Effects of equipment loadings on geosynthetic-lined slope behaviour.

When combined in the lining and covering of waste-containment facilities, soil and geosynthetic components protect the environment by acting as a hydraulic barrier. Equipment loading may significantly increase the tensile stress induced in geosynthetic components, leading to a potential stability problem. Large equipment loadings may also result in a localized circular slip surface during construction operations. New analytical method based on discrete element modelling is proposed for estimating the distribution of tensile force developed in the individual geosynthetic components of the lining system and for evaluating the safety factor of slope failure due to equipment loading. The analytical results of an example are presented to demonstrate the applicability of the analytical method for the lining system of a waste landfill. The analyses of the example show that equipment loading provide a substantial increase in the tensile forces of the geosynthetic components of a lining system and that the possibility of shallow failure due to equipment loading increases as the slope becomes steeper. This method is a useful tool for analysing the lining system of waste landfills with complex lining components.     

Comparative performance between temperature-phased and conventional mesophilic two-phased processes in terms of anaerobically produced bioenergy from food waste.

Comparative evaluation of bioenergy production from food waste was carried out with both a temperature-phased and a conventional mesophilic two-phased process at different organic loading rates (OLRs). No methane was detected in the temperature-phased thermophilic-acidogenic fermenter at all the OLRs tested. However, a significant amount of methane content was detected in the conventional two-phased mesophilic-acidogenic fermenter, with increments depending on the organic loading rate [from 17% at 3 g VS L(-1) day(-1) to 25% at 8 g VS L(-1) day(-1) (VS, volatile solid)]. Acetate and butyrate were the main volatile fatty acids (VFAs) in the temperature-phased thermophilic-acidogenic fermenter; conversely propionate was a major VFA in the conventional two-phased mesophilic-acidogenic fermenter. Through the chemical oxygen demand (COD) balance of both temperature-phased and conventional mesophilic two-phased processes, the fraction of the feed-COD converted to the hydrogen-COD in the thermophilic-acidogenic fermenter within the former process was estimated from 7.9 to 9.3%, with a peak at ORL of 6 g VS L(-1) day(-1), whereas it was quantified from 0.3 to 0.9% in the mesophilic-acidogenic fermenter within the latter one. Moreover, the fraction of the feed-COD converted to the methane-COD in the mesophilic-acidogenic fermenter within the conventional two-phased process ranged from 5.4 to 7.9%. On the other hand, conversion of the feed-COD to the methane-COD in the mesophilic-methanogenic fermenter of both temperature-phased and conventional mesophilic two-phased processes ranged from 66.2 to 72.3% and from 63.5 to 70.5%, respectively, with decrements related to the increase of organic loading rate.     

Effect of soil solids concentration in batch tests on the partition coefficients of organic pollutants in landfill liner-soil materials

 The effect of the soil solids concentration in batch tests on the measured values of the partition coefficient (K _p) of organic pollutants in landfill liner-soil material was investigated. Since this study was based on the results of batch and column tests conducted independently, there were limitations to the conclusions derived. The organic compounds tested were benzene, methylene chloride, toluene, trichloroethylene, and p-xylene. The results of this study showed that as soil solids concentrations increased, the measured K _p values of these organic compounds strongly decreased. The observed values of K _p stabilized when the soil solids concentration was above a certain value. Typical K _p values obtained from batch tests conducted under high soil solids concentrations were close to those obtained from column tests. It was concluded that the K _p values of organic compounds measured under low soil solids concentrations, i.e., less than 100 g/l, may not correctly simulate the field situation. Consequently, the values of K _p obtained with low soil solids concentrations can result in an overestimation of the retardation factor of the landfill liner material. Received: March 14, 2002 / Accepted: August 25, 2002     

STREAM DISCHARGE PREDICTION VIA A GRID BASED SOIL WATER ROUTING WITH PADDY FIELDS1

ABSTRACT: A grid based daily hydrologic model for a watershed with paddy fields was developed to predict the stream discharge. ASCII formatted elevation, soil, and land use data supported by the GRASS Geographic Information System are used to generate distributed results such as surface runoff and subsurface flow, soil water content, and evapotranspiration. The model uses a single flow path algorithm and simulates a water balance at each grid element. A linear reservoir assumption was used to predict subsurface runoff components. The model was applied to a 75.6 km² watershed located in the middle of South Korea, and observed stream flow hydrographs from 1995 and 1996 were compared to model predictions. The stream flow predictions of 1995 and 1996 generally agreed with the observed flow, resulting in a Nash‐Sutcliffe efficiency R² of 0.60 and 0.62, respectively. The hydraulic conductivity for percolating water through the saturated layer affected baseflow generation. The levee height of the paddy influenced the time and magnitude of the surface runoff, depending on irrigation management. The model will be used for making low flow management decisions by evaluating the role of each land use to stream flow, especially in case of paddy decrease by gradual urbanization of a watershed.     

