Evaluation of method of preparation of passive diffusion tubes for measurement of ambient nitrogen dioxide

This study was carried out in response to suggestions that the measurement of NO(2) by Palmes-type passive diffusion tubes (PDT) is affected by the method of preparation of the triethanolamine (TEA) absorbent coating on the grids. The following combinations of factors were investigated: TEA solvent (acetone or water), volume composition of TEA in solvent (50% or 20%), and grid coating method (dipping in solution prior to assembly or pipetting solution on after assembly). Duplicate PDTs prepared by each of the 8 methods were exposed in parallel, in urban air, for a total of 80 separate 1 week exposures. NO(2) concentrations derived from PDTs prepared by pipetting methods were significantly less precise than concentrations from dipping methods, with mean RSDs for duplicate measurements of 13.8% and 8.5%, respectively (n= 316 each category). Pipetting methods using solutions of 50% TEA composition were particularly imprecise (mean RSD 17.2%). Data from PDTs prepared by pipetting methods were systematically more poorly correlated with each other and with data from co-located chemiluminescence analysers, than corresponding data from PDTs prepared by dipping methods, indicating that more consistent accuracy was also obtained by the latter PDTs. The statistical evidence suggested that PDTs prepared by pipetting 50% TEA in water generally gave lower NO(2) concentrations. Although this is in agreement with a previous study, it is also possible that such an observation here may be a statistical artefact given the demonstrably poorer precision of this method. The general tendency of PDTs to show positive bias in NO(2) measurement in urban air in 1 week exposures was again evident in this study (mean biases at roadside and urban centre locations of +35% (n= 475) and +18% (n= 112), respectively) consistent with augmentation of within-tube NO(2) flux by chemical reaction between co-diffusing NO and O(3). Overall, it is recommended that the pipetting method of PDT grid preparation is avoided, or at least investigated further, because of the apparent degradation in precision and accuracy of NO(2) measurement. Potential reasons for the effect are discussed.     

Selenium in the Blackfoot, Salt, and Bear River Watersheds

Nine stream sites in the Blackfoot River, Salt River, and Bear River watersheds in southeast Idaho, USA were sampled in May 2001 for water, surficial sediment, aquatic plants, aquatic invertebrates, and fish. Selenium was measured in these aquatic ecosystem components, and a hazard assessment was performed on the data. Water quality characteristics such as pH, hardness, and specific conductance were relatively uniform among the nine sites. Of the aquatic components assessed, water was the least contaminated with selenium because measured concentrations were below the national water quality criterion of 5 g/L at eight of the nine sites. In contrast, selenium was elevated in sediment, aquatic plants, aquatic invertebrates, and fish from several sites, suggesting deposition in sediments and food web cycling through plants and invertebrates. Selenium was elevated to concentrations of concern in fish at eight sites (> 4 g/g in whole body). A hazard assessment of selenium in the aquatic environment suggested a moderate hazard at upper Angus Creek (UAC) and Smoky Creek (SC), and high hazard at Little Blackfoot River (LiB), Blackfoot River gaging station (BGS), State Land Creek (SLC), upper (UGC) and lower Georgetown Creek (LGC), Deer Creek (DC), and Crow Creek (CC). The results of this study indicate that selenium concentrations from the phosphate mining area of southeast Idaho were sufficiently elevated in several ecosystem components to cause adverse effects to aquatic resources in southeastern Idaho.     

Natural capital in ecology and economics: an overview

The Brundtland Commission report, Our Common Future, defined sustainable development as development that meets the needs of the present without compromising the ability of futuregenerations to meet their own needs. Although the idea of sustainable development has been widely accepted, it has proveddifficult to identify and implement policies and practices thatpromote sustainable economic growth. Some economists, environmental scientists and policy analysts believe that they can transform the consensus about sustainability into manageablepractices. They propose to accomplish this feat with a set of new ideas about the relationships between the economy and theenvironment offered under the banner of 'natural capital'. An ideal account of natural capital would be one or more standard measures or models that would allow the direct comparison of environmental goods, like forests, fresh water and clean air, with economic goods, like money, capital and productivity. By bringing economic science and environmental science to an objective common ground, a natural capital model has the potentialto provide a concrete means of comparing the economic and ecological costs and benefits of particular policies and programmes. This paper offers a survey and analysis of several new contributions to the formation of the natural capital concept from economists, ecologists, policy analysts, biometricians, foresters and a philosopher. The paper concludes that existingmicroeconomic theory may be 'ungreenable', if it is not reformulated. While macroeconomic approaches to natural capitalhave been more successful, they share the limitation that ecosystems and species are valued solely in monetary terms. These problems are taken to suggest that the development of a successful natural capital model may require economic theory tobe recast to include non-monetary social preferences and values.     

