水稻烤田期间N2O排放及其影响因素

水稻田间实验研究了烤田期间的土壤温度、Eh、含水量和裂缝基本性质,矿质态氮以及与氮有关的酶活性的演变规律,及其对N2O排放的影响.试验表明,在水稻分蘖期间烤田,N2O有一个排放高峰,其最高值可达75.6μg·m-2·h-1.在排放高峰后,即使继续烤田,N2O的排放值也将降低.N2O排放与尿素氮肥的施用量没有明显关系.裂缝的生成,改变了N2O的日排放规律.随着烤田时间的延长,脲酶和羟胺还原酶活性呈波动变化,硝酸还原酶活性递减,亚硝酸还原酶活性极低.硝酸还原酶活性与N2O排放之间没有显著相关性.土壤中的脲酶活性与N2O日排放通量呈显著的线性正相关.在烤田期间,NO-3含量呈增加趋势.土壤中的硝态氮含量与N2O排放通量之间呈显著正线性关系.土壤中的铵态氮含量与N2O排放通量之间呈显著负线性相关.     

On-line optical determination of floc size of Fe(Ⅲ) coagulants

This study investigated the floc aggregation, average floc size, floc size variance and floc growth velocity when ferric chloride （FeCl3） and polyferric chloride （PFC） were used to treat the simulated water samples. The factors including coagulant dose, ionic strength and solution pH, which affect the floc aggregation, were studied. Experiments were carried out in a bench-scale reactor using photometric dispersion analyzer （ PDA）. Results showed that there were great differences between the floc aggregation of PFC and FeCl3. The average floc size and fioc growth velocity of PFC were much larger than those of FeCl3. Compared with FeCl3, PFC gave a better coagulation performance in wider range of pH, dosage and ionic strength. It was also found that the coagulation efficiency of PFC did not depend on average floc size but on floc growth velocity.     

Sorption of pyrene on two paddy soils and their particle-size fractions

In the present study, the sorption of pyrene on two kinds of bulk paddy soils, Gleyic Stagnic Anthrosols, and Ferric accumulic Stagnic Anthrosols as well as their particle-size fractions was investigated. The sorption isotherms fitted well with Freundlich equation. For both soils, the clay fraction（ 〈 2μm） and coarse sand fraction（2000-250μm） had higher sorption capacity than fine sand fraction（250-20 μm） and silt fraction（20-2 μm）. The IogKoc values obtained of each soil and its particle-size fractions were similar, proving that SOM content was a key factor affecting pyrene sorption. The Kd values showed a significant correlation with contents of dithionite-extractable Fe in both paddy soils and a good relationship with CEC in Gleyic Stagnic Anthrosols, indicating possible effects of surface properties of particle-size fractions on the sorption of pyrene.     

Simulating dairy liquid waste management options as a nitrogen source for crops

Large scale dairy operations are common. In many cases the manure is deposited on a paved surface and then removed with a flushing system, after which the solids are separated, the liquid stored in ponds, and eventually the liquid applied on adjacent crop land. Management of liquid manure to maximize the fertilizer value and minimize water quality degradation requires knowledge of the interactive effects of mineralization of organic N (ON) to NH₄⁺, crop uptake of mineral N, and leaching of NO₃⁻ on a temporal basis. The purpose of the research was to use the ENVIRO-GRO model to simulate how the amount of applied N, timing of N application, ON mineralization rates, chemical form of N applied, and irrigation uniformity affected (1) yields of corn (Zea mays) in summer and a forage grass in winter in a Mediterranean climate and (2) the amount of NO₃⁻ leached below the root zone. This management practice is typical for dairies in the San Joaquin Valley of California. The simulations were conducted for a 10-year period. Steady state conditions, whereby an equivalent amount of N applied in the organic form will be mineralized in a given year, are achieved more rapidly for materials with high mineralization rates. Both timing and total quantity of N application are important in affecting crop yield and potential N leaching. Major conclusions from the simulations are as follows. Frequent low applications are preferred to less frequent higher applications. Increasing the amount of N application increased both the crop yield and the amount of NO₃⁻ leached. Increasing irrigation uniformity increased crop yields but had variable effects on the amount of NO₃⁻ leached. A winter forage crop following a summer corn crop effectively reduced the leaching of residual soil N following the corn crop.     

采用钙钛矿型催化剂(La0.8K0.2Cu0.05Mn0.95O3)同时催化去除NOx和碳烟的研究

将钙钛矿型催化剂与碳烟均匀混合后置于固定床连续流动反应体系中,利用程序升温反应技术,在模拟柴油机尾气的情况下对同时催化去除氮氧化物(NOx)和碳烟的反应进行了实验研究.通过改变含Cu原料的用量,得到不同Cu取代量的催化剂La0.8K0.2CuxMn1-xO3,性能评价结果表明,La0.8K0.2Cu0.05Mn0.95O3催化剂的综合性能较好,碳烟的起燃温度及NO向N2的最大转化率分别为280℃和58.0%.采用该催化剂,进一步考察了进气中NO浓度、O2浓度、进气总流量及催化剂与碳烟的接触状况对反应的影响.研究结果表明,进气中NO浓度、O2浓度、气体总流量和催化剂与碳烟之间的接触状况对NO的去除率的影响比较明显,而对碳烟起燃温度的影响较小.O2浓度从5%变为7.5%时,碳烟的起燃温度及最大NO转化率分别从280℃和53.8%变为270℃和96.7%.碳烟与催化剂松散接触时,碳烟的起燃温度及最大NO转化率分别为290℃和48.4%,紧密接触时分别为275℃和70.4%.而进气中NO浓度、气体总流量的变化对碳烟的燃烧基本上没有影响,虽然NO的转化率有明显变化,但生成的N2总量基本不变.     

