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71.
Leite Marilaine Cristina Marques de Araujo Maycon Anderson da Silva de Paiva Wesller Camargos Liliane Santos Martins Aline Redondo 《Environmental science and pollution research international》2022,29(5):6900-6910
Environmental Science and Pollution Research - The indiscriminate use of fertilizers and chemical pesticides can lead to boron contamination of the soil. Decontamination in general is expensive and... 相似文献
72.
Mateus Tonelli Maria Fernanda Gomes Villalba Peñaflor Luís Garrigós Leite Weliton Dias Silva Fernanda Martins José Maurício Simões Bento 《Chemoecology》2016,26(2):59-66
Few systems have been described in which herbivore-induced root volatiles mediate attraction of entomopathogenic nematodes (EPNs), and they only concern root damage inflicted by chewing insects. EPNs, especially Heterorhabditis indica and Steinernema carpocapsae, are potential biological control agents of sugarcane spittlebug (Mahanarva fimbriolata) populations. Here, we investigated the response of these two species of EPNs to sugarcane root volatiles damaged by M. fimbriolata nymphs in a belowground six-arm olfactometer. We also examined changes on root volatile profile in response to herbivory of sugarcane spittlebug nymphs. Results showed that both EPN species did not discriminate between odors of undamaged sugarcane and moistened sand (blank). However, when EPNs were exposed to odors of spittlebug-damaged and undamaged sugarcane roots, both species significantly preferred odors of spittlebug-damaged roots. Headspace collection followed by GC–MS analyses showed no qualitative difference (total of 11 compounds) between volatile profiles of spittlebug-damaged and undamaged sugarcane roots. In contrast to the previous studies involving feeding by root chewing insects, our root volatile analysis did not reveal any up-regulation resulting from sugarcane spittlebug damage, but the down-regulation of the terpenes dihydromyrcenol and β-isomethyl ionone when compared with the profile of undamaged sugarcane roots. Here, we propose alternative explanations for the EPN attraction to spittlebug-damaged roots as it is unlikely that reduced concentrations of the volatiles play a role in this interaction. Further studies are necessary to determine the key compounds of the root volatile emission to enhance biological control efficacy with EPNs against M. fimbriolata in sugarcane. 相似文献
73.
Olukemi A. Adeniran Martins E. Obuotor Femi K. Agboola Akindele J. Famurewa Stephen Osasan 《毒物与环境化学》2013,95(7):1361-1374
In this study, a mannose-specific, homodimeric lectin from the seeds of Treculia africana was purified, characterized and its adverse effects were investigated in mice. The purification protocol involved anionic exchange chromatography on DEAE-Cellulose followed by gel filtration on Sephadex G-100. The hemagglutinating activity of lectin towards human erythrocytes was sensitive to inhibition by D-mannose. Treatment of the protein with EDTA exerted no inhibitory effect; however, analysis of metal content by atomic absorption spectroscopy revealed the presence of Cu2+, Fe3+, and Mg2+. The results obtained showed that the lectin possesses maximum hemagglutinating activity towards human erythrocytes activity over the pH range 3–7.2 and is relatively thermostable up to 50°C. Periodic acid Schiff's (PAS) reagent staining showed that the protein was non-glycosylated while its amino acid composition analysis revealed that the protein contained 155 residues per subunit. The subunit had a minimal molecular weight of 22,139 Daltons, while the native molecular weight was estimated to be 41,000 Daltons. The lectin was found to be moderately toxic to mice with an LD50 of 47.21 µg g?1 body weight while, histopathological analysis showed no treatment related effects in any of the organs examined. 相似文献
74.
