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111.
采用平行因子分析方法,结合紫外吸收光谱、三维荧光光谱以及傅里叶变换红外光谱技术,研究了沉水植物狐尾藻在低、中、高营养底泥腐解过程中胡敏酸(HA)的变化,进一步揭示了不同营养底泥对沉水植物腐解的影响机制.结果表明,底泥营养水平越高,狐尾藻腐解得越快(P<0.05),释放出更多的溶解性有机碳(DOC)、溶解性总氮(DTN)、溶解性总磷(DTP)和腐殖质;底泥营养程度与HA的疏水性、分子复杂性、分子量大小呈正相关(P<0.05);荧光鉴别出不同营养底泥HA都含有1种类蛋白质组分C2和2种类富里酸组分C1、C3,且类富里酸组分和类蛋白质组分在不同腐解条件下具有相似的组分特征;不同营养底泥不同时间提取的HA红外图谱较为相似,表明不同腐解条件不同时间提取的HA含有相似的官能团,狐尾藻腐烂高营养底泥组提取的HA含有更多的芳香性物质和有机磷.采用光谱分析法对狐尾藻腐烂分解HA成分的化学结构特征进行系统的研究,可深入了解不同营养底泥对沉水植物腐解的影响机制,为湖泊水环境生态治理和修复提供理论参考. 相似文献
112.
Jasmin Shah M. Rasul Jan Behisht Ara Farhat-un-Nisa Shehzad 《Environmental monitoring and assessment》2011,178(1-4):111-119
A method for the determination of herbicides residues, triazine (atrazine, metribuzin, ametryn, and terbutryn), in soil samples with high-performance liquid chromatography (HPLC)?CUV detection is described. The proposed method is based on microwave-assisted extraction (MAE) of soil samples for 4 min at 80% of 850-W magnetron outputs in the presence of mixture of solvents (methanol/acetonitrile/ethylacetate). Related important factors influencing the MAE efficiency, such as the solvent type and volume, irradiation energy, and time, were optimized in detail. Calibration curve ranges established using HPLC for metribuzin, atrazine, ametryn, and terbutryn are 1.0?C19.0, 0.9?C18.0, 0.6?C11.0, and 0.7?C11.0 µg mL???1, respectively. The limits of detection of metribuzin, atrazine, ametryn, and terbutryn are 0.30, 0.24, 0.16, and 0.20 µg mL???1 while limits of quantification are 1.0, 0.80, 0.50, and 0.60 µg mL???1, respectively. A Plackett?CBurman factorial design was used as a screening method in order to select the variables that influence MAE extraction. The recoveries of the method at three different spiked levels were assessed by analyzing real soil samples and were found to be in the range of 83.33 ± 0.12?C96.33 ± 0.23 with good precision (<8%). 相似文献
113.
基于向量自回归模型(VAR)的计量分析,对甘肃省旅游业发展与经济增长的关系进行了实证分析.结果显示,甘肃省旅游业发展与经济增长间存在长期均衡的协整关系;经济增长是旅游收入提高的Granger原因,而旅游业发展不是经济增长的Granger原因;甘肃省经济增长对其旅游业发展具有正向影响;同时,旅游业收入的结构冲击对经济增长波动的影响有限. 相似文献
114.
Lifei ZHANG Minghui ZHENG Bing ZHANG Wenbin LIU Lirong GAO Te BA Zhiyuan REN Guijin SU 《环境科学学报(英文版)》2008,20(12):1523-1526
Decomposition of hexachlorobenzene (HCB) was investigated over several metal oxides (i.e., MgO, CaO, BaO, La2O3, CeO2, MnO2, Fe2O3, and Co3O4) supported on Al2O3, which was achieved in closed system at a temperature of 300°C. Catalysts were prepared by incipient wetness impregnation with different metal oxides loading and impregnating solvents. The decomposition efficiency of different catalysts for this reaction depends on the nature of the metal oxide used, and Al2O3 supported La2O3 was found to be the most active one. Pentachlorobenzene (PeCB), and all tetrachlorobenzene (TeCB), trichlorobenzene (TrCB), and dichlorobenzene (DCB) isomers were detected after the decomposition reaction, indicating that the decomposition was mainly a dechlorination process. The detection of all lower chlorinated benzenes suggested the complexity of decomposition and the presence of more than one dechlorination pathway. 相似文献
115.
