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641.
To evaluate the treatment capability of subsurface flow constructed wetland (SFCW) and the effect of salinity on the degradation of atrazine, the degradation of atrazine in SFCW was studied. Under the static condition, the degradation of atrazine in SFCW followed first-order kinetics: c=0.09679 exp(-0.0396t) (c, residue concentration, mg l(-1); t, retention time, d), with a half-life of approximately 17.5 days. The atrazine degradation kinetic functions were established for salinities of 1.5, 3.0, 5.0, 10.0 and 15.0 g l(-1), respectively, which appeared to approach first-order kinetics. The effect of salinity on the atrazine treatment efficiency showed an exponential inhibition: lnk=3.204+0.04991 C (k, degradation constant; C, NaCl concentration, mg l(-1)). The attenuation of atrazine in SFCW cannot be a result of hydrolysis or sorption process. It was considered that some bacteria in the wetland system degraded atrazine into deethylatrazine (DEA) and deisopropylatrazine (DIA) and sequentially into CO(2) and H(2)O. Salinity impacted on the growth of bacteria resulting in a switch of the microbial community. With the increase of salinity, Shannon-Wiener Diversity Index in the SFCW system declined. The relationship between atrazine degradation constant (k) and Shannon Index was established as shown in linear phase, y=-0.07286+0.0363x. The positive correlation between them indicated that microbial community played an important role in the atrazine degradation process. 相似文献
642.
深圳市公路建设对生态环境的影响、治理及对策 总被引:7,自引:0,他引:7
公路建设曾经给深圳的生态环境造成了较为严重的危害 ,主要有 :严重的水土流失及其派生影响 ,对一些具有观赏价值的自然景观产生破坏 ,影响了部分区域动植物生存环境等。主要对这些环境影响及已进行的治理及其成效进行综述 ,对治理工作的不足及未来对策也进行了探讨。 相似文献
643.
644.
A serious forest decline of Betula ermanii Cham. has been observed at Mt. Mae-Shirane, Oku-Nikko, Japan, where high ozone (O3) concentration and severe water deficiency have been measured. In order to consider the possibility whether O3 and/or water stresses could have been the causes of the forest decline of B. ermanii, plant growth experiments were conducted in environment-controlled growth cabinets. Two-year-old seedlings of B. ermanii were exposed to either charcoal-filtered air (O3 concentration <5 ppb) or 50 ppb O3 (daily average, ranging between 20–100 ppb) for 123 days at 20.0/12.5 ± 1.0°C (day/night) and 70/80 ± 7% relative humidity
(day/night). Simultaneously, seedlings were treated with three watering regime: 1.0 < pF < 1.8 (no water stress), 1.8 < pF < 2.5
(mild water stress) or 2.5 < pF < 3.0 (severe water stress). O3 exposure significantly reduced the dry weights of leaf, root and the whole plant, while water stress significantly reduced
the dry weights of each organ and the whole plant. Significant reductions of net photosynthesis, transpiration and stomatal
conductance were also observed under O3 and/or water deficiency treatments, while contents of RuBP carboxylase/oxygenase (Rubisco), chlorophyll
a+b
and some essential nutrient elements (N, P, K, Mg and Ca) were not markedly changed. It was suggested that the decrease in
net photosynthetic rate induced mainly by stomatal closure was the major cause of the growth reduction under O3 and/or water stresses. No significant interactions between O3 and water stresses were observed in terms of the depression of dry matter production, which suggested that simultaneous stress
treatments of O3 exposure and water deficiency could affect the tree growth of B. ermanii additively. 相似文献
645.
Atmospheric aerosol particles and metallic concentrations, ionic species were monitored at the Experimental harbor of Taichung
sampling site in this study. This work attempted to characterize metallic elements and ionic species associated with meteorological
conditions variation on atmospheric particulate matter in TSP, PM2.5, PM2.5–10. The concentration distribution trend between TSP, PM2.5, PM2.5–10 particle concentration at the TH (Taichung harbor) sampling site were also displayed in this study. Besides, the meteorological
conditions variation of metallic elements (Fe, Mg, Cr, Cu, Zn, Mn and Pb) and ions species (Cl−, NO3
−, SO4
2−, NH4
+, Mg2+, Ca2+ and Na+) concentrations attached with those particulate were also analyzed in this study. On non-parametric (Spearman) correlation
analysis, the results indicated that the meteorological conditions have high correlation at largest particulate concentrations
for TSP at TH sampling site in this study. In addition, the temperature and relative humidity of meteorological conditions
that played a key role to affect particulate matter (PM) and have higher correlations then other meteorological conditions
such as wind speed and atmospheric pressure. The parameter temperature and relative humidity also have high correlations with
atmospheric pollutants compared with those of the other meteorological variables (wind speed, atmospheric pressure and prevalent
wind direction). In addition, relative statistical equations between pollutants and meteorological variables were also characterized
in this study. 相似文献
646.
