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111.
Lazar M. Kaluđerović Zorica P. Tomić Rada D. Đurović-Pejčev Predrag J. Vulić Darko P. Ašanin 《Journal of environmental science and health. Part. B》2017,52(5):291-297
This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86 mmol/100 g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM. 相似文献
112.
Radić Danka S. Pavlović Vera P. Lazović Milana M. Jovičić-Petrović Jelena P. Karličić Vera M. Lalević Blažo T. Raičević Vera B. 《Environmental science and pollution research international》2017,24(27):21885-21893
Environmental Science and Pollution Research - Modern, efficient, and cost-effective approach to remediation of heavy metal-contaminated soil is based on the application of microorganisms. In this... 相似文献
113.
Our laboratory investigation aimed at assessing to what extent suspended particles could adsorb formaldehyde, allowing it, when inhaled, to penetrate deeper into the lung. We used two types of pure soot, N-220 and N-660 (the former being a highly active oil furnace soot with smaller particles and a larger surface area than the latter), because of their chemical inactivity and the adsorptive properties. The results obtained in experimental conditions showed that soot particles could bind 2.3 to 50.2% of formaldehyde, depending on the particle size, relative humidity, amount of particles and the duration of the contact. The recovery of formaldehyde from the particles was also tested. Further investigation is planned under realistic conditions. 相似文献
114.
Marković DM Marković DA Jovanović A Lazić L Mijić Z 《Environmental monitoring and assessment》2008,145(1-3):349-359
O(3), NO(2), SO(2), CO and PM(10) concentrations, simultaneously determined for the first time in Belgrade urban area in the autumnal period of 2005, are presented. The obtained results display similar behaviour of SO(2), NO(2), CO, PM(10) opposite from that of O(3). The weekend effect was also investigated showing diminution of average daily concentrations of SO(2), NO(2), PM(10) and CO for 72, 40, 37 and 42% respectively, and increase of the average daily concentration of O(3) for 56%. Influence of meteorological conditions on observed concentration levels was studied, too. The observed influence of wind speed on the O(3) nightly concentration levels was analyzed pointing to the phenomena of O(3) transport during episodic measurements. To make an identification of possible pollution sources and analyse the influence of meteorological parameters on pollution levels, air back trajectories for high level concentrations episodes were calculated and analysed. A multivariate receptor modelling (Principal Component Analysis, Cluster Analysis) has been applied to a set of data in order to determine the contribution of different sources. It was found that the main principal components, extracted from the air pollution data, were related to gasoline combustion, oil combustion and ozone transport. 相似文献
115.
Marković DM Novović I Vilotić D Ignjatović Lj 《Environmental monitoring and assessment》2009,153(1-4):377-382
In this work, experiments were undertaken in an open field having 10,000 m2 area purified from any noise on 121 survey stations using the central frequencies of seven different octave bands with a single and double artificially formed sources of noise. Meteorological parameters such as temperature, humidity, atmospheric pressure, velocity and direction of wind were also taken into consideration. Additionally, the effect of reflecting waves from any surface was also experimentally examined. To evaluate the data obtained, the statistical program of SPSS 9.05 was utilized. From this research, an equation utilising all the parameters was developed. 相似文献
116.
The long-term behaviour of (137)Cs activity concentrations in air and fallout has been studied in the city of Zagreb for the post-Chernobyl period (1986-2006) as a part of an extended monitoring program of radioactive contamination of human environment in Croatia. Annual mean (137)Cs activity concentrations in air and annual total deposition fluxes (wet plus dry) decreased from 2.8 x 10(-4) Bq m(-3) in September 1986 to 3.0 x 10(-6) Bq m(-3) in last quarter of 2006 and from 6,410 Bq m(-2) year(-1) in 1986 to 2 Bq m(-2) year(-1) in 2006 respectively. By fitting the measured (137)Cs activity concentrations to the theoretical curve the ecological half-lives of (137)Cs in air and fallout were estimated with respective values of 0.46 and 0.54 years for immediate post-Chernobyl period, increasing to 5.52 and 3.97 years afterwards. Using the data on (137)Cs activity concentrations in air and fallout total caesium deposition velocity of (3.34 +/- 3.13) x 10(-2) ms(-1) was estimated with median value being 2.13 x 10(-2) ms(-1). Such relatively high (137)Cs deposition velocities compared with pre-Chernobyl ones, are characteristic for the post-Chernobyl period and, according to Stokes' settling law, indicate that the diameters of aerosol particles associated with (137)Cs originated from the Chernobyl accident are pretty large, i.e. >1 microm. (134)Cs/(137)Cs activity ratio in fallout and in air has been found to be similar to the theoretically predicted values, initial value being about 0.5 and decreasing according to differential radioactive decay. The similar ratio has been observed in most of the other environmental samples. 相似文献
117.
