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31.
Figueira R Pacheco AM Sousa AJ Catarino F 《Environmental pollution (Barking, Essex : 1987)》2002,119(1):69-78
Blubber collected from beluga whales and ringed seals during subsistence hunts in the southern Baffin Island region of the Canadian Arctic were analysed for polychlorinated naphthalenes and eight planar PCB congeners (mono-ortho PCBs: 105, 114, 118 and 156; non-ortho PCBs: 77, 81, 126, 169). SigmaPCN (3-7 Cl) concentrations in blubber ranged from 35.9-383 pg/g (lipid weight; lw) in beluga and 35.4-71.3 pg/g (lw) in ringed seal. These represent the first measurements of PCNs in marine mammals in the Canadian Arctic, mammals which are an important part of the traditional diet of the indigenous population. SigmaCoplPCB concentrations were much higher, ranging from 15.5-317 ng/g (lw) in beluga whale blubber and 16.5-40.9 ng/g (lw) in ringed seal blubber. PCNs and coplanar PCBs both exhibit dioxin-like toxicity. Although average sigmaPCN concentrations were less than 1% of sigmaCoplPCBs, PCNs contribute up to 11% of TEQ relative to the coplanar PCBs based on TEFs determined by H4IIE enzyme assays. 相似文献
32.
The sole routine testing of the standard earthworm Eisenia fetida for the terrestrial risk assessment of pesticides has been under much debate since other soil invertebrates may be more sensitive than this standard test species. However, the very low availability of laboratory toxicity data for taxa other than E. fetida has greatly hampered sensitivity comparisons. In the present study, the relative tolerance (Trel) approach was used to enable comparing toxicity thresholds obtained from the US-EPA ECOTOX database, for main terrestrial taxonomic groups and pesticidal types of action (insecticides, fungicides, herbicides, and other) separately. Analyses confirmed previously reported lower and higher sensitivity of collembolans to fungicides and insecticides, respectively. However, various other discrepancies in susceptibility relative to E. fetida were encountered as indicated by species sensitivity distributions and/or calculated 95% confidence intervals of Trel values. Arachnids and isopods were found to be more sensitive to insecticides, and nematodes to fungicides, as compared to E. fetida. Implications of study findings for the terrestrial risk assessment of pesticides are discussed. 相似文献
33.
Alvim-Ferraz MC Sousa SI Pereira MC Martins FG 《Environmental pollution (Barking, Essex : 1987)》2006,140(3):516-524
The main purpose of this study was to evaluate the contribution of anthropogenic pollutants to the increase of tropospheric ozone levels in the Oporto Metropolitan Area (Portugal) since the 19th century. The study was based on pre-industrial and recent data series, the results being analyzed according to the atmospheric chemistry. The treatment of ozone and meteorological data was performed by classical statistics and by time-series analysis. It was concluded that in the 19th century the ozone present in the troposphere was not of photochemical origin, being possible to consider the respective concentrations as reference values. For recent data a cycle of 8h for ozone concentrations could be related to traffic. Compared to the 19th century, the current concentrations were 147% higher (252% higher in May) due to the increased photochemical production associated with the increased anthropogenic emissions. 相似文献
34.
The performance of three statistical methods: time-series, multiple linear regression and feedforward artificial neural networks models were compared to predict the daily mean ozone concentrations. The study here reported was based on data from one urban site with traffic influences and one rural background site. The studies were performed for the year 2002 and the respective four trimesters separately. In the multiple linear regression and feedforward artificial neural network models, the concentrations of ozone, the concentrations of its precursors (nitrogen oxides) and some meteorological variables for one and two days before the prediction day were used as predictors. For the application of these models in the validation step, the inputs of ozone concentration for one and two days before were replaced by the ozone concentrations predicted by the models. The results showed that time-series modelling was not profitable. In the development step, similar performances were obtained with multiple linear regression and feedforward artificial neural network. Better performance indexes were achieved with feedforward artificial neural network models in validation step. Concluding, feedforward artificial neural network models were more efficient to predict ozone concentrations. 相似文献
35.
