diverse social and environmental interventions. These groups have in recent years become the subject of political attention and funding schemes, underpinned by beliefs that LCCGs are key to fostering resilience to climate change and meeting national-level greenhouse gas emission reduction targets. While previous research into LCCGs has focused on drivers, barriers and outcomes of LCCG action, there is now growing policy and academic interest in groups' capacities for, and uses of, monitoring and evaluation (M&E) processes and tools. However, little is known about the experiences, opportunities and potential challenges for LCCGs undertaking M&E. In response, this paper draws on a Knowledge Exchange project that explored M&E processes and tools with a sample of UK LCCGs. It outlines the benefits and drawbacks of groups' attempts to achieve change and to account for their outcomes and/or impacts, individually, and as part of a wider movement. It argues that, while M&E could be one way for groups to “scale up” their impact without losing their grounding in place and community, issues of capacity, resources and utility remain paramount.     

Bankfull Regional Curves for the Inner and Outer Bluegrass Regions of Kentucky1

Brockman, Ruth R., Carmen T. Agouridis, Stephen R. Workman, Lindell E. Ormsbee, and Alex W. Fogle, 2012. Bankfull Regional Curves for the Inner and Outer Bluegrass Regions of Kentucky. Journal of the American Water Resources Association (JAWRA) 48(2): 391‐406. DOI: 10.1111/j.1752‐1688.2011.00621.x Abstract: Bankfull regional curves that relate channel dimensions and discharge to watershed drainage area are useful tools for assisting in the correct identification of bankfull elevation and in stream restoration and reconstruction. This study assessed 28 stable streams located in two physiographic regions of Kentucky: the Inner Bluegrass and the Outer Bluegrass. Bankfull channel dimensions, discharge, and return period as well as average channel slope, median bed material size, sinuosity, Rosgen stream classification, and percent impervious area were determined. Significant relationships were found between drainage area and the bankfull characteristics of cross‐sectional area, width, mean depth, and discharge for both the Inner Bluegrass and Outer Bluegrass regions (α = 0.05). It was also found that the percent impervious area in a watershed had minimal effect on bankfull dimensions, which is attributed to the well‐vegetated nature of the streambanks, cohesive streambank materials, and bedrock control. No significant differences between any of the Inner Bluegrass and Outer Bluegrass regional curves were found (α = 0.05). Comparisons were made between the Inner Bluegrass and Outer Bluegrass curves and others developed in karst‐influenced areas in the Eastern United States. Although few significant differences were found between the regional curves for bankfull discharge and width, a number of the curves differed with regards to bankfull cross‐sectional area and mean depth.     

Adaptation of the Daphnia sp. acute toxicity test: miniaturization and prolongation for the testing of nanomaterials

Manufacturing of nanomaterials (NMs) is often complex and expensive, and their environmental risks are poorly understood or even unknown. An economization of testing NMs is therefore desirable, which can be achieved by miniaturizing test systems. However, the downsizing of test vessels and volumes can enlarge the surface/volume ratio (SVR) which in turn can affect the bioavailable concentration of adsorbing substances like NMs. The present study focused on the miniaturization of the acute toxicity test with Daphnia magna. The adaptations were verified with three reference substances, the non-adsorbing potassium dichromate (K₂Cr₂O₇) and as potentially highly-adsorbing substances silver nanoparticles (AgNPs) and silver nitrate (AgNO₃). The miniaturized test was conducted in 24-well microtiter plates (MT) and simultaneously compared to the OECD standard test (ST). Furthermore, the test duration was prolonged from 48 to 96 h since NMs tend to show effects only after extended exposure. The toxicity of K₂Cr₂O₇ and AgNPs continued to increase within the prolonged test span. The test comparisons with K₂Cr₂O₇ did not reveal any significant differences between ST and MT. AgNO₃ toxicity was significantly decreased in MT compared to ST due to the enlarged SVR. The toxicity of AgNPs in MT after 24 h was equal to ST. Contrary to our expectations an exposure longer than 24 h resulted in an increase of AgNP toxicity in MT, possibly due to enhanced dissolution of silver. Microtiter plates are appropriate alternative test vessels for the Daphnia sp. acute toxicity test; thus, its miniaturization is feasible. The enlarged SVR has to be taken into account since it can affect the toxicity of potentially adsorbing substances. Furthermore, the standard test duration of 48 h might underestimate the toxicity of many substances, especially of NMs.     

Diet and environment 1.2 million years ago revealed through analysis of dental calculus from Europe’s oldest hominin at Sima del Elefante,Spain

Sima del Elefante, Atapuerca, Spain contains one of the earliest hominin fragments yet known in Europe, dating to 1.2 Ma. Dental calculus from a hominin molar was removed, degraded and analysed to recover entrapped remains. Evidence for plant use at this time is very limited and this study has revealed the earliest direct evidence for foods consumed in the genus Homo. This comprises starchy carbohydrates from two plants, including a species of grass from the Triticeae or Bromideae tribe, meat and plant fibres. All food was eaten raw, and there is no evidence for processing of the starch granules which are intact and undamaged. Additional biographical detail includes fragments of non-edible wood found adjacent to an interproximal groove suggesting oral hygiene activities, while plant fibres may be linked to raw material processing. Environmental evidence comprises spores, insect fragments and conifer pollen grains which are consistent with a forested environment.     

Effects of silver adsorbed on fumed silica, silver phosphate glass, bentonite organomodified with silver and titanium dioxide in aquatic indicator organisms

In order to reduce the level of transmission of diseases caused by bacteria and fungi, the development of antimicrobial additives for use in personal care, hygiene products, clothing and others has increased. Many of these additives are based on metals such as silver and titanium. The disposal of these products in the environment has raised concerns pertaining to their potential harmfulness for beneficial organisms. The objective of this study was to evaluate the influence of the shape, surface chemistry, size and carrier of three additives containing silver and one with titanium dioxide (TiO₂) on microcrustacean survival. Daphnia magna was used as a bioindicator for acute exposure test in suspensions from 0.0001 to 10,000 ppm. Ceriodaphnia dubia was used for chronic test in TiO₂ suspensions from 0.001 to 100 ppm. D. magna populations presented high susceptibility to all silver based additives, with 100% mortality after 24 hr of exposure. A different result was found in the acute experiments containing TiO₂ suspensions, with mortality rates only after 48 hr of incubation. Even on acute and chronic tests, TiO₂ did not reach a linear concentration-response versus mortality, with 1 ppm being more toxic than 10,000 ppm on acute test and 0.001 more toxic than 0.01 ppm on chronic assay. Silver based material toxicity was attributed to silver itself, and had no relation to either form (nano or ion) or carrier (silica, phosphate glass or bentonite). TiO₂ demonstrated to have a low acute toxicity against D. magna.