外控电势对Ch-1菌株生长及Cr(Ⅵ)还原的影响

为进一步优化Ch-1菌株对碱性含铬废水的处理及铬渣的解毒效果,以细菌总数和6价铬的还原率为指标,详细考察了外控电位对Ch-1菌株生长及Cr(Ⅵ)还原的影响.结果表明,电极材料对细菌生长及其活性有一定的影响,不锈钢电极和铂电极体系对细菌生长及活性的影响基本相同,而采用石墨电极细菌的培养效果欠佳.静态培养和动态培养Ch-1菌株时,Cr(Ⅵ)的最终还原率与初始Cr(Ⅵ)浓度无关,24h时Cr(Ⅵ)的还原率均达到了100%;但就还原过程而言,动态培养对Cr(Ⅵ)的还原速率明显优于静态培养,外控电势能够增强或抑制Ch-1菌株的生长及活性,0～-900 mV的负电位可以促进细菌的生长,而400 mV以上的正电势对Ch-1菌株的生长有抑制作用.在-800～ 200 mV的电势范围内,Ch-1菌株还原6价铬的能力得到增强,在此范围外其还原能力受到抑制.     

模拟消落带水华暴发行为的数值沙堆模型

以长江最大支流汉江近年来水华污染的现场资料为例,通过氮磷浓度、水温、流速和光照等实测数据构建了消落带开放水域环境体系的数值沙堆模型,描述了藻类生长及水华暴发的动力学机制;利用数值沙堆系统崩塌行为反映出的频率-尺度幂律关系作为判断消落带水域是否暴发水华以及规模大小的依据,采用有限尺度标度分析从不同侧面验证了水华暴发系统的自组织临界性,并揭示出各种拟合参数与水华暴发规模之间的定量关系.研究表明,沙堆模型如果存在良好的幂律关系,相应的消落带水域将暴发水华,且幂律指数越大,水华污染程度越严重.     

Ni2+对2-氯酚厌氧降解系统的影响

针对重金属对难降解有毒有机物厌氧降解的影响问题,采用间歇试验法研究Ni2 对2-氯酚(2-CP)厌氧降解系统的影响规律.结果表明,当ρ(Ni2 )＜5 mg/L时,Ni2 对2-CP厌氧降解表现出轻度促进,当ρ(Ni2 )为5～500 mg/L,Ni2 以抑制作用为主,抑制作用随ρ(Ni2 )的增加而增强.Ni2 对原基质及关键中间产物苯酚和苯甲酸的抑制程度表现为:苯酚＞苯甲酸＞2-CP;ρ(Ni2 )低时的驯化能有效提高厌氧污泥对Ni2 毒性的耐受性能,300 mg/L Ni2 对2-CP降解的抑制从驯化前的65%降至驯化后的21%.Ni2 对2-CP厌氧降解的抑制作用与污泥中Ni的截留量之间存在正相关关系.抑制浓度CIP值和方程αC=[1-(I/I*)m]/[1 (I/I*)n)]能较好地表征厌氧生物处理过程受抑制程度.     

Membrane fouling control by ultrasound in an anaerobic membrane bioreactor

In this study, ultrasound was used to control the membrane fouling online in an anaerobic membrane bioreactor (AMBR). Short-term running experiments were carried out under different operating conditions to explore feasible ultrasonic parameters. The experimental results indicated that when the crossflow velocity was more than 1.0 m/s, membrane fouling could be controlled effectively only by hydrodynamic methods without ultrasound. When ultrasound was applied, an ultrasonic power range of 60–150 W was suitable for the membrane fouling control in the experimental system. The experimental results showed that the membrane fouling was controlled so well that membrane filtration resistance (ΣR) could stay at 5 × 10¹¹ m⁻¹ for more than a week with the crossflow velocity of 0.75 m/s, which equaled the effect of crossflow velocity of more than 1.0 m/s without ultrasound. Translated from Techniques and Equipment for Environmental Pollution Control, 2006, 7(4): 25–29 [译自: 环境污染治理技术与设备]     

Toxic effects of wastewater from various phases of monosodium glutamate production on seed germination and root elongation of crops

To make a comprehensive assessment on monosodium glutamate (MSG) wastewater pollution, a pollution exposure experiment was carried out on the seed germination and root elongation of wheat, Chinese cabbage and tomato by using the wastewater discharged from different processing phases of MSG production. The results showed that there were significantly positive linear relationships between the inhibitory rates of wheat seed germination and root elongation and the COD_cr of the mother liquor scraps. The toxicity of MSG wastewater to the test crops was in the order of tomato > Chinese cabbage > wheat, indicating that tomato was the most sensitive to the wastewater, and could be considered as an ideal toxic bioindicator. The half-effect concentrations (IC₅₀) based on the seed germination and root elongation of the test crops exposed to the wastewater discharged from various processing phases of MSG production was 22.0–32 432 and 17.3–3320 mg/L, respectively. Translated from Chinese Journal of Applied Ecology, 2006, 17(7): 1286–1290 [译自: 应用生态学报]