Suitability of passive sampling for the monitoring of pharmaceuticals in Finnish surface waters

The occurrence of five pharmaceuticals, consisting of four anti-inflammatory and one antiepileptic drug, was studied by passive sampling and grab sampling in northern Lake Päijänne and River Vantaa. The passive sampling was performed by using Chemcatcher® sampler with a SDB-RPS Empore disk as a receiving phase. In Lake Päijänne, the sampling was conducted during summer 2013 at four locations near the discharge point of a wastewater treatment plant and in the years 2013 and 2015 at four locations along River Vantaa. The samples were analyzed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) in the multiple reaction monitoring mode. The concentrations of carbamazepine, diclofenac, ibuprofen, ketoprofen, and naproxen in Lake Päijänne determined by passive sampling ranged between 1.4–2.9 ng L^?1, 15–35 ng L^?1, 13–31 ng L^?1, 16–27 ng L^?1, and 3.3–32 ng L^?1, respectively. Similarly, the results in River Vantaa ranged between 1.2–40 ng L^?1, 15–65 ng L^?1, 13–33 ng L^?1, 16–31 ng L^?1, and 3.3–6.4 ng L^?1. The results suggest that the Chemcatcher passive samplers are suitable for detecting pharmaceuticals in lake and river waters.     

Simultaneous removal of potent cyanotoxins from water using magnetophoretic nanoparticle of polypyrrole: adsorption kinetic and isotherm study

Cyanotoxins, microcystins and cylindrospermopsin, are potent toxins produced by cyanobacteria in potable water supplies. This study investigated the removal of cyanotoxins from aqueous media by magnetophoretic nanoparticle of polypyrrole adsorbent. The adsorption process was pH dependent with maximum adsorption occurring at pH 7 for microcystin-LA, LR, and YR and at pH 9 for microcystin-RR and cylindrospermopsin (CYN). Kinetic studies and adsorption isotherms reflected better fit for pseudo-second-order rate and Langmuir isotherm model, respectively. Thermodynamic calculations showed that the cyanotoxin adsorption process is endothermic and spontaneous in nature. The regenerated adsorbent can be successfully reused without appreciable loss of its original capacity.     

Release of PCBs from Silvretta glacier (Switzerland) investigated in lake sediments and meltwater

This study is part of our investigations about the release of persistent organic pollutants from melting Alpine glaciers and the relevance of the glaciers as secondary sources of legacy pollutants. Here, we studied the melt-related release of polychlorinated biphenyls (PCBs) in proglacial lakes and glacier streams of the catchment of the Silvretta glacier, located in the Swiss Alps. To explore a spatial and temporal distribution of chemicals in glacier melt, we combined two approaches: (1) analysing a sediment record as an archive of past remobilization and (2) passive water sampling to capture the current release of PCBs during melt period. In addition, we determined PCBs in a non-glacier-fed stream as a reference for the background pollutant level in the area. The PCBs in the sediment core from the Silvretta lake generally complied with trends of PCB emissions into the environment. Elevated concentrations during the most recent ten years, comparable in level with times of the highest atmospheric input, were attributed to accelerated melting of the glacier. This interpretation is supported by the detected PCB fractionation pattern towards heavier, less volatile congeners, and by increased activity concentrations of the radioactive tracer ¹³⁷Cs in this part of the sediment core. In contrast, PCB concentrations were not elevated in the stream water, since no significant difference between pollutant concentrations in the glacier-fed and the non-glacier-fed streams was detected. In stream water, no current decrease of the PCBs with distance from the glacier was observed. Thus, according to our data, an influence of PCBs release due to accelerated glacier melt was only detected in the proglacial lake, but not in the other compartments of the Silvretta catchment.     

Analysis of waste management issues arising from a field study evaluating decontamination of a biological agent from a building