Development of community of practice to support quantitative risk assessment for synthetic biology products: contaminant bioremediation and invasive carp control as cases

Synthetic biology has the potential for a broad array of applications. However, realization of this potential is challenged by the paucity of relevant data for conventional risk assessment protocols, a limitation due to to the relative nascence of the field, as well as the poorly characterized and prioritized hazard, exposure, and dose–response considerations associated with the development and use of synthetic biology-derived organisms. Where quantitative risk assessment approaches are necessarily to fulfill regulatory requirements for review of products containing genetically modified organisms, this paper reviews one potential avenue for early-stage quantitative risk assessment for biosafety considerations of synthetic biology organism deployment into the environment. Building from discussion from a March 2018 US Army Engineer Research and Development Center workshop on developing such quantitative risk assessment for synthetic biology, this paper reviews the findings and discussion of workshop participants. This paper concludes that, while synthetic biology risk assessment and governance will continue to refine and develop in the coming years, a quantitative framework that builds from existing practice is one potentially beneficial option for risk assessors that must contend with the technology’s limited hazard characterization or exposure assessment considerations in the near term.     

Assigning Degrees of Ease or Difficulty for Pet Animal Maintenance: The EMODE System Concept

Pet animal management is subject to varied husbandry practices and the resulting consequences often impact negatively on animal welfare. The perceptions held by someone who proposes to keep an animal regarding the ease or difficulty with which its biological needs can be provided for in captivity are key factors in whether that animal is acquired and how well or poorly it does. We propose a system to ‘score’ animals and assign them to categories indicating the ease or difficulty with which they can be kept as pets in accordance with welfare and public health and safety considerations. The ‘EMODE’ (‘Easy’, ‘Moderate’, ‘Difficult’, ‘Extreme’) system has two fundamental components: animal welfare—which considers the ‘five freedoms’ principles; and public health and safety—which considers management associated with risks from disease or injury to the keeper and to others. EMODE incorporates two tiers of assessment and guidance, and may offer a reasonable guide for the majority of relevant animals. EMODE Tier 1 provides a primary and general assessment of animals by class or group, and EMODE Tier 2 provides a secondary refined assessment of animals by species or breed. EMODE offers a user-friendly and versatile foundation concept for the future development of guidance for the layperson who may be considering acquiring a pet or for certain personnel when considering assigning species to restrictive lists of suitable animals, for example, ‘positive lists’ as used by governments to control animals in trade and keeping.     

Estimated benefit of automated emergency braking systems for vehicle–pedestrian crashes in the United States

Abstract

Objective: The objective of this research study is to estimate the benefit to pedestrians if all U.S. cars, light trucks, and vans were equipped with an automated braking system that had pedestrian detection capabilities.

Methods: A theoretical automatic emergency braking (AEB) model was applied to real-world vehicle–pedestrian collisions from the Pedestrian Crash Data Study (PCDS). A series of potential AEB systems were modeled across the spectrum of expected system designs. Both road surface conditions and pedestrian visibility were accounted for in the model. The impact speeds of a vehicle without AEB were compared to the estimated impact speeds of vehicles with a modeled pedestrian detecting AEB system. These impacts speeds were used in conjunction with an injury and fatality model to determine risk of Maximum Abbreviated Injury Scale of 3 or higher (MAIS 3+) injury and fatality.

Results: AEB systems with pedestrian detection capability, across the spectrum of expected design parameters, reduced fatality risk when compared to human drivers. The most beneficial system (time-to-collision [TTC]?=?1.5?s, latency = 0?s) decreased fatality risk in the target population between 84 and 87% and injury risk (MAIS score 3+) between 83 and 87%.

