Environmental Monitoring Of Remedial Dredging At The New Bedford Harbor, Ma, Superfund Site

New Bedford Harbor (NBH), MA, is a Superfund site because of high polychlorinated biphenyl (PCB) concentrations in the sediment. From April 1994 to September 1995, a remedial dredging operation (termed the “Hot Spot”) removed the most contaminated sediments (PCB concentrations greater than 4000μg/g) from the upper harbor. During remediation, a monitoring program assessed the potential environmental impacts to NBH and adjacent Buzzards Bay. The monitoring program was developed with input from federal, state, and local authorities. Site-specific decision criteria were established to assess net PCB transport, water column toxicity, and PCB bioaccumulation in blue and ribbed mussels (Mytilus edulis and Geukensia demissa, respectively). The remediation was completed without exceeding PCB net transport or acute toxicity effects specified in the decision criteria. In addition, PCB bioaccumulation in mussels during this time period was not significantly greater than pre- or post-operational measurements. The results indicated that approximately 14000 cubic yards of highly PCB contaminated sediment were permanently removed with minimal environmental effects. The lessons learned during this operation, as well as previous pilot studies at the site, will be used to make full-scale remedial efforts in NBH more efficient and environmentally protective.     

Variability in the identification and enumeration of marine benthic invertebrate samples and its effect on benthic assessment measures

Studies designed to measure anthropogenic impacts on marine benthic communities depend on the ability of taxonomists to consistently discriminate, identify, and count benthic organisms. To quantify errors and discrepancies in identification and enumeration, 20 samples were completely reprocessed by another one of four participating laboratories. Errors were detected in 13.0% of the data records, affecting total abundance by 2.1%, numbers of taxa by 3.4%, and identification accuracy by 4.7%. Paired t-tests were used to test for differences in the Benthic Response Index (BRI), total abundance, numbers of taxa, and the Shannon-Wiener index between the original and the reanalysis data. Differences in the BRI were statistically insignificant. Although statistically significant differences were observed for numbers of taxa, total abundance, and the Shannon-Wiener index, the differences were small in comparison to the magnitude of differences typically observed between anthropogenically affected and reference sites.     

Relationship between depth, sediment, latitude, and the structure of benthic infaunal assemblages on the mainland shelf of southern California

A regional benthic survey was conducted in 1994, and the data were used to assess the relationship among three habitat factors (depth, sediment grain size, and latitude) and the distribution of benthic infaunal assemblages on the southern California coastal shelf. Benthic samples were collected with a 0.1 m² Van Veen grab from 251 sites on the continental shelf (10–200 m deep) from Point Conception, California, to the United States–Mexico international border. The relationship between habitat and assemblages was investigated by conducting a Q-mode cluster analysis to define groups of stations with similar species composition and then examining whether differences were present in physical habitat attributes among those groups of stations. Analysis of data from 175 uncontaminated sites yielded four habitat-related benthic infaunal assemblages along the southern California coastal shelf: a shallow-water assemblage from 10–32 m, a mid-depth assemblage between 32 and 115 m, and two deep-water (115–200 m) assemblages, one in fine and one in coarse sediments. These empirically defined points in the depth and sediment grain size gradients can be used to define reference habitats for the development of biocriteria. Benthic abundance and diversity were greatest in the mid-depth assemblage, conforming to predictions for benthic assemblages in regions of upwelling. Within the 500 km of coastline examined, latitude was not an important factor in defining assemblages. Received: 3 December 1999 / Accepted: 9 October 2000     

Retrospective monitoring of persistent organic pollutants,including PCBs,PBDEs, and polycyclic musks in blue mussels (Mytilus edulis) and sediments from New Bedford Harbor,Massachusetts, USA: 1991–2005

Blue mussels (Mytilus edulis) and sediments collected from 1991 to 2005 from New Bedford Harbor (NBH), MA, were analyzed for two polycyclic musks (HHCB or Galaxolide® and AHTN or Tonalide®), polybrominated diphenyl ethers (PBDEs), polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs). HHCB and AHTN were found in mussel tissues at mean concentrations of 836 and 376 ng/g lipid weight (lw), respectively, which were two- to seven-fold higher than those found at a reference site. Mean concentrations of HHCB and AHTN in NBH sediments were 12 and 6.3 ng/g dry weight (dw), respectively. Four- and five-ringed PAHs, such as phenanthrene, anthracene, fluoranthene, and pyrene, collectively accounted for 61 % of the ∑PAHs concentrations in mussels from NBH. Mean ΣPCB concentrations in mussels from upper and lower NBH were 942 and 182 μg/g lw, respectively, and were dominated by tetra- and penta-chlorobiphenyl congeners, collectively accounting for 61 % of the ΣPCB concentrations. The mean concentration of ∑PBDEs in mussels from NBH was 277 ng/g lw, and no significant difference existed in the concentrations between upper and lower NBH. DDTs were the major OCP found in mussels, found at a mean concentration of 778 ng/g lw. The concentrations of HHCB, AHTN, ΣPBDEs, ΣPAHs, and DDTs in mussels decreased significantly (r ²?≥?0.56, p?≤?0.052) from 1991 to 2005. The concentrations of PCBs and chlordanes did not exhibit a decreasing trend in mussel tissues (r ²?<?0.50; p?>?0.076) from 1991 to 2005. Based on the temporal trends in the concentrations of HHCB, AHTN, ∑PAHs, and ∑PBDEs found in mussels from NBH, it was estimated that between 5.5 and 12 years were required for the concentrations of these compounds to decrease by half (i.e., environmental halving time) of the levels found in 1991.     

