Survey of PCDD/Fs and non-ortho PCBs in UK sewage sludges

A survey of PCDD/F and non-ortho PCB concentrations in the mesophilic, anaerobically digested sludge of 14 UK wastewater treatment works was carried out. The range of total Cl1-Cl8DD/F concentrations in the sludges was 8880-428000 pg/g dw with a median of 23300 pg/g dw. The concentrations of the three non-ortho PCBs were in the range 272-63000 pg/g dw with a median of 695 pg/g dw. The PCDD/F I-TEQs of the sludges studied were comparable to those published in the literature with a range of 20-225 pg I-TEQ/g dw and a median of 40.4 pg/g dw. The non-ortho PCBs usually added 2-7 pg/g to the total TEQ with one notable exception which increased the TEQ value 20-fold. With three exceptions, the PCDD/F content of the sludges fell well below the draft EU limit values proposed on 27 April 2000. The homologue group pattern of the PCDD/Fs is dominated by the HpCDDs and OCDD and is consistent with that found in most sewage sludges. There appears to be no correlation between the degree of industrial input and the PCDD/F concentration. This suggests that trade effluent is not always the most significant source of PCDD/Fs to wastewater in the UK.     

Observations on the short-term movements and behaviour of whale sharks (Rhincodon typus) at Ningaloo Reef, Western Australia

The short-term movements and behaviour of whale sharks (Rhincodon typus Smith, 1828) during March 1994 and April 1997 are reported from data collected by acoustic tracking and archival tags at Ningaloo Reef on the north west coast of Western Australia. Sharks were tracked for up to 26 h and generally swam slowly at ≃0.7 m s⁻¹ parallel to the reef edge; occasionally they swam in a wide arc adjacent to passes in the reef. All tracked sharks made regular dives through the water column, mostly from the surface to near the bottom. These dives did not appear to be related to hydrographic features, and the sharks were probably searching the water column for food. Most sharks were accompanied by other fishes, usually the golden trevally Gnathanodon speciosus. Received: 19 January 1999 / Accepted: 22 June 1999     

Fate of 1,2,3,4,6,7,8-heptachlorodibenzofuran and pentachlorophenol during laboratory-scale anaerobic mesophilic sewage sludge digestion

The possibility of the formation of PCDDs and dechlorination of PCDFs during the anaerobic digestion of sewage sludge in laboratory scale digesters was investigated. Digesters were spiked with 1,2,3,4,6,7,8-HpCDF-13C(6) (240 ng/g organic matter (OM)) and pentachlorophenol (PeCP)-13C(6) (24 microg/g OM) and the output sludge monitored for 60 days. No dechlorination or formation of the labelled or native PCDD/Fs was observed. The detectable 1,2,3,4,6,7,8-HpCDF-13C(6) dechlorination yield was 0.0008-1% depending on homologue group and the detectable formation of OCDD yield was 0.00042% PeCP-13C(6). Preferential respiration of other, more bioavailable, substrates is suggested as the most plausible explanation for the lack of dechlorination. Formation of PCDDs from PeCP has been observed in aerobic environments but this study provides further evidence that it is not a precursor for formation during anaerobic digestion.     

Dissolved organic nitrogen regulation in freshwaters

Dissolved organic nitrogen (DON) has been hypothesized to play a major role in N cycling in a variety of ecosystems. Our aim was to assess the seasonal and concentration relationships between dissolved organic carbon (DOC), DON, and NO3- within 102 streams and 16 lakes within catchments of differing complexity situated in Wales. Further, we aimed to assess whether patterns of land use, soil type, and vegetation gave consistent trends in DON and dissolved inorganic nitrogen (DIN) relationships over a diverse range of catchments. Our results reinforce that DON constitutes a significant component of the total dissolved N pool typically representing 40 to 50% of the total N in streams and lakes but sometimes representing greater than 85% of the total dissolved N. Generally, the levels of DON were inversely correlated with the concentration of DIN. In contrast to DIN concentrations, which showed distinct seasonality, DON showed no consistent seasonal trend. We hypothesize that this reflects differences in the bioavailability of these two N types. The amount of DON, DOC, and DIN was significantly related to soil type with higher DON export from Histosol-dominated catchments in comparison with Spodosol-dominated watersheds. Vegetation cover also had a significant effect on DON concentrations independent of soil type with a nearly twofold decrease in DON export from forested catchments in comparison with nonforested watersheds. Due to the diversity in catchment DON behavior, we speculate that this will limit the adoption of DON as a broad-scale indicator of catchment condition for use in monitoring and assessment programs.     