Patinha C Reis AP Dias C Cachada A Adão R Martins H Ferreira da Silva E Sousa AJ 《Environmental geochemistry and health》2012,34(2):213-227
Previous environmental biomonitoring studies indicated higher environmental lead (Pb) pollution levels at the districts of
Aveiro and Leiria (Portugal). In evaluating the risk for human health, which is associated with contaminated soils after oral
uptake, total soil concentrations have generally been held against criteria established from toxicological studies based upon
the assumption that the uptake of the contaminant is similar in the toxicological studies and from the soils assessed. This
assumption is not always valid, as most toxicological studies are carried out with soluble forms of the contaminants, whereas
many soil contaminants are or become embedded in the soil matrix and thus exhibit limited availability. This study intends
to estimate the soluble fraction of Pb in the soils from central Portugal, and to assess the bioaccessibility of Pb and, hence,
infer exposure and risk for human health. Yet, as the physical–chemical properties of the soil exert some control over the
solubility of Pb in the surface environment, the relation between such soil properties and the estimated soluble and/or bioaccessible
fractions of Pb is also investigated. Other objective, with a more practical nature, was to give some contribution to find
a suitable in vitro mimetic of the gastrointestinal tract environment. The results indicate relatively low total metal concentrations
in the soils, even if differences between regions were observed. The Aveiro district has the higher total Pb concentration
and the metal is in more soluble forms, that is, geoavailable. Soils with higher concentrations of soluble Pb show higher
estimates of bioaccessible Pb. Soil pH seems to influence human bioaccessibility of Pb. 相似文献
75.
Ana P. L. Batista Hudson Wallace Pereira Carvalho Gustavo H. P. Luz Paulo F. Q. Martins Maraísa Gonçalves Luiz C. A. Oliveira 《Environmental Chemistry Letters》2010,8(1):63-67
A photocatalyst based on CuO/SiO2 was prepared, and evaluated for the degradation of methylene blue in aqueous medium. The photocatalyst was obtained by calcination
method of copper salt, in the presence of silica. The characterization by XRD, FTIR, and TPR techniques confirmed the formation
of CuO as active phase. SEM studies showed CuO deposited on the surface of SiO2. By ESI-MS, it was demonstrated that the degradation of methylene blue occurs through successive hydroxylations. Photodegradation
assays showed that CuO/SiO2 was efficient for degradation, and that the material worked better in the presence of UV light. 相似文献
76.
Sergio Machado Corrêa Graciela Arbilla Eduardo Monteiro Martins Simone Lorena Quitério Claudinei de Souza Guimarães Luciana Vanni Gatti 《Atmospheric environment (Oxford, England : 1994)》2010,44(19):2302-2308
The fuel matrix used in Brazil is unique around the world. The intensive use of hydrated ethanol, gasohol (gasoline with 25% v/v of ethanol), compressed natural gas (CNG), and biodiesel leads to a peculiar composition of the urban atmosphere. From 1998 to 2002 an increase in formaldehyde levels was observed and since then, a reduction. This work presents a monitoring campaign that was executed from March 2004 to February 2009 by sampling at early morning on every sunny Wednesday for a total of 183 samples. The results indicate a strong reduction in formaldehyde levels from 2004 (average of 135.8 μg m?3 with SD 28.4 μg m?3) to 2009 (average of 49.3 μg m?3 with SD 27.4 μg m?3). The levels of acetaldehyde showed a slight reduction from 2004 (average of 34.9 μg m?3 with SD 8.0 μg m?3) to 2009 (average of 26.8 μg m?3 with SD 11.5 μg m?3). Comparing the results with the concurrent evolution of the fleet and of fuel composition indicates that the observed formaldehyde levels could be associated with the increase in ethanol use and in CNG use by engines with improved technology over the first converted CNG engines. Modelling studies using the OZIPR trajectory model and the SAPRC chemical mechanism indicate that formaldehyde is the main ozone precursor in Rio de Janeiro and acetaldehyde is the forth one. 相似文献
77.
Ana Isabel Miranda Vera Martins Pedro Cascão Jorge Humberto Amorim Joana Valente Richard Tavares Carlos Borrego Oxana Tchepel António Jorge Ferreira Carlos Robalo Cordeiro Domingos Xavier Viegas Luís Mário Ribeiro Luís Paulo Pita 《Environment international》2010,36(7):736-745
Forest fires represent a serious threat to public security in Europe due to the large burned area. Moreover, smoke pollution due to forest fire events is an important public health issue for the communities directly affected, and particularly for the personnel involved in firefighting operations. Aiming to contribute to the scientific knowledge concerning firefighters exposure to forest fires smoke, data of individual exposure to carbon monoxide, nitrogen dioxide, volatile organic compounds, and particulate matter were obtained during experimental field fires for a group of 10 firefighters equipped with portable “in continuum” measuring devices. Measured values are very high exceeding the Occupational Exposure Standard limits, in particular for peak limit thresholds. These are the first measurements and analysis of firefighter's individual exposure to toxic gases and particles in fire smoke experiments in Europe. However, they already indicate that urgent measures to avoid these levels of exposure are needed. 相似文献
78.