Rodolfo N. Sousa Marcello M. Veiga Bern Klein Kevin Telmer Aaron J. Gunson Ludovic Bernaudat 《Journal of Cleaner Production》2010,18(16-17):1757-1766
Worldwide, the environmental impacts of artisanal and small-scale gold mining (ASGM) are extensive. Annual losses from mercury, which is used to amalgamate gold, are in the range of 1000 tonnes, and at advanced sites, there is the additional threat of cyanide contamination.Recent developments in The Brazilian Amazon, an area populated by 200,000 small-scale gold miners, have the potential to reduce these impacts considerably. In the locality of Garimpo Ouro Roxo, miners are presently using amalgamation and cyanidation in vat-leaching. Each cycle typically recovers 50% of the gold and lasts 20 days (per tank), consuming around 3300 kg NaCN/month. A new process has been developed and implemented in a pilot plant in this area, involving gravity concentration followed by cyanidation in a ball mill. Concentrate leaching is conducted with a PVC capsule filled with activated carbon inserted in the cyanide solution in the mill. The cycle takes less than 24 h and recovers up to 98% of the gold in the concentrate. The main advantages of wide adoption of this method, apart from a reduced gold recovery cycle and improved recovery, include possible phase out of amalgamation altogether, and marked reductions in cyanide consumption (from current 22,000 kg–980 kg annually). 相似文献
36.
Marta Horta de Sousa Vergílio Helena Maria Gregório Pina Calado 《Journal of Environmental Planning and Management》2015,58(6):1015-1033
The biophysical features of small islands (SI) distinguish them from other territories; isolation, small size and several anthropogenic pressures reduce the resilience of ecosystems and increase their vulnerability to global changes. Many SI have a shortage of infrastructures, institutions and technical/financial resources that hinder planning and require different integrated solutions. In Portugal, the National Ecological Reserve (NER) is legally binding for spatial planning instruments. It aims to defend natural values and areas of ecological value, or sensibility, or susceptible to natural hazards. However, the criteria for the design of NER are strictly set for mainland territory, not taking into account specific features of small islands. A case study of the Azores Archipelago is used to demonstrate that spatial planning instruments should be adapted to island contexts. Such adaptation will increase the effectiveness of their implementation in relation to the protection of natural resources, stability of biophysical structures and prevention of natural hazards. Observing the main differences between mainland and the Azores Archipelago it is possible to define a methodological transposition of the NER aims and goals into an island context. This approach is an answer to the constraints in effective adaptation of spatial planning instruments for islands. 相似文献
37.
Simões Eliane de Sousa Junior Wilson C. de Freitas Débora M. Mills Morena Iwama Allan Y. Gonçalves Isabel Olivato Débora Fidelman Pedro 《Regional Environmental Change》2017,17(6):1739-1750
Regional Environmental Change - This paper examines barriers and opportunities for climate change adaptation in an urban coastal setting where adaptation is in its infancy. It draws on a diagnostic... 相似文献
38.
39.
de Abreu Íthalo Barbosa Silva de Sousa Maria Helena da Silva Andressa Pereira de Araújo Padilha Carlos Eduardo Sales Aldo Torres da Silva Antonio Samuel Alves Dutra Emmanuel Damilano Menezes Rômulo Simões Cezar 《Journal of Material Cycles and Waste Management》2023,25(3):1309-1324
Journal of Material Cycles and Waste Management - The use of food waste (FW) for the production of biofuels and value-added compounds is growing worldwide. However, the significant chemical... 相似文献
40.
Helena Piairo Raquel Menezes Inês Sousa Rui Figueira Cecília Sérgio 《Environmental science and pollution research international》2014,21(23):13420-13433
The use of mosses as biomonitors operates as an indicator of their concentration in the environment, becoming a methodology which provides a significant interpretation in terms of environmental quality. The different types of pollution are variables that can not be measured directly in the environment - latent variables. Therefore, we propose the use of factor analysis to estimate these variables in order to use them for spatial modelling. On the contrary, the main aim of the commonly used principal components analysis method is to explain the variability of observed variables and it does not permit to explicitly identify the different types of environmental contamination. We propose to model the concentration of each heavy metal as a linear combination of its main sources of pollution, similar to the case of multiple regression where these latent variables are identified as covariates, though these not being observed. Moreover, through the use of geostatistical methodologies, we suggest to obtain maps of predicted values for the different sources of pollution. With this, we summarize the information acquired from the concentration measurements of the various heavy metals, and make possible to easily determine the locations that suffer from a particular source of pollution. 相似文献