Accelerated soil dissipation of tebuconazole following multiple applications to peanut

Repeated application may increase rates of pesticide dissipation in soil and reduce persistence. The potential for this to occur was investigated for the fungicide, tebuconazole (alpha-[2-(4-chlorophenyl)ethyl]-alpha-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol), when used for peanut (Arachis hypogaea L.) production. Soil samples were collected from peanut plots after each of four tebuconazole applications at 2-wk intervals. Soil moisture was adjusted to field capacity as necessary and samples were incubated in the laboratory for 63 d at 30 degrees C. Untreated plot samples spiked with the compound served as controls. Results indicated accelerated dissipation in field-treated samples with the time to fifty percent dissipation (DT50) decreasing from 43 to 5 d after three tebuconazole applications. Corresponding increases in rates of accumulation and decay of degradates were also indicated. Best-fit equations (r2 = 0.84-0.98) to dissipation kinetic data combined with estimates of canopy interception rates were used to predict tebuconazole and degradates concentration in soil after each successive application. Predicted concentrations compared with values measured in surface soil samples were from twofold less to twofold greater. Use of kinetic data will likely enhance assessments of treatment efficacy and human and ecological risks from normal agronomic use of tebuconazole on peanut. However, the study indicated that varying soil conditions (in particular, soil temperature and water content) may have an equal or greater impact on field dissipation rate than development of accelerated dissipation. Results emphasize that extension of laboratory-derived kinetic data to field settings should be done with caution.     

Risk assessment of particulate matter by considering time-activity-pattern and major microenvironments for preschool children living in Seoul,South Korea

Environmental Science and Pollution Research - Preschool children aged 3–6 years are vulnerable to exposed to particulate matter (“PM10” and “PM2.5”). It is required...     

Soil pH effects on the interactions between dissolved zinc,non-nano- and nano-ZnO with soil bacterial communities

Zinc oxide nanoparticles (ZnO NPs) are used in an array of products and processes, ranging from personal care products to antifouling paints, textiles, food additives, antibacterial agents and environmental remediation processes. Soils are an environment likely to be exposed to manmade nanoparticles due to the practice of applying sewage sludge as a fertiliser or as an organic soil improver. However, understanding on the interactions between soil properties, nanoparticles and the organisms that live within soil is lacking, especially with regards to soil bacterial communities. We studied the effects of nanoparticulate, non-nanoparticulate and ionic zinc (in the form of zinc chloride) on the composition of bacterial communities in soil with a modified pH range (from pH 4.5 to pH 7.2). We observed strong pH-dependent effects on the interaction between bacterial communities and all forms of zinc, with the largest changes in bacterial community composition occurring in soils with low and medium pH levels (pH 4.8 and 5.9). The high pH soil (pH 7.2) was less susceptible to the effects of zinc exposure. At the highest doses of zinc (2500 mg/kg dw soil), both nano and non-nano particulate zinc applications elicited a similar response in the soil bacterial community, and this differed significantly to the ionic zinc salt treatment. The results highlight the importance of considering soil pH in nanotoxicology studies, although further work is needed to determine the exact mechanisms controlling the toxicity and fate and interactions of nanoparticles with soil microbial communities.     

Inhibition of residual <Emphasis Type="Italic">n</Emphasis>-hexane in anaerobic digestion of lipid-extracted microalgal wastes and microbial community shift

Converting lipid-extracted microalgal wastes to methane (CH₄) via anaerobic digestion (AD) has the potential to make microalgae-based biodiesel platform more sustainable. However, it is apparent that remaining n-hexane (C₆H₁₄) from lipid extraction could inhibit metabolic pathway of methanogens. To test an inhibitory influence of residual n-hexane, this study conducted a series of batch AD by mixing lipid-extracted Chlorella vulgaris with a wide range of n-hexane concentration (～10 g chemical oxygen demand (COD)/L). Experimental results show that the inhibition of n-hexane on CH₄ yield was negligible up to 2 g COD/L and inhibition to methanogenesis became significant when it was higher than 4 g COD/L based on quantitative mass balance. Inhibition threshold was about 4 g COD/L of n-hexane. Analytical result of microbial community profile revealed that dominance of alkane-degrading sulfate-reducing bacteria (SRB) and syntrophic bacteria increased, while that of methanogens sharply dropped as n-hexane concentration increased. These findings offer a useful guideline of threshold n-hexane concentration and microbial community shift for the AD of lipid-extracted microalgal wastes.     

Biodegradability of algal-derived organic matter in a large artificial lake by using stable isotope tracers

In order to understand the biodegradability of algal-derived organic matter, biodegradation experiments were conducted with ¹³C and ¹⁵N-labeled natural phytoplankton and periphytic algal populations in experimental conditions for 60 days. Qualitative changes in the dissolved organic matter were also determined using parallel factor analysis and the stable carbon isotopic composition of the hydrophobic dissolved organic matter through the experimental period. Although algal-derived organic matter is considered to be easily biodegradable, the initial amounts of total organic carbon newly produced by phytoplankton and periphytic algae remained approximately 16 and 44 % after 60 days, respectively, and about 22 and 43 % of newly produced particulate nitrogen remained. Further, the dissolved organic carbon derived from both algal populations increased significantly after 60 days. Although the dissolved organic matter gradually became refractory, the contributions of the algal-derived organic matter to the dissolved organic matter and hydrophobic dissolved organic matter increased. Our laboratory experimental results suggest that algal-derived organic matter produced by phytoplankton and periphytic algae could contribute significantly to the non-biodegradable organic matter through microbial transformations.