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641.
Sharma KK Kalpana Sharma V Gupta P Jaya M Kumar A Singh B 《Environmental monitoring and assessment》2008,137(1-3):179-184
Fipronil termiticide belongs to phenyl-pyrazole class of chemical compounds. It has broad-spectrum activity particularly against
house hold pests such as cockroaches, mosquitoes, locusts, ticks, and fleas at both larval and adult stages. At high dosage
it can be used to control subterranean termites in building foundations. To evaluate long term efficacy against termites the
persistence and vertical distribution of fipronil was studied under natural weather conditions of Dehradun, India. Fipronil
was applied at four concentrations i.e. 0.05, 0.1, 0.25 and 0.5% a.i ha−1 by drenching 17 × 17 in.2 plot prepared as per modified ground board test. Soil samples were collected after 22, 38 and 56 months of treatment up to
the depth of 75 cm. The soil core was cut into five distinct sections i.e. 0–15, 15–30, 30–45, 45–60 and 60–75 cm depth. The
residues were extracted by shaking 20 g soil sample with acetone. The acetone extract was concentrated and cleaned-up over
florisil column. Fipronil residues were estimated on GLC at 220, 260, and 300°C oven, injector and detector temperature respectively.
Fipronil was found to persist beyond 56 months after application. Two metabolites viz. desulfinyl and sulfide-fipronil were
detected in sampling after 22 months of application that also dissipated with time. Fipronil residues were found up to 60 cm
depth. The residues in deeper layers dissipate slowly with time and after 56 months of treatment residues were detected only
up to 30 cm depth. 相似文献
642.
Priyanka Chaudhary Harmesh Sahay Richa Sharma Alok Kumar Pandey Shashi Bala Singh A. K. Saxena Lata Nain 《Environmental monitoring and assessment》2015,187(6):391
Polyaromatic hydrocarbons (PAHs) utilizing bacteria were isolated from soils of seven sites of Mathura refinery, India. Twenty-six bacterial strains with different morphotypes were isolated. These strains were acclimatized to utilize a mixture of four polycyclic aromatic hydrocarbons, i.e., anthracene, fluorene, phenanthrene, and pyrene, each at 50 mg/L concentration as sole carbon source. Out of total isolates, 15 potent isolates were subjected to 16S rDNA sequencing and identified as a member of diverse genera, i.e., Bacillus, Acinetobacter, Stenotrophomonas, Alcaligenes, Lysinibacillus, Brevibacterium, Serratia, and Streptomyces. Consortium of four promising isolates (Acinetobacter, Brevibacterium, Serratia, and Streptomyces) were also investigated for bioremediation of PAH mixture. This consortium was proved to be efficient PAH degrader resulting in 40–70 % degradation of PAH within 7 days. Results of this study indicated that these genera may play an active role in bioremediation of PAHs. 相似文献
643.
Soil enzymes are indicators of microbial activities in soil and are often considered as an indicator of soil health and fertility. They are very sensitive to the agricultural practices, pH of the soil, nutrients, inhibitors and weather conditions. To understand the effect of an insecticide, thiamethoxam, on different soil enzyme activities, the experiments were conducted at cotton experimental fields of Punjab Agricultural University, Ludhiana. The results here were presented to understand the impact of thiamethoxam on soil enzyme activities. Thiamethoxam was applied as seed treatment to control the pest. Soil from three localities, i.e. soil in which seed was treated with recommended dose at 2.1 g a.i. kg?1, soil in which seed was treated with four times recommended dose at 8.4 g a.i. kg?1 and from the control field, were tested for different enzyme activities. Phosphatase and dehydrogenase activities were high in control soil in comparison to control soil while no effect of this insecticide on urease activity. Thiamethoxam had inhibitory effects on dehydrogenase and phosphatase activities. Therefore, it can be attributed that agricultural practices, weather conditions and use of thiamethoxam might be responsible for the different level of enzyme activities in soil. 相似文献
644.
645.
Kunwar P. Singh Shikha Gupta Premanjali Rai 《Environmental monitoring and assessment》2014,186(5):2749-2765
Kernel function-based regression models were constructed and applied to a nonlinear hydro-chemical dataset pertaining to surface water for predicting the dissolved oxygen levels. Initial features were selected using nonlinear approach. Nonlinearity in the data was tested using BDS statistics, which revealed the data with nonlinear structure. Kernel ridge regression, kernel principal component regression, kernel partial least squares regression, and support vector regression models were developed using the Gaussian kernel function and their generalization and predictive abilities were compared in terms of several statistical parameters. Model parameters were optimized using the cross-validation procedure. The proposed kernel regression methods successfully captured the nonlinear features of the original data by transforming it to a high dimensional feature space using the kernel function. Performance of all the kernel-based modeling methods used here were comparable both in terms of predictive and generalization abilities. Values of the performance criteria parameters suggested for the adequacy of the constructed models to fit the nonlinear data and their good predictive capabilities. 相似文献
646.