Phorate (O,O-diethyl S-ethylthiomethyl phosphorodithioate) dissolved in aqueous solution was almost completely decomposed by ozonation to form various species within 10 minutes of reaction time for the experimental conditions examined in this research. The generation rate of sulfate was found to be fairly independent of solution pH value. However, the formation of phosphate and carbonate was more favorable for alkaline solutions where hydroxyl free radical is the primary oxidative species. The reaction rates increased with initial gaseous ozone concentrations, indicating the reaction was mass transfer-controlled within the experimental range of this research. Combining the analytical results by various instruments, including gas chromatograph equipped with an electron ionization detector (GC-EID), high performance liquid chromatography (HPLC), ion chromatography (IC), and total organic carbon (TOC), the temporal sequence of phorate ozonation was proposed in this study. The oxidation of sulfur atoms on the phosphorus-sulfur double bond or carbon-sulfur-carbon bond by ozonation was found to occur at first to form sulfate and various intermediates. 相似文献
647.
Is an adjusted rhizosphere-based method valid for field assessment of metal phytoavailability? Application to non-contaminated soils 总被引:1,自引:0,他引:1
Fang J Wen B Shan XQ Lin JM Owens G 《Environmental pollution (Barking, Essex : 1987)》2007,150(2):209-217
Previously recommended rhizosphere-based method (RHIZO) applied to moist rhizosphere soils was integrated with moist bulk soils, and termed adjusted-RHIZO method (A-RHIZO). The A-RHIZO and RHIZO methods were systematically compared with EDTA, DTPA, CaCl2 and the first step of the Community Bureau of Reference (BCR1) methods for assessing metal phytoavailability under field conditions. Results suggested that moist bulk soils are equally suited or even better than rhizosphere soils to estimate metal phytoavailability. The A-RHIZO method was preferred to other methods for predicting the phytoavailability of Ni, Cu, Zn, Cd, Pb and Mn to wheat roots with correlation coefficients of 0.730 (P<0.001), 0.854 (P<0.001), 0.887 (P<0.001), 0.739 (P<0.001), 0.725 (P<0.001) and 0.469 (P<0.05), respectively. When including soil properties, other extraction methods were also able to predict phytoavailability reasonably well for some metals. Soil pH, organic matter and Fe-Mn oxide contents, and cation-exchange capacity mostly influenced the extraction and phytoavailability of metals. 相似文献
648.
弱势群体物质生活贫困,在市场中缺乏竞争能力,在社会和政治层面也处于弱势地位,这些特点决定了他们是公民环境权的贫困者。为此,需要设计合理的制度保护弱势群体公民环境权,需要用法律手段保护弱势群体公民环境权,还需要提高弱势群体保护公民环境权的自觉性。 相似文献
649.
650.
污水厂生物除臭设施运行及影响因素的研究 总被引:2,自引:0,他引:2
在污水处理过程中会有大量的恶臭气体产生,主要含硫化氢和氨等发臭物质.这些臭味物质逸散到空气中,对污水处理厂及其周边的空气环境造成危害.针对清河污水处理厂原有生物除臭设施除臭效率难以提高的问题,对气体收集系统和生物除臭滤池内的喷淋管路进行了改造,并更换了新型生物填料.本研究对改造前后的除臭效果进行了考察,结果显示,硫化氢的平均去除率从改造前的36.5%提高到62.9%,最大去除率可以达到96.2%;氨的去除率从28.2%提高到接近100%.臭味气体的处理效果随除臭滤池的温度、气体的相对湿度的升高而提高.为此,对臭味气体的负荷、流量、温度以及湿度等因素进行了研究,在温度>20℃、相对湿度>80%的条件下,生物除臭滤池能够有比较理想的处理效果. 相似文献