Assessment of tropical suburban surface soils contamination from Jengka,Malaysia

Heavy metals in suburban soils pose both indirect and direct health risks. This study assessed the concentrations of Cr, Zn, Pb, and Cd in Jengka (Malaysia) suburban soil and estimated the human health risk. Health risk assessment (HRA) was utilized to assess non-cancer and cancer risks. The concentrations of heavy metals increased in the following order: Cd < Zn < Cr < Pb. The heavy metals were found to be divided into two components using principal component analysis (PCA), with PC1 comprising Pb and Cd and PC2 containing Zn and Cr. PC1 originates from anthropogenic sources, while PC2 is often from mixed anthropogenic and natural sources. Despite having the lowest mean concentration, Cd was enriched based on the geo-accumulation index (Igeo) and enrichment factor (EF). Average hazard index values were below the acceptable threshold (HI < 1) for dermal and inhalation pathways suggesting a low non-cancer risk. Jengka suburban soil had total lifetime cancer risk values slightly higher than the acceptable threshold (1 × 10⁻⁵). Skin contact was the most prominent contributing exposure pathway for both non-carcinogenic and carcinogenic risks. This study suggests that heavy metal bioactivity levels be used to make a plausible HRA of heavy metal pollution in suburban soils.     

Impact of NOx Emissions Released from a Gas Turbine-Based Power Plant on the Ambient Air Quality

The number of gas turbine- (GT-) based power plants is rapidly increasing to meet the world’s power demands. Until a few years ago, fossil fuel, and specifically fuel oil, was considered the major energy source for gas turbine operation. Due to the high amount of pollution that fuel oil generates, natural gas has become a popular source of energy due to its lower emissions compared to fuel oil. As a result, many GTs have switched to natural gas as an alternative to fuel oil. However, pollutants expelled from GT-based power plants operating on natural gas impact surrounding air quality. The objective of this study was to examine the dispersion of nitrogen oxides (NO_x) emitted from a GT-based power plant located in the Sultanate of Oman. Supported by CALPUFF dispersion modeling software, six scenarios were investigated in this study. The first four scenarios considered a case where the GT-based power plant was operating on natural gas during winter and summer and for open and combined cycle modes. The remaining two scenarios considered, for both open and combined cycle modes, the case where the GT-based power plant was operating on fuel oil. Whether run by natural gas or fuel oil, CALPUFF simulation results for both seasons showed that NO_x concentrations were higher when GTs were used in the combined cycle mode. The concentrations were still lower than the allowable concentrations set by the United States Environmental Protection Agency (U.S. EPA) standards. In contrast, for the case where the power plant operated on fuel oil, the NO_x one-hour average simulated results exceeded the allowable limits only when the combined cycle mode was activated.     

Agricultural innovation and adaptation to climate change: empirical evidence from diverse agro-ecologies in South Asia

While impacts of climate change on agricultural systems have been widely researched, there is still limited understanding of what agricultural innovations have evolved over time in response to both climatic and non-climatic drivers. Although there has been some progress in formulating national adaptation policies and strategic planning in different countries of South Asia, research to identify local-level adaptive strategies and practices is still limited. Through eight case studies and a survey of 300 households in 15 locations in India, Nepal and Bangladesh, this paper generates empirical evidence on emerging agricultural innovations in contrasting socio-economic, geographical and agro-ecological contexts. The study demonstrates that several farm practices (innovations) have emerged in response to multiple drivers over time, with various forms of institutional and policy support, including incentives to reduce risks in the adoption of innovative practice. It further shows that there is still limited attempt to systematically mainstream adaptation innovations into local, regional and national government structures, policies and planning processes. The paper shows that the process of farm-level adaptation through innovation adoption forms an important avenue for agricultural adaptation in South Asia. A key implication of this finding is that there is a need for stronger collaborations between research institutions, extension systems, civil society and the private sector actors to enhance emerging adaptive innovations at the farm level.     

Preparation and characterization of glass hollow fiber membrane for water purification applications

This work discusses the preparation and characterizations of glass hollow fiber membranes prepared using zeolite-5A as a starting material. Zeolite was formed into a hollow fiber configuration using the phase inversion technique. It was later sintered at high temperatures to burn off organic materials and change the zeolite into glass membrane. A preliminary study, that used thermogravimetric analysis (TGA), X-ray diffraction (XRD), and Fourier transform infrared (FTIR), confirmed that zeolite used in this study changed to glass at temperatures above 1000 °C. The glass hollow fiber membranes prepared using the phase inversion technique has three different microstructures, namely (i) sandwich-like structure that originates from inner layer, (ii) sandwich-like that originates from outer layer, and (iii) symmetric sponge like. These variations were influenced by zeolite weight loading and the flow rate of water used to form the lumen. The separation performances of the glass hollow fiber membrane were studied using the pure water permeability and the rejection test of bovine serum albumin (BSA). The glass hollow fiber membrane prepared from using 48 wt% zeolite loading and bore fluid with 9 mL min^?1 flow rate has the highest BSA rejection of 85% with the water permeability of 0.7 L m^?2 h^?1 bar^?1. The results showed that the separation performance of glass hollow fiber membranes was in the ultrafiltration range, enabled the retention of solutes with molecular sizes larger than 67 kDa such as milk proteins, endotoxin pyrogen, virus, and colloidal silica.     