Ângelo Barroso Cristina Chaves Francisco Vitorino Martins Manuel Castelo Branco 《Environment, Development and Sustainability》2016,18(5):1399-1414
The main purpose of this paper is to discuss whether it is possible to achieve human development without or with less economic growth. For this to happen, it is important that developed countries can maintain high levels of human development while reducing the scale of production and consumption so that developing countries can achieve greater economic growth. Using panel data from 118 countries aggregated in ten blocks of countries, we assess the influence of “growth” on “development”, as proxied by a transformed variable “Social Human Development Index” (SHDI), controlling for the influence of geo-economic factors. In particular, we analyse whether developed countries present a weaker statistical relation between GDP and the social dimension of HDI than their less developed counterparts. Results reveal that the GDP elasticity of SHDI is higher in blocks of countries where the concentration of developing countries occurs than in blocks dominated by the presence of developed countries. Thus, it is possible to envisage that a slowdown in economic activity in developed countries may occur without great sacrifice of human development, at least when it is measured by health and education components. We interpret the findings as meaning that at an aggregate level there are conditions for development to occur without or with less growth. 相似文献
79.
Alexandre Carneiro Silvino Danielle Bonilha de Abreu Talina Martins Aline da Costa Rodrigues Marcos Lopes Dias 《Journal of Polymers and the Environment》2013,21(4):1002-1008
Solid state polymerizations (SSP) and the kinetic behavior in melt state of l-lactide polymerizations employing magnesium stearate as catalyst were investigated. The solid state polymerizations were carried out in two steps where pre-polymers were first prepared in melt polymerizations at 180 °C and the subsequent post-polymerizations were performed around the Tc of polylactide (PLA). In order to find the initial SSP conditions, kinetic profiles of melt polymerizations of l-lactide with magnesium stearate were determined. According to the kinetics data the melt polymerizations were found to be first order with respect to lactide as evident from a linear relationship of logarithmic variations of l-lactide concentration versus time using catalyst/monomer ratios of 1:500 and 1:5,000. When the catalyst content is increased to 1:100 the relationship loses its linearity due to fast propagation in the early stages of the reaction. From the GPC data it can be noted that the molecular weight of PLA can be increased by 5–17 times under the conditions established for our SSP experiments. A comparison between the two step solid state polymerizations and already reported melt polymerizations using the same catalyst showed that SSP furnished polymers with much lower amount of polymer degradation. 相似文献
80.
Respiration induced by substrate and bacteria diversity after application of diuron,hexazinone, and sulfometuron-methyl alone and in mixture 总被引:1,自引:0,他引:1
Fabrícia Cristina Dos Reis Valdemar Luiz Tornisielo Bianca A. B. Martins Adijailton José de Souza Pedro Avelino Maia De Andrade Fernando Dini Andreote 《Journal of environmental science and health. Part. B》2013,48(7):560-568
AbstractAfter application, herbicides often reach the soil and affect non-target soil microorganisms, decreasing their population, diversity or affecting metabolic activity. Therefore, laboratory studies were performed to evaluate the effects of diuron, hexazinone and sulfometuron-methyl alone and mixed upon carbon transformation by soil microorganisms in clayey and sandy soils and the effect on bacterial diversity and structure. Control treatment without herbicide application was also performed. Sub-samples from the control and herbicide treatments (10?g – in triplicate) were collected before herbicide application and 7, 14, 28 and 42?days after treatment (DAT), then 1?mL of 14C-glucose solution was applied. The released 14CO2 was trapped in 2?M NaOH solution and the radioactivity was analyzed by liquid scintillation counting (LSC), 12?h after glucose application. The effect of herbicides on bacterial diversity was evaluated by T-RFLP. The experiment was conducted in a complete randomized design. Hexazinone did not affect 14CO2 evolution. Diuron showed a greater 14CO2 evolution in sandy and clayey soil, while sulfometuron-methyl led to an increase in sandy soil, at 42 DAT. A greater evolution of carbon was observed in the treatment with herbicide mixture in sandy soil, compared with the same treatment in clayey soil or control. However, the herbicide mixture application did not affect the soil biological activity measured by the respiration rate induced by substrate. On the other hand, the herbicide mixtures affected the bacterial diversity in both soils, being the strongest effect to diuron and sulfometuron-methyl in clayey soil and hexazinone in sandy soil. 相似文献