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Anne Mbiri Gunther Wittstock Dereje H. Taffa Erastus Gatebe Joseph Baya Michael Wark 《Environmental science and pollution research international》2018,25(35):34873-34883
Advanced oxidation processes using semiconducting photocatalysts for the degradation of organic pollutants are a promising approach for the remediation of pesticide-contaminated wastewater. High photodegradation efficiency and stability of the photocatalyst are of key importance for practical application of the semiconductor. In this study, mesoporous TiO2/ZrO2 nanopowders were synthesized via two techniques; evaporation-induced self-assembly (EISA) and sol-gel using triblock copolymers Pluronic P123 and F127. The photodegradation activities of the composites were determined by employing the herbicide chloridazon as a model compound. Due to well-developed mesoporosity, the TiO2/ZrO2 nanocomposite synthesized by EISA displays high surface area and small crystallite sizes leading to higher photocatalytic activity than pristine TiO2 prepared under similar condition and commercial Degussa P25 nanopowder. The optimum amount of zirconium required for the highest activities was identified and found to be 0.14 and 0.05 mol% for the EISA and sol-gel-prepared samples, respectively. Systematic studies of the post-thermal treatment step for both samples show that Zr inhibits an anatase-to-rutile phase transition only up to 600 °C, at higher temperature phase separation occurs. Samples synthesized by EISA method showed enhanced degradation activity than sol-gel-synthesized samples. 相似文献
704.
Hanitra Randrianaivo Georges Haddad Horatiu Roman Anne Lise Annick Toutain Martine Le Merrer Claude Moraine 《黑龙江环境通报》2002,22(9):806-810
An Erratum has been published for this article in Prenatal Diagnosis 22(13) 2002, 1241. Fibrochondrogenesis is a rare and lethal osteochondrodysplasia with an autosomal recessive mode of inheritance. We report a male fetus in which the diagnosis of lethal osteochondrodysplasia was suspected on prenatal ultrasound and radiological examinations during the second trimester of pregnancy. After termination of pregnancy, fibrochondrogenesis was diagnosed by radiological examination and histological study of fetal bones. Interwoven fibrous septa and fibroblastic degeneration of chondrocytes are pathognomonic. The recurrence rate is 25% and accurate diagnosis is necessary to enable genetic counselling. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
705.
Sandra Alker Victoria Joy Peter Roberts Nathan Smith 《Journal of Environmental Planning and Management》2000,43(1):49-69
This paper discusses the need for a more robust definition of the term 'brownfield' from a multidisciplinary perspective. It examines the issues involved in constructing an agreed and accepted definition and its importance with regard to UK government policy. Current usage of the term 'brownfield' and related terminology is reviewed. The paper proposes that: a brownfield site is any land or premises which has previously been used or developed and is not currently fully in use, although it may be partially occupied or utilized. It may also be vacant, derelict or contaminated. Therefore a brownfield site is not necessarily available for immediate use without intervention. Interpretation of the terminology incorporated with the definition is presented herein. The definition is subsequently evaluated with respect to the views of different stakeholder groups involved in the redevelopment of brownfield sites. 相似文献
706.
The capping of waste management units and contaminated soils is receiving increasing attention as a low-cost method for hazardous chemical site remediation. Capping is used to prevent further groundwater pollution by existing waste management units and contaminated soils through limiting the moisture that enters the wastes. In principle, for wastes located above the water table, the construction of an impermeable cap can prevent leaching of the wastes (leachate generation) and groundwater pollution. In practice, appropriately designed and constructed RCRA caps can provide for only short-term prevention of groundwater pollution. Alternative approaches are available for capping of wastes that can be effective in preventing moisture from entering the wastes and concomitant groundwater pollution. These approaches recognize the inability of the typical RCRA cap to keep wastes dry for as long as waste constituents will be a threat and, most importantly, provide the necessary funds to effectively address all plausible worst-case scenario failures that could occur at a capped waste management unit or contaminated soil area. 相似文献
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Anne Steinemann 《Journal of the American Water Resources Association》2003,39(5):1217-1233
ABSTRACT: Drought management depends on indicators to detect drought conditions, and triggers to activate drought responses. But determining those indicators and triggers presents challenges. Indicators often lack spatial and temporal transferability, comparability among scales, and relevance to critical drought impacts. Triggers often lack statistical integrity, consistency among drought categories, and correspondence with desired management goals. This article presents an approach for developing and evaluating drought indicators and triggers, using a probabilistic framework that offers comparability, consistency, and applicability. From that, a multistate Markov model investigates the stochastic behavior of indicators and triggers, including transitioning, duration, and frequency within drought categories. This model is applied to the analysis of drought in the Apalachicola‐Chattahoochee‐Flint River Basin in the southeastern United States, using indicators of the Standardized Precipitation Index (for 3, 6, 9, and 12 months), the Palmer Drought Severity Index, and the Palmer Hydrologic Drought Index. The analysis revealed differences among the performance of indicators and their trigger thresholds, which can influence drought responses. Results contribute to improved understanding of drought phenomena, statistical methods for indicators and triggers, and insights for drought management. 相似文献
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Silvia Serrao-Neumann Ben Harman Anne Leitch Darryl Low Choy 《Journal of Environmental Planning and Management》2015,58(7):1196-1216
Public participation in decision making is a central component of the planning process; however, implementing effective engagement initiatives to resolve complex planning and policy problems, such as climate change, is challenging for planners. These challenges are particularly acute in coastal communities throughout Australia, where many settlements are at risk of future climate perturbations. Using the International Association for Public Participation framework for public participation, we analyse three local government led public participation initiatives in New South Wales, Victoria and Tasmania, Australia. Our analysis suggests there are three critical factors that can influence the level of public participation in the context of climate change adaptation: the technocratic approach to decision making; absent high order government support; and the lack of evaluation mechanisms for public participation. 相似文献