从生态经济学观点论开发皖中农业自然资源的某些战略性问题

生态学是研究自然界水、土、光、气、热等无生命物质之间,动物、植物、微生物等生物之间以及非生物与生物之间的相互联系、相互依赖、相互制约的一门科学。它是生态经济学的基础。单有生态学观点还不能直接为国民经济服务,还必须与经济学相结合。要研究生态规律与经济规律的关系、生态效益与经济效益的关系。生态效益和经济效益的实现,还必须有相应的经济政策的保证,才能达到研究生态经济学的目的。作者近年来在工作中不断学习,不断体会,希望促进这门综合性学科形成一门独立的学科。     

夏季城市大气O3浓度影响因素及其相关关系

利用2003年夏季济南市区近地面大气O₃、相关前体物和气象因素等观测数据,研究了O₃浓度的分布特征及时间变化规律,分析了7月份O₃与NO、NO₂和CO等前体物及太阳辐射和气温气象条件的相关性.结果表明,济南市区夏季O₃污染比较严重,观测期间各污染物O₃、NO、NO₂、NO_x和CO浓度都相对较高,昼间O₃与各前体物的浓度呈较好的负相关关系,与太阳辐射具有非常明显的相关性,而与气温的相关性不明显.根据以上分析结果,利用回归分析方法,建立了昼间O₃浓度与前体物、气象因子之间的相关模式,结果表明O₃浓度的计算值与观测值符合性较好.     

不同温度下约束钢梁的落锤冲击响应分析

研究不同温度和冲击荷载作用下约束钢梁的动力响应问题。利用通用非线性有限元分析程序ANSYS/LS-DYNA,分别模拟了两端固支、一端固支一端轴向弹簧约束的钢梁在不同温度下受到落锤冲击时的动力响应。在温度荷载和冲击荷载联合作用下,分析了位移响应、撞击力时程曲线及冲量等的温度效应。通过撞击力时程曲线分析得出最大撞击力随温度的变化趋势与欧洲规范EC3给出的不同温度下的钢材的屈服强度折减系数的变化趋势相似,钢梁跨中的横向位移随着温度的升高而增加。还分析了高温和冲击荷载联合作用下落锤的撞击速度、不同的质量—速度组合、横向加劲肋对钢梁的变形的影响。     

空气中异氰酸甲酯的气相色谱测定

用无水乙醇作吸收液,使异氰酸甲酯转化为取代氨基甲酸酯,用氮磷检测器（ＮＰＤ）检测,可消除其他组分的干扰,方法的检测限可达μｇ／Ｌ水平。该方法比目前使用的分光光度法快速、简便、准确。     

Promotion effect of graphene on phytoremediation of Cd-contaminated soil

Echinacea purpurea (L.) Moench was selected as a remediation plant in this study, and different concentrations of graphene oxide (GO) were added to Cd-contaminated soil. Through pot experiments, the effect of E. purpurea on Cd-contaminated soil was determined at 60 days, 120 days, and 150 days. A preliminary study on the remediation mechanism of GO was explored through changes in the forms of Cd in the rhizosphere soil, soil pH, and soil functional groups. Results showed that the optimal concentration of GO was 0.4 g/kg, and under the condition, the accumulation of Cd in the roots of E. purpurea was as high as 113.69 ± 23.86 mg/kg, and the maximum EF reached 5.87 ± 1.34. Compared with those of the control group, accumulated Cd concentration and EF in the roots increased by 60.34% and 2.32, respectively. Correlation analysis showed that the absorption and accumulation of Cd was negatively correlated with the exchangeable Cd content at 120 days, and the exchangeable Cd was negatively correlated with the relative content of functional groups in the soil with 0.4 g/kg GO (E2). The artificial application of GO to the soil can be used as an effective way to improve the effect of E. purpurea in the remediation of Cd soil pollution, and it has great application potential in the stabilization of plants and vegetations and restoration of high-concentration Cd-contaminated soil.

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Understanding the effect of calcium containing compounds on ash deposition during boiler operation: experiment study and dynamics calculation

Environmental Science and Pollution Research - During the operation of the boiler, the ash deposition phenomenon in the furnace will cause abnormal operation of the boiler system. This will lead to...     

松香基三烯丙酯交联聚合树脂的合成及其对水中Pb（II）、Cd（II）和Cu（II）的吸附性能与机制

以自制的松香基三烯丙酯（triallyl maleopimarate， TAMP）为交联剂，通过悬浮聚合法合成了一种松香基三烯丙酯交联聚合树脂（triallyl maleopimarate-acrylic copolymer， TAMPA），采用红外光谱（FTIR）、扫描电镜（SEM）、N₂吸附脱附曲线和热重（TG）分析等方法对其物理化学结构及热稳定性等进行表征，采用批量吸附实验探讨了TAMPA投加量、溶液pH、温度、接触时间和离子强度等因素对TAMP树脂对Pb（II）、Cd（II）和Cu（II）重金属离子吸附性能的影响.结果表明，当pH值为2.0~5.0，TAMPA树脂对Pb（II）、Cu（II）和Cd（II）吸附量呈先增大后平缓的趋势，pH=5.0为最大值.随着离子溶液的增加对TAMP树脂去除重金属离子有抑制作用；吸附动力学符合准二级模型；Freundlich等温吸附模型可以较好地描述TAMPA对3种重金属的吸附；吸附热力学结果表明其能自发对相关金属离子进行吸附.以EDTA为洗脱剂，重复再生3次后TAMPA仍有可观的吸附性能.结合XPS和量子化学计算模拟结果，提出了TAMPA对Pb（II）、Cd（II）和Cu（II）的吸附作用机制，主要为重金属离子与材料基体中的C?O氧配位螯合作用.     

Clean energy investment and financial development as determinants of environment and sustainable economic growth: evidence from China

Environmental Science and Pollution Research - Environmental sustainability has become one of the most common phrases in discussions about climate change. This study examines the impact of clean...     

Combined effects of air pollution in adulthood and famine exposure in early life on type 2 diabetes

Environmental Science and Pollution Research - Famine exposure or air pollution is linked to type 2 diabetes mellitus (T2DM). However, their combined effects on T2DM remain largely unknown. A total...