Metal and metallothionein level in the heat-treated cytosol of gills of transplanted mussels Mytilus galloprovincialis Lmk 总被引:3,自引:0,他引:3
A stock of mussels Mytilus galloprovincialis was transplanted over 1 year to four sites in a semi-enclosed bay in Croatia which is under the influence of various sources of pollution. The positive correlation of metal (Cd, Zn, Cu, Mn, Fe) and metallothionein (MT) tissue contents based on the analysis of heat-treated cytosol of gills with shell mass, as an indicator of mussel age, indicated to accumulation of metals, as well as the increase of MTs with mussel age. The principal component analysis (PCA) revealed that 74% of total variance of obtained results could be explained through two principal components. The first principal component was highly correlated with MT, Cd and Zn indices (metal or MT content/shell mass), and the second one with Cu, Mn, and Fe indices, as well as the gill index. High correlation of MTs with Zn and Cd is consistent with their affinity for binding to MTs. 相似文献
118.
Spatial distribution of trace metals in the Krka River, Croatia: an example of the self-purification 总被引:2,自引:0,他引:2
The spatial distribution of dissolved and total trace metals (Zn, Cd, Pb and Cu) in the Krka River (partly located in the Krka National Park) has been studied using a "clean" sampling, handling and analysis technique. Differential pulse anodic stripping voltammetry (DPASV) with a hanging mercury drop electrode (HMDE) has been used for trace metal analysis. The Krka River has been divided into the upper and lower flow region with respect to the metals concentration and main physico-chemical parameters. A significant increase in trace metal concentration as the result of the untreated waste water discharge downstream of Knin Town has been registered in the upper flow region. Due to a specific characteristic of the Krka, the so-called self-purification process, a decrease in the elevated trace metals concentration from the water column takes place at numerous small lakes formed by tufa barriers (at the end of the upper flow region). The clean groundwater input at the beginning of the lower flow region additionally contributes to the observed decrease in trace metals concentration in the Krka, maintaining them at a very low level in the remaining region of fresh-water flow. The determined median total concentrations were zinc 120-7400 ng l(-1), cadmium 3-8 ng l(-1), lead 11-250 ng l(-1) and copper 110-440 ng l(-1). Karst rivers, such as the Krka River, with extremely low natural concentrations of trace metals are highly sensitive to the anthropogenic influence. Therefore, such aquatic systems require implementation of strict protection regimes in the entire catchments area. 相似文献
119.
Jeran Z Mrak T Jaćimović R Batic F Kastelec D Mavsar R Simoncic P 《Environmental pollution (Barking, Essex : 1987)》2007,146(2):324-331
Two country-wide surveys using epiphytic lichens as biomonitors of atmospheric pollution carried out during 2000 and 2001 in Slovenia were compared with surveys in 1991 and 1992. In the first survey, epiphytic lichen cover was studied in more than 500 plots of the 4 x 4 km national grid carried out within the framework of forest decline inventories. In the second survey, the epiphytic lichen Hypogymnia physodes (L.) Nyl., was collected on a 16 x 16 km bioindication grid and analysed for S, N, As, Br, Ce, Cd, Cr, K, La, Mo, Rb, Sb, Th, U and Zn contents. Only 'forested area' sampling points were included in the present study. Lichen cover was low, with about 70% of plots with less than 10% foliose lichen cover. No relationship was found between Hypogymnia trace element, N and S concentrations and foliose epiphytic lichen cover. 相似文献
120.
Irena Ciglenečki Srđan Pichler Esad Prohić Božena Ćosović 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):537-545
Geochemical, mineralogical and sedimentological analyses were carried out to contrast two different sites (respectively characterized
by permanently oxic and anoxic conditions) in a small, meromictic, seawater lake. In fact, due to relatively high organic
matter content, and reduced water exchange, the Rogoznica Lake has almost permanent anoxic conditions below the depth of 12 m,
where sediment can be considered an anoxic–sulphidic sedimentary environment. Different water column and sediments redox conditions
affect the distribution and speciation of major redox-sensitive metals (Fe, Mn, Mo), reduced sulphur species (RSS) and dissolved
organic C (DOC). Trace metals, especially those that accumulate in anoxic–sulphidic environments (Fe, Mo) showed a marked
enrichment in the solid phase, whereas the low solubility of sulphides leads to low porewater concentrations. The relatively
high sedimentary enrichment of Mo (up to 81 mg/kg) also confirms highly anoxic conditions within the Rogoznica Lake sediments.
Results clearly show that chemical species within the sediments will tend towards equilibrium between porewater and solid
phase according the prevailing environment conditions such as redox, pH, salinity, DOC. 相似文献