Flocculants—an Ecofriendly Approach

Although water-soluble synthetic polymers find wide applications as flocculants, the potential problem associated with their use is lack of biodegradability and high cost. Polysaccharides owing to their distinctive features like ability to undergo different chemical reactions, biodegradability and sustainability inspire hope to obtain effective, economical viable and safe substitute of the synthetic flocculants. In this regard, chemical modification of Cassia tora and guar gum was carried out through different substitution and grafting reactions. The modified products were tested against kaolin under laboratory conditions vis-a-vis polyacrylamide based synthetic flocculant.     

Responses of two cultivars of Trifolium repens L. to ethylene diurea in relation to ambient ozone

Three ethylene diurea(EDU) concentrations(0,150 and 300 mg/L) were used to evaluate the negative impact of ozone(O3) on two cultivars of Trifolium repens L.cv.Vardan and Bundel grown under natural field conditions in a suburban area of Varanasi,India.Mean O3 concentrations varied from 30.3 to 46.6 μg/L during the experimental period.Higher photosynthetic pigments and ascorbic acid concentrations were noticed in both EDU-treated cultivars over non-EDU-treated ones,but a reverse trend was found for lipid peroxidation.Growth parameters and biomass also showed increments under EDU treatment of both cultivars.The ratio of variable fluorescence to maximum fluorescence increased significantly in Vardan but not in Bundel upon EDU treatment.Results revealed that EDU concentration of 300 mg/L was more effective to combat the oxidative stress as well as protecting plants from O3 injury symptoms.The test cultivar Vardan is relatively sensitive to O3,thereby can be used as a bioindicator of O3 pollution in areas having higher O3 concentrations.Results also indicated that Bundel has more efficient antioxidant defense system than Vardan and hence was more tolerant to O3 stress.     

Resource conservation strategies for rice‐wheat cropping systems on partially reclaimed sodic soils of the Indo‐Gangetic region,and their effects on soil carbon

The Indo‐Gangetic plain is characterized by intensive agriculture, largely by resource‐poor small and marginal farmers. Vast swathes of salt‐affected areas in the region provide both challenges and opportunities to bolster food security and sequester carbon after reclamation. Sustainable management of reclaimed soils via resource conservation strategies, such as residue retention, is key to the prosperity of the farmer, as well as increases the efficiency of expensive initiatives to further reclaim sodic land areas, which currently lay barren. After five years of experimentation on resource conservation strategies for rice‐wheat systems on partially reclaimed sodic soils of the Indo‐Gangetic region, we evaluated changes in different soil carbon pools and crop yield. Out of all resource conservation techniques which were tested, rice‐wheat crop residue addition (30% of total production) was most effective in increasing soil organic carbon (SOC). In rice, without crop residue addition (WCR), soils under zero‐tillage with transplanting, summer ploughing with transplanting and direct seeding with brown manuring showed a significant increase in SOC over the control (puddling in rice, conventional tillage in wheat). In these treatments relatively higher levels of carbon were attained in all aggregate fractions compared to the control. Soil aggregate sizes in meso (0.25‐2.0 mm) and macro (2‐8 mm) ranges increased, whereas micro (< 0.25 mm) fractions decreased in soils under zero‐till practices, both with and without crop residue addition. Direct seeding with brown manuring and zero tillage with transplanting also showed an increase of 135% and 95%, respectively, over the control in microbial biomass carbon, without crop residue incorporation. In zero tillage with transplanting treatment, both with and without crop residue showed significant increase in soil carbon sequestration potential. Though the changes in accrued soil carbon did not bring about significant differences in terms of grain yield, overall synthesis in terms of balance between yield and carbon sequestration indicated that summer ploughing with transplanting and zero tillage with transplanting sequestered significantly higher rates of carbon, yet yielded on par with conventional practices. These could be appropriate alternatives to immediately replace conventional tillage and planting practices for rice‐wheat cropping systems in the sodic soils of the Indo‐Gangetic region.     

Lignin modification and valorization in medicine,cosmetics, environmental remediation and agriculture: a review

Environmental Chemistry Letters - The circular economy requires advanced methods to recycle biomass into value-added materials, such as lignin extraction and modification. Here, we review lignin...     

Biochemical responses,growth and reproduction of earthworm in low density polyethylene (LDPE)

There is an unprecedented production of plastic that is accelerating its disposal while affecting the fitness of the terrestrial as well as the aquatic environment. The term microplastics refers to plastic fragments that are less than 5 mm in size and are widely distributed in the environment. Therefore, the present study intends to explore the biological response of earthworms (Eisenia fetida) toward different concentrations of low-density polyethylene. E. fetida treated with low-density polyethylene concentration (Control), 250 mg kg⁻¹, 1000 mg kg⁻¹, 6000 mg kg⁻¹, 12,000 mg kg^−1, and 25,000 mg kg⁻¹. The above ratios were thoroughly mixed with 1kg of artificial soil and tested for growth, reproduction (cocoons and hatchling count), and enzymatic activities namely superoxide dismutase, guaiacol peroxidase, glutathione-S-transferase, and glutathione reductase and molecular docking studies. No mortality was observed during the exposure period at any concentrations. On the 28th day, when compared to the control the highest decrease in body weight of earthworms was observed in 25,000 mg (28.4%) followed by 12,000 mg (12.2%) and 6000 mg (3.4%). The cocoon and hatchlings significantly declined as the dose of microplastics increases. Enzymatic activity such as SOD and POD showed declined trend as the dose increased, while GST and GR increased with an increase in microplastic concentrations on 28th day. Furthermore, molecular docking showed that LDPE can modulate the activity of all four enzymes significantly.     