Identifying impediments to long‐distance mammal migrations

In much of the world, the persistence of long‐distance migrations by mammals is threatened by development. Even where human population density is relatively low, there are roads, fencing, and energy development that present barriers to animal movement. If we are to conserve species that rely on long‐distance migration, then it is critical that we identify existing migration impediments. To delineate stopover sites associated with anthropogenic development, we applied Brownian bridge movement models to high‐frequency locations of pronghorn (Antilocapra americana) in the Greater Yellowstone Ecosystem. We then used resource utilization functions to assess the threats to long‐distance migration of pronghorn that were due to fences and highways. Migrating pronghorn avoided dense developments of natural gas fields. Highways with relatively high volumes of traffic and woven‐wire sheep fence acted as complete barriers. At crossings with known migration bottlenecks, use of high?quality forage and shrub habitat by pronghorn as they approached the highway was lower than expected based on availability of those resources. In contrast, pronghorn consistently utilized high?quality forage close to the highway at crossings with no known migration bottlenecks. Our findings demonstrate the importance of minimizing development in migration corridors in the future and of mitigating existing pressure on migratory animals by removing barriers, reducing the development footprint, or installing crossing structures. Identificación de los Impedimentos para las Migraciones de Larga Distancia de Mamíferos     

Assessment of Benthic Infaunal Condition on the Mainland Shelf of Southern California

Benthic infauna were sampled from 251 Southern California Bight (SCB) mainland shelf sites in the summer of 1994. Sample sites were selected using a stratified random design, with the primary strata being depth zone, geography, and proximity to point and non-point discharges. Benthic infaunal condition was assessed using the Benthic Response Index (BRI), and by comparing dominant taxa and community parameters (e.g., number of taxa) among strata. Ninety-one percent of sediments in the SCB were found to contain healthy benthic communities. Most stations with altered benthos were located near river mouths, in Santa Monica Bay, or on the Palos Verdes Shelf. Deviations at sites with altered benthic communities were mostly limited to minor changes in species composition, rather than to large declines in diversity or abundance.     

Climate change impacts detection in dry forested ecosystem as indicated by vegetation cover change in —Laikipia,of Kenya

The objective of the study was to detect and identify land cover changes in Laikipia County of Kenya that have occurred during the last three decades. The land use types of study area are six, of which three are the main and the other three are the minor. The main three, forest, shrub or bush land and grassland, changed during the period, of which grasslands reduced by 5864 ha (40%), forest by 3071 ha (24%) and shrub and bush land increased by 8912 ha (43%). The other three minor land use types were bare land which had reduced by 238 ha (45%), river bed vegetation increased by 209 ha (72%) and agriculture increased by 52 ha (600%) over the period decades. Differences in spatiotemporal variations of vegetation could be largely attributed to the effects of climate factors, anthropogenic activities and their interactions. Precipitation and temperature have been demonstrated to be the key climate factors for plant growth and vegetation development where rainfall decreased by 200 mm and temperatures increased by 1.5 °C over the period. Also, the opinion of the community on the change of land use and management was attributed to climate change and also adaptation strategies applied by the community over time. For example unlike the common understanding that forest resources utilisation increases with increasing human population, Mukogodo dry forested ecosystem case is different in that the majority of the respondents (78.9%) reported that the forest resource use was more in that period than now and also a similar majority (74.2%) had the same opinion that forest resource utilisation was low compared to last 30 years. In Yaaku community, change impacts were evidenced and thus mitigation measures suggested to address the impacts which included the following: controlled bush management and indigenous grass reseeding programme were advocated to restore original grasslands, and agricultural (crop farming) activities are carried out in designated areas outside the forest conservation areas (ecosystem zoning) all in consultation with government (political class), community and other stakeholders. Groups are organised (environmental management committee) to address conservation, political and vulnerability issues in the pastoral dry forested ecosystem which will sustain pastoralism in the ecosystem.     

Modelling tritium and phosphorus transport by preferential flow in structured soil

Subsurface solute transport through structured soil is studied by model interpretation of experimental breakthrough curves from tritium and phosphorus tracer tests in three intact soil monoliths. Similar geochemical conditions, with nearly neutral pH, were maintained in all the experiments. Observed transport differences for the same tracer are thus mainly due to differences in the physical transport process between the different monoliths. The modelling is based on a probabilistic Lagrangian approach that decouples physical and chemical mass transfer and transformation processes from pure and stochastic advection. Thereby, it enables explicit quantification of the physical transport process through preferential flow paths, honouring all independently available experimental information. Modelling of the tritium breakthrough curves yields a probability density function of non-reactive solute travel time that is coupled with a reaction model for linear, non-equilibrium sorption–desorption to describe the phosphorus transport. The tritium model results indicate that significant preferential flow occurs in all the experimental soil monoliths, ranging from 60–100% of the total water flow moving through only 25–40% of the total water content. In agreement with the fact that geochemical conditions were similar in all experiments, phosphorus model results yield consistent first-order kinetic parameter values for the sorption–desorption process in two of the three soil monoliths; phosphorus transport through the third monolith cannot be modelled because the apparent mean transport rate of phosphorus is anomalously rapid relative to the non-adsorptive tritium transport. The occurrence of preferential flow alters the whole shape of the phosphorus breakthrough curve, not least the peak mass flux and concentration values, and increases the transported phosphorus mass by 2–3 times relative to the estimated mass transport without preferential flow in the two modelled monoliths.