Multi-scale spatial structure of heavy metals in agricultural soils in Beijing

To effectively investigate the spatial variability of heavy metals in soil, produce a higher quality spatial distribution map, and identify the potential pollution sources of heavy metals, geostatistics was employed to evaluate the effect of scale on spatial variability of heavy metals in Beijing agricultural soils. The results revealed that spatial variability of Cr, Ni, Zn, and Hg was dependent on scale. Validation of the optimality of theoretical semivariance and comparative analysis of the estimation accuracy demonstrated that the multi-scale nested model can reveal the spatial structure of heavy metals effectively and improve the estimation accuracy better than the single-scale method, thereby enabling production a higher quality spatial interpolation map. Thus, the multi-scale kriging nested model is a useful tool for revealing spatial variability of heavy metals in soils, while the spatial distribution maps allow the identification of hot spots with high concentrations of heavy metals.     

Effects of potassium alkalis and sodium alkalis on the dechlorination of o-chlorophenol in supercritical water

Effects of potassium alkalis and sodium alkalis on the dechlorination of o-chlorophenol (o-CP) in supercritical water (SCW) were studied in this paper under the conditions of 450 degrees C and 25 MPa. Experimental results indicated that the dechlorination of o-CP can be accelerated significantly by all alkalis investigated. The dechlorination of o-CP proceeded mainly via two pathways: hydrodechlorination and hydrolysis. Both of the two pathways can be promoted by alkalis, and the dechlorination of o-CP can be accelerated by both the cations and hydroxide ion dissociated from alkalis. The overall dechlorination of o-CP can be accelerated by cations via promoting the hydrodechlorination pathway, while, hydroxide ion via promoting the hydrolysis pathway. In addition, the hydrodechlorination can be accelerated faster by sodium alkalis than that by potassium ones, while, the hydrolysis can be promoted faster by potassium alkalis. This difference may be caused by the different charge density between potassium ion and sodium ion, and the different solubility and dissociation constant between potassium alkalis and sodium alkalis in SCW. Dechlorination of o-CP with addition of alkalis prior to supercritical water oxidation (SCWO) process not only can avoid the reactor corrosion caused by the generated hydrochloric acid in direct SCWO of o-CP, but also can reduce the formation of toxic chlorinated byproducts compared with direct SCWO process or SCWO of o-CP with addition of alkali.     

从安全经济学看道路交通事故频发原因

针对我国目前道路交通事故频繁发生的现象,文章指出了事故发生的原因,并重点从安全经济学的角度,分析了事故发生的深层原因。然后运用安全经济学和安全科学的基本理论,提出了防止道路交通事故频发的合理、有效的对策。     

用海泡石处理采油废水

用海泡石吸附法处理采油废水,考察了处理时间、海泡石加入量和采油废水pH对采油废水COD去除率的影响,并通过正交实验优化了采油废水处理工艺条件。通过正交实验得到的采油废水处理最佳工艺条件为：处理时间6h,粒径为150μm的海泡石加入量200g／L,采油废水pH9。在该条件下处理采油废水,COD去除率达到91％,处理后出水的COD为34．71mg／L,小于GB8978-1996（（污水综合排放标准》中的一级标准（60mg／L）。     

改革开放30年再生资源行业变迁

再生资源回收利用自建国初期就受到党和国家的高度重视,1958年周总理为其题词：“实行废品收购,变无用为有用,变一用为多用,勤俭节约,变破旧为崭新,把工农商学兵连成一片,密切协作,为全面地发展生产服务,以便更好地实现勤俭建国,改造社会的任务。”国务院专门发布了《关于加强对废弃物品收购和利用工作的指示》,把一切废弃物品广泛收集和充分利用起来,以支援国家的社会主义建设。文革期间,再生资源的回收利用受到了一定的影响。     

河北省钢铁工业主要大气污染物减排潜力分析

通过对河北省钢铁工业存在问题的分析,得出我省钢铁行业主要大气污染物为二氧化硫和粉尘.结合我省钢铁企业的实际情况,从工程技术、政策管理等方面提出相应治理措施,并对"十一五"期间我省钢铁行业二氧化硫和粉尘减排效益进行预测.预测结果显示:采用所建议的减排措施后,我省钢铁工业二氧化硫减排量对全省"十一五"减排计划的贡献率为81.4%;粉尘可减排60%.     

