Temporal trends of hydrocarbons in sediment cores from the Pearl River Estuary and the northern South China Sea

Concentrations and fluxes of unresolved complex mixture of hydrocarbons (UCM) and polycyclic aromatic hydrocarbons (PAHs) were analyzed for two ²¹⁰Pb dated sediment cores from the Pearl River Estuary (PRE) and the adjacent northern South China Sea (NSCS). Compound-specific stable carbon isotopic compositions of individual n-alkanes were also measured for identification of the hydrocarbon sources. The historical records of PAHs in the NSCS reflected the economic development in the Pearl River Delta during the 20th century. PAHs in the NSCS predominantly derive from combustion of coal and biomass, whereas PAHs in the PRE are a mixture of petrogenic and pyrogenic in origins. The isotopic profiles reveal that the petrogenic hydrocarbons in the PRE originate predominantly from local spillage/leakage of lube oil and crude oils. The accumulation rates of pyrogenic PAHs have significantly increased, whereas UCM accumulation has slightly declined in the NSCS in the recent three decades.     

Combined amendment reduces soil Cd availability and rice Cd accumulation in three consecutive rice planting seasons

The scientific application of stabilized materials has been considered an effective method for the in situ remediation of Cd-contaminated soil. This study aimed to investigate the persistence of the effect of a combined amendment of limestone and sepiolite(LS) on soil Cd availability and accumulation in rice grown in a mildly Cd-contaminated paddy field(0.45 mg/kg of Cd) over three consecutive rice seasons. 1125–4500 kg/ha of LS was applied to the soil before the first rice planting season and 5...     

康滇地轴东缘岩石与铅锌矿石稀土元素地球化学研究

本文系统地研究了康滇地轴东缘不同时代岩石及不同含矿层位铅锌矿石的稀土元素地球化学特征 ,并加以对比。认为本区地壳演化的不均一性及多期构造岩浆活动反映在不同时代岩石其稀土元素地球化学特征也不相同 ,继承性差。本区矿石的稀土元素分布模式不同于以前报道过的呈W型 ,而是一种新的稀土元素分布模式。不同含矿层位铅锌矿石稀土元素分布模式及其参数类似 ,与岩石差异明显 ,说明主要成矿物质不来自基底及盖层岩石 ,而来自深部 (上地幔 ) ,并且是在同一个成矿期形成的。     

某催化裂化装置生产过程中职业病危害因素调查

通过对催化裂化装置生产过程中职业病危害因素调查,找出职业病危害的关键控制点,并提出防护要求。     

Assessing cypermethrin-contaminated soil with three di erent earthworm test methods

A series of tests (lethal, sublethal, and behavioral) on earthworms were conducted as an eco-assessment of pesticides. In this study, the toxicity of cypermethrin-contaminating soil on adult and juvenile earthworms was assessed. Beside the acute and chronic tests, an avoidance response test was carried out. It was shown that the all-round toxicity from cypermethrin was weak on adult earthworms. Compared with adult earthworms, the toxicity of juvenile earthworms from cypermethrin especially chronic toxicity increased significantly. Growth and reproduction of earthworms appeared to be more severely a ected by cypermethrin at juvenile stage than at adult stage. Applied at 10 mg/kg, cypermethrin had obvious adverse impact on the growth of juvenile earthworms, while 20 mg/kg, cypermethrin caused significant toxic e ects in reproduction. The results also indicated that ecotoxicological risk assessment using only adult specimens may underestimate the e ects of cypermethrin on soil invertebrate populations.     

丙烯酸酯类共聚物生产过程中职业病危害因素调查

通过对丙烯酸酯类共聚物生产过程中职业病危害因素进行调查,找出了职业病危害的关键控制点,并提出了防护要求。     

炼油企业硫化氢危害识别与中毒防治措施

介绍了炼油行业硫化氢中毒的现状,识别了炼油企业硫化氢危害,分析了硫化氢中毒的事故原因,并介绍了三级预防的防治措施。     

MTBE装置职业病危害关键控制点及防护对策

通过职业病危害现场调查,分析了某MTBE装置的生产工艺、装置存在的主要职业病危害因素、检测结果、职业病危害防护措施,找出了职业病危害的关键控制点,并提出了防护对策.     

深井厚煤层大巷孤立煤体冲击危险性评价研究*

为了探究大采深条件下厚煤层大巷孤立煤体频繁发生冲击地压的原因,以梁宝寺煤矿35000采区为工程背景,采取现场实践、数值模拟等方法分析不同采深、煤厚、大巷间距等因素对大巷孤立煤体冲击地压的影响,提出深井厚煤层大巷孤立煤体冲击地压的危险性评价方法。研究结果表明:大巷孤立煤体的采深与垂直应力峰值呈正相关,采深1 200 m时煤体的垂直应力峰值是采深500 m时的3倍左右;大巷孤立煤体随着煤层厚度的增加,其应力集中程度不断升高,且应力峰值向煤体弹性承载区转移;大巷间距越小,孤立煤体弹性承载区应力越集中,发生冲击地压可能性越高;包含开采影响因素和煤层冲击倾向性的大巷孤立煤体冲击危险性评价方法符合现场实际情况,可为大巷孤立煤体冲击危险性评价提供1种思路。     

废催化裂化催化剂的危险性及污染特征

为考察我国废催化裂化(FCC)催化剂的危险性及污染特征,以国内典型FCC装置的废催化剂为研究对象,分析其易燃性、反应性、腐蚀性、浸出毒性、毒性物质含量及急性毒性。研究发现:废FCC催化剂无易燃性、反应性、腐蚀性、急性毒性危险;未检测出具有致癌致突变性的有机污染物;废FCC催化剂的特征污染物为Ni及其化合物,Ni的浸出浓度低于国家标准限值,Ni的存在形态为Ni Al2O4尖晶石,而非具有致癌性的Ni O形态。