Impact of Coal Power Plant Emission on the Foliar Elemental Concentrations in Plants in a Low Rainfall Tropical Region 总被引:1,自引:0,他引:1
A field study was conducted around two thermal power plants of India to quantify the changes in foliar elemental concentrations due to emission in a low rainfall tropical area. Sulphur dioxide and particulates were at high levels which may cause serious ecological effects. Emission from the power plants has altered the elemental concentrations in the leaves of evergreen and deciduous plants. The foliar total-S and SO4
2–-S levels were significantly higher in all the plants growing at polluted sites. However, the organic-S content was more or less unaltered. In evergreen plants, the SO4
2–-S content increased gradually from summer through winter, whereas in the deciduous plants there was a higher magnitude of increase after onset of new leaves during summer. With the increasing pollution load, foliar Ca2+ and K+ contents increased, whereas N content decreased. The reduction in N content was greater during summer in evergreen plants and during winter in deciduous plants. The plants growing closer to the power plants accumulated more trace elements (Mn, Fe, Cd, Pb and Ni) as compared to those growing at distant sites. In deciduous plants the leaf fall during winter lowered down the trace element 相似文献
647.
S. K. Sahoo Kousik Mandal Gurmail Singh Rajinder Kumar G. S. Chahil R. S. Battu Balwinder Singh 《Environmental monitoring and assessment》2013,185(2):1711-1718
Quizalofop ethyl, a phenoxy propionate herbicide, is used for postemergence control of annual and perennial grass weeds in broad-leaved crops in India. The experiments were designed to study the dissipation kinetics of quizalofop ethyl on onion for two seasons. A simple, rapid, and sensitive method for estimation of quizalofop ethyl residues in onion and soil was developed and validated. The recoveries of quizalofop ethyl residues from onion and soil at different spiking level range from 84.81 to 92.68 %. The limit of quantification of this method was found to be 0.01 μg g?1. The risk assessment through consumption of the onion in comparison to its acceptable daily intake which is an important parameter for the safety of the consumer was also evaluated. Standardized methodology supported by recovery studies was adopted to estimate residues of quizalofop ethyl on onion and soil. The average initial deposits of quizalofop ethyl on onion were observed to be 0.25 and 0.33 mg kg?1, following single application of the herbicide at 50 g active ingredient (a.i.) ha?1 during 2009 and 2010, respectively. The half-life values (T 1/2) of quizalofop ethyl on onion crop were worked out to be 0.85 and 0.79 days, respectively, during 2009 and 2010. At harvest time, the residues of quizalofop ethyl on onion and soil were found to be below the determination limit of 0.01 mg kg?1 following single application of the herbicide at 50 and 100 g a.i. ha?1 for both the periods. 相似文献
648.
Effects of BHC (8 mg litre(-1)) and malathion (10 mg litre(-1)) exposure for 96 h have been studied on T(3) and T(4) concentrations in plasma, and in pharyngeal thyroid tissue preparations. Thyroid peroxidase (TPO) activity in the pharyngeal thyroid tissue, along with the extra-thyroidal conversion of T(4) into T(3) were measured in a freshwater catfish, Heteropneustes fossilis. BHC stimulated TPO activity in this fish, during both in vitro and in vivo studies. In contrast, malathion was found to stimulate TPO activity during the in vitro experiments but to inhibit it in the in vivo study. Concentrations of T(3) and T(4) increased in the thyroid gland, as well as in the plasma, in response to BHC exposure. However, in both these tissues, malathion increased T(3) concentrations and reduced T(4) concentrations. The extrathyroidal conversion of T(4) into T(3) was stimulated by malathion and inhibited by BHC. 相似文献
649.
Shilpa Nitai Basak Sumer Singh Meena 《Frontiers of Environmental Science & Engineering》2022,16(12):161
650.
Antibiotics are routinely used in intensive animal agriculture operations collectively known as Concentrated Animal Feed Operations(CAFO) which include dairy, poultry and swine farms. Wastewater generated by CAFOs often contains low levels of antibiotics and is typically managed in an anaerobic lagoon. The objective of this research is to investigate the uptake and fate of aqueous sulfamethazine(SMN) antibiotic by alfalfa(Medicago sativa)grass grown under hydroponic conditions. Uptake studies were conducted using hydroponically grown alfalfa in a commercially available nutrient solution supplemented with 10 mg/L of SMN antibiotic. Analysis of alfalfa sap, root zone, middle one-third, and top portion of the foliage showed varying uptake rate and translocation of SMN. The highest average amount of SMN(8.58 μg/kg) was detected in the root zone, followed by the top portion(1.89 μg/kg), middle one-third(1.30 μg/kg), and sap(0.38 μg/kg) samples, indicating a clear distribution of SMN within the sampled regions. The ultraviolet(UV) spectra of parent SMN and translocated SMN identified in different parts of the plant present the possibility of metabolization during the uptake process. Uptake of SMN using alfalfa grown under hydroponic conditions has potential as a promising remediation technology for removal of similar antibiotics from wastewater lagoons. 相似文献