Various manganese oxides (MnOx) prepared via citric acid solution combustion synthesis were applied for catalytic oxidation of benzene. The results showed the ratios of citric acid/manganese nitrate in synthesizing process positively affected the physicochemical properties of MnOx, e.g., BET (Brunauer-Emmett-Teller) surface area, porous structure, reducibility and so on, which were in close relationship with their catalytic performance. Of all the catalysts, the sample prepared at a citric acid/manganese nitrate ratio of 2:1 (C2M1) displayed the best catalytic activity with T90 (the temperature when 90% of benzene was catalytically oxidized) of 212℃. Further investigation showed that C2M1 was Mn2O3 with abundant nano-pores, the largest surface area and the proper ratio of surface Mn4+/Mn3+, resulting in preferable low-temperature reducibility and abundant surface active adsorbed oxygen species. The analysis results of the in-situ Fourier transform infrared spectroscopy (in-situ FTIR) revealed that the benzene was successively oxidized to phenolate, o-benzoquinone, small molecules (such as maleates, acetates, and vinyl), and finally transformed to CO2 and H2O. 相似文献
SUMMARY Arid and semi-arid environments undergo periodic seasonal agricultural droughts of varying extents and duration, erratic and ineffective rainfall of high intensity and short duration, with high surface runoff. High efficiency water-harvesting agriculture has been routinely used in the Loess Plateau agricultural production of China over the past 10 years. Localized habitat effect and regional water resource enrichment are the theoretical basis of high efficient water-harvesting agriculture. Features of this agricultural system are described, including: water harvesting of surface runoff from roads and collection in concrete yards on plastic sheets; water storage cellar tanks for harvesting runoff to provide life-saving/critical irrigation, with devices for water lifting and conveying such as hand pumps and pipelines; feasible methods of water use for limited supplies such as drip, hole, subsoil, and super-sheet irrigation; agronomic measures of high water use efficiency; and field micro-catchment for water harvesting and conservation to increase fallow efficiency in rainy seasons. Using the stored runoff water to irrigate the mulched winter wheat and spring corn, as well as vegetables and fruit trees, significant yield increasing and water use efficiency improvements have been achieved. Plastic mulching for increasing fallow efficiency in rainy seasons and improving yield of the next winter wheat crop have been developed and demonstrated. These techniques have provided obvious benefits in terms of soil and water conservation on slope farmland in the hill regions and remarkable effects of storing water and reducing drought in the dryland farming regions have been obtained. 相似文献
Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of Fe3+ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of Fe3+ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA.