Economic analysis of biogas and compost projects in a palm oil mill with clean development mechanism in Malaysia

This article is a case study to compare the economic viabilities of biogas generation and compost projects in a palm oil mill in Malaysia with and without clean development mechanism (CDM). Biogas is captured from anaerobic ponds or digester tanks treating palm oil mill effluent (POME) and converted to green renewable electricity for grid connection, while compost is produced from the shredded empty fruit bunch and raw untreated POME. The both technologies were compared by considering the changes of the materials flow and energy balances. A palm oil mill with a capacity of 54?t fresh fruit bunch per hour has the potential to produce either 6.9?GWh of electricity from biogas or fertilizer equivalent to 488?t of nitrogen, 76?t of phosphorus and 1,065?t of potassium per year. The economic analysis for 10?years project term analysis indicated that CDM gave a significant impact and ensured economic viability for both projects with 25?% of internal rate of return (IRR), RM 12.39 million of net present value (NPV) and 3.5?years of payback period (PBP) for biogas project, whereas 31?% of IRR, RM 10.87 million of NPV and 2.9?years of PBP for compost project, respectively. In addition, sensitivity analysis indicated that the profitability of both projects will vary depending on the economic situation, such as electricity price which is based on the government policy, whereas compost price that depend on fertilizer market price with 43?% NPV change in 20?% range of fertilizer value.     

On-line CO, CO2 emissions evaluation and (benzene, toluene, xylene) determination from experimental burn of tropical biomass

Atmospheric pollution and global warming issues are increasingly becoming major environmental concerns. Fire is one of the significant sources of pollutant gases released into the atmosphere; and tropical biomass fires, which are of particular interest in this study, contribute greatly to the global budget of CO and CO₂. This pioneer research simulates the natural biomass burning strategy in Malaysia using an experimental burning facility. The investigation was conducted on the emissions (CO₂, CO, and Benzene, Toluene, Ethylbenzene, Xylenes (BTEX)) from ten tropical biomass species. The selected species represent the major tropical forests that are frequently subjected to dry forest fire incidents. An experimental burning facility equipped with an on-line gas analyzer was employed to determine the burning emissions. The major emission factors were found to vary among the species, and the specific results were as follows. The moisture content of a particular biomass greatly influenced its emission pattern. The smoke analysis results revealed the existence of BTEX, which were sampled from a combustion chamber by enrichment traps aided with a universal gas sampler. The BTEX were determined by organic solvent extraction followed by GC/MS quantification, the results of which suggested that the biomass burning emission factor contributed significant amounts of benzene, toluene, and m,p-xylene. The modified combustion efficiency (MCE) changed in response to changes in the sample moisture content. Therefore, this study concluded that the emission of some pollutants mainly depends on the burning phase and sample moisture content of the biomass.     

Assessment of electrocoagulation for the treatment of petroleum refinery wastewater

Batch electrocoagulation experiments were carried out to evaluate the removal of sulfate and COD from petroleum refinery wastewater using three types of electrodes: aluminum, stainless steel, and iron. The effects of current density, electrode arrangement, electrolysis time, initial pH, and temperature were investigated for two wastewater samples with different concentrations of COD and sulfate. The experimental results indicated that the utilization of aluminum, as anode and cathode, was by far the most efficient arrangement in the reduction of both the contaminants. The treatment process was found to be largely affected by the current density and the initial composition of the wastewater. Although electrocoagulation was found to be most effective at 25°C and a pH of 8, the influence of these two parameters on the removal rate was not significant. The results demonstrated the technical feasibility of electrocoagulation as a possible and reliable technique for the pretreatment of heavily contaminated petroleum refinery wastewater.     

Synthesis of Alkyd Resin from Non-Edible Jatropha Seed Oil

The kinetics of polyesterification of glycerol, phthalic anhydride and jatropha oil leading to the formation of alkyd resins were studied. A series of alkyd resins having different amount of jatropha oil viz., 40–80% have been prepared by employing two stage alcoholysis-polyesterification process. The extent of reaction and average degree of polymerisation were calculated from the end group analysis of the reaction mixture withdrawn at regular intervals of time. The initial reaction rates followed the second order kinetics and thereafter deviations were observed. An appreciable degree of conversion was noticed from the extent of the reaction which lies in the range of 49.5–62.5%. The average degree of polymerisation calculated in the region of deviation from second order suggested the occurrence of chain branching at relatively shorter intervals along the polymer chain. The second order rate constants were found to be of the order of 10⁻⁵ g (mg KOH)⁻¹ min⁻¹.     

Pesticide risk assessment: A study on inhalation and dermal exposure to 2,4-D and paraquat among Malaysian paddy farmers

A cross-section analytical study was conducted to evaluate the risk of pesticide exposure to those applying the Class II pesticides 2,4-D and paraquat in the paddy-growing areas of Kerian, Perak, Malaysia. It investigated the influence of weather on exposure as well as documented health problems commonly related to pesticide exposure. Potential inhalation and dermal exposure for 140 paddy farmers (handlers of pesticides) were assessed. Results showed that while temperature and humidity affected exposure, windspeed had the strongest impact on pesticide exposure via inhalation. However, the degree of exposure to both herbicides via inhalation was below the permissible exposure limits set by United States National Institute of Occupational Safety and Health (NIOSH). Dermal Exposure Assessment Method (DREAM) readings showed that dermal exposure with manual spraying ranged from moderate to high. With motorized sprayers, however, the level of dermal exposure ranged from low to moderate. Dermal exposure was significantly negatively correlated with the usage of protective clothing. Various types of deleterious health effects were detected among users of manual knapsack sprayers. Long-term spraying activities were positively correlated with increasing levels of the gamma-glutamyl transpeptidase (GGT) liver enzyme. The type of spraying equipment, usage of proper protective clothing and adherence to correct spraying practices were found to be the most important factors influencing the degree of pesticide exposure among those applying pesticides.