Distribution and abundance of zooplankton in relation to petroleum hydrocarbon content along the coast of Kollam (Quilon), south west coast of India

In the present study we examine status, impact and trends in prevailing situation of coastal ecosystem of Chavara, Neendakara, Tangasseri and Paravur zones of Kollam coast in terms of zooplankton density and petroleum hydrocarbon content (PHC). Zooplankton samples and water samples were collected during the period May 2003 to June 2004. The numerical count of zooplankton made and PHC content estimated. Paravur offshore recorded the maximum zooplankton count (1390 no./m3) and Tangasseri nearshore the lowest (700.5 no/m3). The petroleum hydrocarbon content was highest at Tangasseri nearshore (21.95 microg/l) and lowest at Paravur offshore (9.40 microg/l). We also observe statistically significant negative correlation between zooplankton density and PHC for a few organisms. The overall impact appears minor, yet, coastal ocean monitoring imperative for sustainable development.     

Heavy metal accumulation in lichens growing in north side of Lucknow city, India

Accumulation of Pb, Fe, Cr, Zn, Cd, Ni, Cu and Hg metals in six common lichen species growing on Mangifera indica trees in mango orchard surrounding the north side of the Lucknow city, were analyzed. The study revealed the higher concentration of Pb (3.3 - 15.6 microgg(-1)), Cr (25.6 - 137.5 microgg(-1)), Zn (49.4 - 219.7 microgg(-1)), Cu (10.2 - 66.6 microgg(-1)) and Fe (1748 - 19374 microgg(-1)).     

Development,validation of QuEChERS-based method for simultaneous determination of multiclass pesticide residue in milk,and evaluation of the matrix effect

Extraction and quantification of pesticide residue from the milk matrix at or below the established maximum residue limit (MRL) is a challenging task for both analytical chemists and the regulatory institutions to take corrective actions for the human health and safety. The main aim of the study is to develop a simple rapid and less expensive QuEChERS extraction and cleanup method for simultaneous analysis of 41 multiclass pesticide residue in milk by gas chromatography-electron capture detector (GC-ECD), followed by confirmation of the residues with gas chromatography-mass spectrometer (GC-MS). Effect of sorbent type, temperature, spiking concentration, matrix effect (ME), measurement uncertainty (MU), inter- and intra-assay repeatability, reproducibility of recovery, and trueness of the results were investigated to validate the effectiveness of the method. Limit of determination (LOD) and limit of quantitation (LOQ) for all the analytes ranged within 0.001–0.02 and 0.002–0.05 µg mL^?1, respectively. The % recovery of all the pesticides ranged between 91.38 and 117.56% with relative standard deviation (RSD) below 2.79%. The MU for all the analytes was ≤29% of respective LOQs, and except for few pesticides, the ME was largely negative. The method fulfilled all the SANTE guidelines and thus can be extended for routine analysis of multiclass pesticide residue in milk.     

Bioindicator responses and performance of plant species along a vehicular pollution gradient in western Himalaya

Loss of green cover, and increasing pollution is a prime global concern. The problem calls for screening of pollution-tolerant tree species that can be integrated into plantation drives. Recognizing this, the study analyzed bio-indicator responses and performance of commonly occurring plant species along a pollution gradient in western Himalaya. Based on distance from the road, three sites viz., highly polluted (HP), moderately polluted (MP), and least polluted (LP), were identified. From these sites, leaves of commonly occurring 26 tree species were collected and analyzed for dust accumulation, total chlorophyll, relative water content (RWC), ascorbic acid, and pH using standard protocols. Later, assessment of Air Pollution Tolerance Index (APTI) and Anticipated Performance Indices (API) was carried out. The results revealed variations in biochemical characteristics. The pH, RWC, and total chlorophyll increased with decreasing pollution while ascorbic acid increased with increasing pollution. Dust capturing potential of Ficus carica (1.191 mg/m²) and Toona ciliata (0.820 mg/m²) was relatively higher. Based on the results of APTI, Grevillea robusta was classified as tolerant. It scored significantly higher values (21.06, 21.19, and 19.61 in LP, MP, and HP sites, respectively). Quercus floribunda, G. robusta (68.75% each), Juglans regia (68.7%), and T. ciliata (62.50%) were good performers in HP sites. Acer caesium, Betula utilis, and Morus alba that had low API scores (43.75%) were predicted as poor performers. Thus, G. robusta, Q. floribunda, J. regia, T. ciliata, and F. carica were evaluated as best performers. They could be integrated into plantations drives for environmental management.