The Bio-response Operational Testing and Evaluation (BOTE) Project was a cross-government effort designed to operationally test and evaluate a response to a biological incident (release of Bacillus anthracis [Ba] spores, the causative agent for anthrax) from initial public health and law enforcement response through environmental remediation. The BOTE Project was designed to address site remediation after the release of a Ba simulant, Bacillus atrophaeus spp. globigii (Bg), within a facility, drawing upon recent advances in the biological sampling and decontamination areas. A key component of response to a biological contamination incident is the proper management of wastes and residues, which is woven throughout all response activities. Waste is generated throughout the response and includes items like sampling media packaging materials, discarded personal protective equipment, items removed from the facility either prior to or following decontamination, aqueous waste streams, and materials generated through the application of decontamination technologies. The amount of residual contaminating agent will impact the available disposal pathways and waste management costs. Waste management is an integral part of the decontamination process and should be included through “Pre-Incident” response planning. Overall, the pH-adjusted bleach decontamination process generated the most waste from the decontamination efforts, and fumigation with chlorine dioxide generated the least waste. A majority of the solid waste generated during pH-adjusted bleach decontamination was the nonporous surfaces that were removed, bagged, decontaminated ex situ, and treated as waste. The waste during the two fumigation rounds of the BOTE Project was associated mainly with sampling activities. Waste management activities may represent a significant contribution to the overall cost of the response/recovery operation. This paper addresses the waste management activities for the BOTE field test.Implications: Management of waste is a critical element of activities dealing with remediation of buildings and outdoor areas following a biological contamination incident. Waste management must be integrated into the overall remediation process, along with sampling, decontamination, resource management, and other important response elements, rather than being a stand-alone activity. The results presented in this paper will provide decision makers and emergency planners at the federal/state/tribal/local level information that can be used to integrate waste management into an overall systems approach to planning and response activities.     

Characteristics of stone moroko population dynamics at different stages of naturalization in lake- and steam-type Dnieper reservoirs

The probable source of stone moroko, Pseudorasbora parva (Temminck & Schlegel, 1846), populations in lake- and stream-type Dnieper reservoirs was revealed. The dynamics and specific growth rates of these populations over 20 years were analyzed. The dynamic phase portrait method was used to determine the timing of stages in the process of invader naturalization and the periods when its populations were in equilibrium. The potential growth rates of P. parva populations in the Kremenchug and Dneprodzerzhinsk reservoirs were estimated.     

Fluctuating asymmetry of rodent cranial structures in an industrial pollution gradient

Fluctuating asymmetry (FA) of the mandible shape has been analyzed in bank voles from the zones affected by pollution from three copper smelters in the Urals. It has been shown that there is the necessity for a detailed analysis of the material, since the level of FA may depend on population parameters. Regardless of the pollution level, FA of the mandible region including the lower part of the mandibular body, ramus and processes is higher than in the diastema region. A gradient effect of toxic exposure on FA has been revealed: an increase in its level under increasing technogenic impact is clearly manifested along local pollution gradients.     

Long-term dynamics and correlations of ecophysiological parameters in murine rodent communities

The dynamics and correlations of ecophysiological parameters have been studied in two spatially separated multispecies communities of murine rodents and ixodid tick larvae and nymphs that parasitize them. It has been shown that all the processes under consideration have nonstationary, oscillatory dynamics. The long-term dynamics of connectivity of ecophysiological characteristics within communities and their synchronization by weather–climatic factors are, by nature, wavelike processes of transitions between the states with stronger and weaker linkage between parameters, which, along with nonstationarity, can contribute to the maintenance of stability and integrity of communities.     

The ecology of the red fox (<Emphasis Type="Italic">Vulpes vulpes</Emphasis> L.) in the middle Lena River basin

The population of foxes in the central regions of Yakutia has grown by a factor of four to five during the period from 2000 to 2011–2012, following an increase in the abundance of voles from the genus Microtus. A total of 130 carcasses of foxes taken in 2007–2012 have been examined. Age- and sex-related variation in morphological features has been described. The demographic structure of the population has been studied by estimating animal age from annual layers in the recording structures. Changes in female fertility and involvement in reproduction depending on age and feeding conditions have been analyzed. Changes in the composition of fox diet caused by long-term population depression in the mountain hare and their effect on the dynamics of fox abundance have been revealed. Age- and sex-related characteristics of the condition factor in foxes and sex-related differences in their dietary preferences have been demonstrated.     

Characteristics of soil nematode communities under conditions of woody plant introduction

Nematode communities in the rooted soil layer under the crowns of introduced tree species on Valaam Island (Republic of Karelia) have been studied by conventional nematological methods to evaluate their taxonomic diversity, population density, and eco-trophic structure. On the whole, 49 nematode genera have been recorded, with their total abundance varying from 1209 to 2548 ind./100 g soil. The abundance and proportion of plant parasites in the soil nematode assemblage have proved to be higher under introduced trees, compared to natural forest biocenoses.