Conclusions: Though not all crashes could be avoided, AEB significantly mitigated risk to pedestrians. The longer the TTC of braking and the shorter the latency value, the higher benefits showed by the AEB system. All AEB models used in this study were estimated to reduce fatalities and injuries and were more effective when combined with driver braking.     

Inter-colony movements,at-sea behaviour and foraging in an immature seabird: results from GPS-PPT tracking,radio-tracking and stable isotope analysis

Seabird populations contain large numbers of immatures––in some instances comprising >50% of the fully grown adults in the population. These birds are significant components of marine food webs and may contribute to compensatory recruitment and dispersal, but remain severely understudied. Here, we use GPS-PTTs, radio-tracking and analysis of stable carbon (δ¹³C) and nitrogen (δ¹⁵N) isotopes to investigate the movements and foraging ecology of immature seabirds. Our study focussed on immature northern gannets Morus bassanus aged 2–4 attending non-breeding aggregations alongside a large breeding colony. GPS-PTT tracking of five birds revealed that immatures have the ability to disperse widely during the breeding season, with some individuals potentially prospecting at other colonies. Overall, however, immatures were faithful to the colony of capture. During returns to the focal colony, immatures acted as central place foragers, conducted looping and commuting flights, and analysis of the variance in first-passage time revealed evidence of area-restricted search (ARS) behaviour. In addition, stable carbon (δ¹³C) and nitrogen (δ¹⁵N) isotope analyses indicate that immatures were isotopically segregated from breeders. Our findings provide insights into the foraging, prospecting and dispersal behaviour of immature seabirds, which may have important implications for understanding seabird ecology and conservation.     

The validity of a low-cost simulator for the assessment of the effects of in-vehicle information systems

This study explored the validity of using a low-cost simulator for the assessment of driver distraction arising from the use of an in-vehicle information system. Eighteen participants drove on a rural road whilst carrying out distractor tasks of various levels of difficulty, in both a low-cost simulator (with gaming console steering wheel and pedals with single monitor display) and a medium-cost one (fixed-base, complete vehicle cab, wrap-around visuals). The distractor tasks were presented at identical locations in each of the drives and an identical suite of driver performance and subjective rating measures were elicited to allow a robust comparison between the two simulator environments. As expected, there was a reduction in mean speed when drivers were completing the distraction tasks and this effect was observed in both simulators. However, drivers spent more time at shorter headways in the low-cost version and demonstrated more erratic steering behaviour in the low-cost version. This could be due to a reduced peripheral view and inferior kinaesthetic feedback through the driver controls, but low-cost simulators could play a significant role in the early stages of design and evaluation of in-vehicle information systems.     

A Decade of Geomorphic and Hydraulic Response to the La Valle Dam Project,Baraboo River,Wisconsin

We investigate stream response to the La Valle Dam removal and channel reconstruction by estimating channel hydraulic parameter values and changes in sedimentation within the reservoir. The designed channel reconstruction after the dam removal included placement of a riffle structure at the former dam site. Stream surveys undertaken in 1984 by Federal Emergency Management Agency and in 2001 by Doyle et al. were supplemented with surveys in 2009 and 2011 to study the effects of the instream structure. We created a model in HEC‐RAS IV and surface maps in Surfer© using the 1984, 2009, and 2011 surveys. The HEC‐RAS IV model for 2009 channel conditions indicates that the riffle structure decreases upstream channel shear stress and velocity, causing renewed deposition of sediment within the former reservoir. We estimate by 2009, 61% of former reservoir sediments were removed during dam removal and channel reconstruction. Between 2009 and 2011 renewed sedimentation within the former reservoir represented approximately 7.85% of the original reservoir volume. The HEC‐RAS IV models show the largest impacts of the dam and riffle structure occur at flood magnitudes at or below bankfull. Thus, the riffle and the dam similarly alter channel hydraulics and sediment transport. As such, our models indicate that the La Valle Dam project was a dam replacement rather than a removal. Our results confirm that channel reconstruction method can alter channel hydraulics, geomorphology, and sediment mobility.