116.
尽管世界金融风暴放缓了世界节能减排的步伐,但节能减排仍是中央经济工作会议确定的我国2009年重点工作之一。对于新兴资源型工业城市乌海市来说,确保经济平稳快速增长的同时,又要顺利完成“十一五”节能减排目标,必须要有新的节能减排思路。 相似文献
117.
文章研究了粉煤灰在热处理过程中汞的逸出规律,通过改变焙烧温度、焙烧时间和通气流量等条件,利用安大略水法,对逸出的零价汞(Hg0)和二价汞(Hg2+)以及总汞的含量进行了测定。结果表明:在加热温度达到400℃时,飞灰中的可挥发汞已基本完全释放,逸出量大约为0.2μg/g。当加热温度升高到600~1 000℃之间时,零价汞含量明显降低,而二价汞含量明显升高,可以观察到较为明显的零价汞氧化为二价汞的现象。汞的逸出量与氧化程度主要与加热温度有关,而加热时间与通气量的影响相对较小。在1 000℃,加热时间30 min,通气量0.5 L/min的条件下,可挥发汞将完全逸出并有部分零价汞被氧化。结合上述研究结果,在对粉煤灰进行加热处理时,需要对其中汞的二次释放现象加以重视并采取相应的控制措施。 相似文献
118.
Impacts of continuously regenerating trap and particle oxidation catalyst on the NO2 and particulate matter emissions emitted from diesel engine 总被引:1,自引:1,他引:0
Zhihua Liu Yunshan Ge Jianwei Tan Chao He Asad Naeem Shah Yan Ding Linxiao Yu Wei Zhao 《环境科学学报(英文版)》2012,24(4):624-631
Two continuously regenerating diesel particulate filter (CRDPF) with different configurations and one particles oxidation catalyst (POC) were employed to perform experiments in a controlled laboratory setting to evaluate their effects on NO2, smoke and particle number emissions. The results showed that the application of the after-treatments increased the emission ratios of NO2/NOx significantly. The results of smoke emissions and particle number (PN) emissions indicated that both CRDPFs had sufficient capacity to remove more than 90% of total particulate matter (PM) and more than 97% of solid particles. However, the POC was able to remove the organic components of total PM, and only partially to remove the carbonaceous particles with size less than 30 nm. The negligible effects of POC on larger particles were observed due to its honeycomb structure leads to an inadequate residence time to oxidize the solid particles or trap them. The particles removal efficiencies of CRDPFs had high degree of correlations with the emission ratio of NO2/NOx. The PN emission results from two CRDPFs indicated that more NO2 generating in diesel oxidation catalyst section could obtain the higher removal efficiency of solid particles. However this also increased the risk of NO2 exposure in atmosphere. 相似文献
119.
Irfan Muhammad Dawar Khadim Fahad Shah Mehmood Imran Alamri Saud Siddiqui Manzer H. Saud Shah Khattak Jabar Zaman Khan Ali Shamsher Hassan Shah Nawaz Taufiq Hammad Hafiz Mohkum Banout Jan Nasim Wajid 《Environmental science and pollution research international》2022,29(25):37676-37684
Environmental Science and Pollution Research - Biochar remediation efficiency could be enhanced through numerous treatments such as acids treatment. Still, there has little work done on... 相似文献
120.
Song Junxiu Geng Linling Fahad Shah 《Environmental science and pollution research international》2022,29(35):52984-52994
Environmental Science and Pollution Research - Poverty is a significant global ongoing issue that influences a substantial amount of people despite all efforts to eliminate or lessen it. Although... 相似文献