On the potential of iPhone significant location data to characterize individual mobility for air pollution health studies

● We evaluated the accuracy of iPhone data in capturing time-activity patterns. ● iPhone data captured the most important microenvironments and time spent in them. ● iPhone data also accurately captured daily exposure to ambient PM pollution. ● A considerable fraction of the population in the USA may have iPhone data available. ● iPhone data has great potential in air pollution health studies. In many air pollution health studies, the time-activity pattern of individuals is often ignored largely due to lack of data. However, a better understanding of this location-based information is expected to decrease uncertainties in exposure estimation. Here, we showcase the potential of iPhone’s Significant Location (iSL) data in capturing the user’s historical time-activity patterns in order to estimate exposure to ambient air pollutants. In this study, one subject carried an iPhone in tandem with a reference GPS tracking device for one month. The GPS device recorded locations in 10 second intervals while the iSL recorded the time spent in locations the subject visited frequently. Using GPS data as a reference, we then evaluated the accuracy of iSL data in capturing the subject’s time-activity patterns and time-weighted air pollution concentration within the study time period. We found the iSL data accurately captured the time the subject spent in 16 microenvironments (i.e. locations the subject visited more than once), which was 93% of the time during the study period. The average error of time-weighted aerosol optical depth value, a surrogate of particle pollution, is only 0.012%. To explore the availability of iSL data among iPhone users, an online survey was conducted. Among the 349 surveyed participants, 72% of them have iSL data available. Considering the popularity of iPhones, iSL data may be available for a significant portion of the general population. Our results suggest iSL data have great potential for characterizing historical time-activity patterns to improve air pollution exposure estimation.     

Comparing spatial and temporal changes in metal trends (Cr,Ni, Pb and Zn) on the Portuguese shelf since the 1970s

Comparison between an archive dataset, collected during the 1970s (1974–1977), and samples taken during the PALEO1 cruise (2002) enabled evaluation of large-scale and long-term spatiotemporal changes in Al, Cr, Ni, Pb and Zn contents in bulk surface sediments in four areas of the Portuguese shelf. The so-called gradient method (GM) with normalisation to Al, a proxy for terrigenous clay content, was applied. The studied areas are distributed from north to south along the western margin, with the northernmost located off shore the Ave and Douro rivers, a central one located off shore the Lis River and a southern one located off shore the Mira River. One-way ANOVA and Kruskal-Wallis tests were used to identify differences among study areas and periods of sample collection. A comparison of metal contents in 2002 samples with the Portuguese classification scheme regulation for deposition of dredged materials in coastal areas indicates good environmental quality in terms of Cr, Ni, Pb and Zn levels. Nevertheless, the GM results suggest an increase in metal loadings relative to Al from the 1970s to the 2002 samples (except for Pb). The Algarve area on the southern shelf is characterised by having high number of sites with metal level on class 2. These high values have traditionally been explained by a substantial supply of natural metals from the Guadiana, Tinto and Odiel rivers that drain areas Iberian Pyrite Belt formations. This supply has probably been magnified by present and past mining activities. For quality evaluation of marine sediments, especially when using total metal contents, this study shows the importance of considering all possible sources of metal loading. The natural grain size and composition variability have also a crucial influence on the metal content, and the combined evaluation allows a more holistic perspective.     

Closing the gap: a research agenda to accelerate the adoption and effective use of proven older adult fall prevention strategies

IntroductionTo make an impact on the public's health, evidence-based interventions must be disseminated broadly, supported by training and technical assistance, adopted widely, and implemented as designed. Many effective older adult fall prevention interventions have been identified, but too few have gained wide community acceptance and little is known about the best ways to encourage their broader use. Therefore, as in many other fields, fall prevention suffers from a wide gap between scientific discoveries and their everyday use.MethodThis article articulates the key activities embedded in Step 4 of the public health model—specifically translation and dissemination to ensure widespread adoption and use—in order to illuminate critical research needs in older adult fall prevention.ConclusionsThese needs, if addressed, will help close the gap between research and practice.     