Occurrence of phthalates in sediment and biota: relationship to aquatic factors and the biota-sediment accumulation factor

Phthalate compounds in sediments and fishes were investigated in 17 Taiwan's rivers to determine the relationships between phthalate levels in sediment and aquatic factors, and biota-sediment accumulation factor (BSAF) for phthalates. Mean concentrations (range) of di(2-ethylhexyl) phthalate (DEHP), butyl benzyl phthalate (BBzP) and di-n-butyl phthalate (DBP) in sediment at low-flow season were 4.1 (<0.05-46.5), 0.22 (<0.05-3.1) and 0.14 (<0.05-1.3)mgkg(-1)dw; those at high-flow season were 1.2 (<0.05-13.1), 0.13 (<0.05-0.27) and 0.09 (<0.05-0.22)mgkg(-1)dw, respectively. Trace levels of dimethyl phthalate (DMP), diethyl phthalate (DEP) and di-n-octyl phthalate (DOP) in sediment were found in both seasons. Concentrations of DEHP in sediments were significantly affected by temperature, suspended solids, ammonia-nitrogen, and chemical oxygen demand. The highest concentration of DEHP in fish samples were found in Liza subviridis (253.9mgkg(-1)dw) and Oreochromis miloticus niloticus (129.5mgkg(-1)dw). BSAF of DEHP in L. subviridis (13.8-40.9) and O. miloticus niloticus (2.4-28.5) were higher than those in other fish species, indicating that the living habits of fish and physical-chemical properties of phthalates, like logKow, may influence the bioavailability of phthalates in fish. Our data suggested that DEHP level in river sediments were influenced by water quality parameters due to their effects on the biodegradation processes, and that the DEHP level in fish was affected by fish habitat and physiochemical properties of polluted contaminants.     

碱熔融法合成NaA和NaX型粉煤灰沸石的品质表征

以粉煤灰为原料采用碱熔融法合成了2种单一沸石矿物种的NaA和NaX型沸石,并对产物的结构、性能和应用指标进行了详细表征.经x射线衍射和IR光谱分析,表明合成产物是无杂晶生成的NaA和NaX型沸石相;在扫描电镜观察下,产物分别具有NaA和NaX型沸石的立方体和八面体晶体骨架结构.DTA分析表明了合成产物中沸石水的存在,且产物热稳定性较好.通过对比,粉煤灰合成的NaA和NaX型沸石的比表面积达到了相应商品沸石的66.9%和83.6%;孔容为41.1%和70.2%;阳离子交换容量(CEC,cation exchange capacity)为82.93%和84.31%.通过比较化学组成表明,大规模应用合成产物不会对环境造成危害.     

由粉煤灰合成单一的沸石及其对Cr(Ⅵ)的吸附研究

以粉煤厌为原料采用两步法合成了2种单一沸石矿物种的NaA和NaX型沸石,并对产物的结构和性能进行了详细表征.2种沸石产物的吸附性能比较结果表明,NaA型沸石优于NaX型沸石.在静态吸附条件下,研究了NaA型沸石吸附水溶液中Cr(Ⅵ)的相关参数(溶液pH值、吸附温度和吸附时间),并用Langmuir和Freundlich等温吸附线对吸附结果进行拟和.结果表明:Cr(Ⅵ)的吸附行为符合Langmuir方程;饱和吸附量为47.78 mg/g.NaA型沸石对Cr(Ⅵ)的吸附是物理和化学吸附两种行为共同作用的结果.     

基于BP神经网络的垃圾焚烧过程故障诊断

应用BP神经网络方法,建立了垃圾焚烧过程故障诊断的模型.该方法采用梯度下降法训练网络权值,利用最优停止法对网络进行了优化,避免了过拟合现象.提高了BP神经网络的训练速度和泛化能力.并以实际焚烧过程工况数据进行性能检验,检验结果表明了该BP网络具有较高的诊断精度.