Comparison of several packings for CO2 chemical absorption in a packed column

CO₂ capture and storage has gained widespread attention as an option for reducing greenhouse gas emissions. Chemical absorption and stripping of CO₂ with hot potassium carbonate (K₂CO₃) solutions has been used in the past, however potassium carbonate solutions have a low CO₂ absorption efficiency. Various techniques can be used to improve the absorption efficiency of this system with one option being the addition of promoters to the solvent and another option being an improvement in the mass transfer efficiency of the equipment. This study has focused on improving the efficiency of the packed column by replacing traditional packings with newer types of packing which have been shown to have enhanced mass transfer performance. Three different packings (Super Mini Rings (SMRs), Pall Rings and Mellapak) have been studied under atmospheric conditions in a laboratory scale column for CO₂ absorption using a 30 wt% K₂CO₃ solution. It was found that SMR packing resulted in a mass transfer coefficient approximately 20% and 30% higher than that of Mellapak and Pall Rings, respectively. Therefore, the height of packed column with SMR packing would be substantially lower than with Pall Rings or Mellapak. Meanwhile, the pressure drop using SMR was comparable to other packings while the gas flooding velocity was higher when the liquid load was above 25 kg m⁻² s⁻¹. Correlations for predicting flooding gas velocities and pressure drop were fitted to the experimental data, allowing the relevant parameters to be estimated for use in later design.     

Bioconcentration of triclosan, methyl-triclosan, and triclocarban in the plants and sediments of a constructed wetland

Constructed wetlands are a potential method for the removal of two pharmaceutical and personal care products from wastewater effluent. Triclosan (TCS; 5-chloro-2-[2,4-dichlorophenoxy]phenol) and triclocarban (TCC; 3,4,4′-trichlorocarbanillide) are antimicrobial agents added to a variety of consumer products whose accumulation patterns in constructed wetlands are poorly understood. Here, we report the accumulation of TCS, its metabolite methyl-triclosan (MTCS; 5-chloro-2-[2,4-dichlorophenoxy]), and TCC in wetland plant tissues and sediments. Three wetland macrophytes: Typha latifolia, Pontederia cordata, and Sagittaria graminea were sampled from a constructed wetland in Denton, Texas, USA. MTCS concentrations were below the method detection limit (MDL) for all species. TCS root tissue concentrations in T. latifolia were significantly greater than root concentrations in P. cordata (mean ± SE in ng g⁻¹: 40.3 ± 11.3 vs. 15.0 ± 1.9, respectively), while for TCC, shoot tissue concentrations in S. graminea were significantly greater than in T. latifolia (22.8 ± 9.3 vs. 9.0 (MDL), respectively). For both TCS and TCC, T. latifolia root tissue concentrations were significantly greater than shoot concentrations (TCS: 40.3 ± 11.3 vs. 17.2 ± 0.2, TCC: 26.0 ± 3.6 vs. 9.0, (MDL)). TCC concentrations in P. cordata roots were significantly greater than in shoots (34.4 ± 5.3 vs. 15.4 ± 2.8, respectively). TCS concentrations in T. latifolia roots and sediments and TCC concentrations in sediments generally decreased from wetland inflow to outflow. To our knowledge, this is the first study documenting species and tissue specific differences in the accumulation of TCS and TCC in plants from an operational constructed wetland. The species specific differences in bioaccumulation suggest TCS and TCC removal from constructed wetlands could be enhanced through targeted plantings.     

Repeatability of Phase 1 habitat survey

As the major part of a Habitat Survey of Wales, over 80% of the land surface was surveyed in the field between 1987 and 1997 using the Phase 1 method. A resurvey of 294 randomly selected points was carried out during the early stages to audit the quality of the data being collected, leading to the development of a set of recommendations for the surveyors to improve the consistency and accuracy of habitat mapping. Recent studies have indicated a high level of discrepancy between organisations in field habitat mapping using the Phase 1 method. The findings of the Phase 1 audit in Wales are presented here to show the level of repeatability that was achieved within an organisation. There was 76% correspondence in habitat mapping between 'surveyor' and 'assessor' at the level of individual Phase 1 habitat classes. The degree of repeatability varied according to habitat strata: it was highest for modified land cover types (88%), lowest for semi-improved types (56%) and intermediate for semi-natural types (75%). An overall estimate of the repeatability of Phase 1 survey in the study area of 83% was obtained by weighting the figures for the three strata by the proportion of land area occupied by each stratum. This figure increased to 85% when habitats were amalgamated into Broad Habitat groups. These results are considerably better than those reported by studies of consistency between organisations. Most of the discrepancies between surveyor and assessor were caused by differences in habitat identification. However, at almost two thirds of the points where such a difference occurred, the assessor noted that the vegetation was transitional or borderline with that mapped by the surveyor.